### Preflight Checklist

- [X] I have read the [Contributing Guidelines](https://github.com/electron/electron/blob/master/CONTRIBUTING.md) for this project.
- [X] I agree to follow the [Code of Conduct](https://github.com/electron/electron/blob/master/CODE_OF_CONDUCT.md) that this project adheres to.
- [X] I have searched the [issue tracker](https://www.github.com/electron/electron/issues) for a feature request that matches the one I want to file, without success.

### Electron Version

13.1.7

### What operating system are you using?

Windows

### Operating System Version

Windows 10 version 20H2

### What arch are you using?

x64

### Last Known Working Electron version

12.0.15

### Expected Behavior

Checking `navigator.userAgentData` in Chrome 91 returns an array of brands appropriately. Electron 13/14 do not return anything.

This appears to then become a problem for my situation. I am posting a form with hidden variables to a third-party vendor I work with. This form post ultimately loads an iframe.

Expected: As it does in Chrome 91, load the iframe from this third-party vendor.

### Actual Behavior

A header of "sec-ch-ua" is included in the request to the third-party vendor and it is blank. They are rejecting the post because of an invalid header. I suspect this is because Chrome 13/14 does not make this hint data made available correctly.

I tried loading various sites in Chrome 91 that do load brand names in Electron 13/14 and they are empty if you review `navigator.userAgentData`.

### Testcase Gist URL

_No response_

### Additional Information

_No response_
shell/browser/electron_browser_client.cc
prefs->local_storage_enabled = true;
  prefs->databases_enabled = true;
  prefs->allow_universal_access_from_file_urls = true;
  prefs->allow_file_access_from_file_urls = true;
  prefs->webgl1_enabled = true;
  prefs->webgl2_enabled = true;
  prefs->allow_running_insecure_content = false;
  prefs->default_minimum_page_scale_factor = 1.f;
  prefs->default_maximum_page_scale_factor = 1.f;
  prefs->navigate_on_drag_drop = false;
#if !BUILDFLAG(ENABLE_PICTURE_IN_PICTURE)
  prefs->picture_in_picture_enabled = false;
#endif
  ui::NativeTheme* native_theme = ui::NativeTheme::GetInstanceForNativeUi();
  prefs->preferred_color_scheme =
      native_theme->ShouldUseDarkColors()
          ? blink::mojom::PreferredColorScheme::kDark
          : blink::mojom::PreferredColorScheme::kLight;
  auto preloads =
      SessionPreferences::GetValidPreloads(web_contents->GetBrowserContext());
  if (!preloads.empty())
    prefs->preloads = preloads;
  SetFontDefaults(prefs);
  
  auto* web_preferences = WebContentsPreferences::From(web_contents);
  if (web_preferences) {
    web_preferences->OverrideWebkitPrefs(prefs);
  }
}
void ElectronBrowserClient::RegisterPendingSiteInstance(