### Is there an existing issue for this?

- [X] I have searched the existing issues

### Current Behavior

config.py's VALID_REGIONS only uses the default boto3 argument to find available regions. This means that regions from other partitions besides `aws` are not validated. 

When trying to list SNS Topics I get the error:

`An error occurred (InvalidParameter) when calling the ListTopics operation: Invalid region specified in "Authorization" header: "us-gov-west-1"`

I believe this is because VALID_REGIONS is set to use the default boto3 `get_available_regions()` parameter for `partition_name`, which is only 'aws'

https://github.com/localstack/localstack/blob/5784742b6f202133de11ef19544dd53c11c126e1/localstack/config.py#L454

https://github.com/boto/boto3/blob/master/boto3/session.py#L159-L162



### Expected Behavior

Non-default partition regions are also acknowledged as valid regions, and an error is not thrown.

VALID_REGIONS is set to aggregate regions from all available partitions.

### How are you starting LocalStack?

Custom (please describe below)

### Steps To Reproduce

#### How are you starting localstack (e.g., `bin/localstack` command, arguments, or `docker-compose.yml`)

    Running through a kubernetes deployment, using the image localstack: 0.12.17

#### Client commands (e.g., AWS SDK code snippet, or sequence of "awslocal" commands)

```
# using boto3 locally
sns_client: boto3.client = boto3.client("sns", endpoint_url=AWS_URL)
topics = sns_client.list_topics()
```

`An error occurred (InvalidParameter) when calling the ListTopics operation: Invalid region specified in "Authorization" header: "us-gov-west-1"`

### Environment

```markdown
- LocalStack Docker image: 0.12.17
- Kubernetes
- Running on govcloud
```


### Anything else?

Current workaround:

setting `USE_SINGLE_REGION=true` and `AWS_DEFAULT_REGION=us-east-1` successfully mitigates this problem, and causes no error to the thrown when listing topics.
"""Parses the environment variable $SERVICES with a comma-separated list of services
    and (optional) ports they should run on: 'service1:port1,service2,service3:port3'"""
    service_ports = os.environ.get("SERVICES", "").strip()
    if not service_ports:
        return DEFAULT_SERVICE_PORTS
    result = {}
    for service_port in re.split(r"\s*,\s*", service_ports):
        parts = re.split(r"[:=]", service_port)
        service = parts[0]
        key_upper = service.upper().replace("-", "_")
        port_env_name = "%s_PORT" % key_upper
        
        port_number = DEFAULT_SERVICE_PORTS.get(service)
        
        if os.environ.get(port_env_name):
            port_number = os.environ.get(port_env_name)
        
        if len(parts) > 1:
            port_number = int(parts[-1])
        
        try:
            port_number = int(port_number)
        except Exception:
            port_number = 0
        result[service] = port_number
    return result
def populate_configs(service_ports=None):