### Preflight Checklist

- [X] I have read the [Contributing Guidelines](https://github.com/electron/electron/blob/master/CONTRIBUTING.md) for this project.
- [X] I agree to follow the [Code of Conduct](https://github.com/electron/electron/blob/master/CODE_OF_CONDUCT.md) that this project adheres to.
- [X] I have searched the [issue tracker](https://www.github.com/electron/electron/issues) for a feature request that matches the one I want to file, without success.

### Problem Description

We need to load a custom error page when the certificate is invalid but without "isMainFrame" property we don't know when to load the custom error page using webContents.loadURL()

### Proposed Solution

webContents.on("certificate-error", ((event, url, error, certificate, callback, isMainFrame)

### Alternatives Considered

Not sure

### Additional Information

Not sure
shell/browser/api/electron_api_app.cc
const base::RepeatingCallback<
        void(const base::CommandLine& command_line,
             const base::FilePath& current_directory)>& callback,
    const base::CommandLine& cmd,
    const base::FilePath& cwd) {
  
  if (Browser::Get()->is_ready()) {
    callback.Run(cmd, cwd);
  } else {
    scoped_refptr<base::SingleThreadTaskRunner> task_runner(
        base::ThreadTaskRunnerHandle::Get());
    task_runner->PostTask(
        FROM_HERE, base::BindOnce(base::IgnoreResult(callback), cmd, cwd));
  }
  
  return !Browser::Get()->is_shutting_down();
}
void GotPrivateKey(std::shared_ptr<content::ClientCertificateDelegate> delegate,