You will be shown an abstract from a biomedical research paper. Given this abstract, your task is to extract all unique entities of the following types: ["Chemical"].

Please return the output as a JSON object of the format: {"Chemical": ["Arsenic", ...]}. The keys should be entity types and values should be lists of extracted entities belonging to the corresponding type. If you cannot find entities belonging to a specific type, the value should be [].

Only output the JSON object and do not include any additional text.

Abstract:

Nuclear Flux Densities during a Model Pericyclic Reaction with Energies Well Above and Below the Potential Barrier. Pericyclic reactions with energies E well above the potential energy barrier B (case E>B) proceed with quantum nuclear flux densities 〈j〉 which are essentially proportional to the nuclear densities ρ in the femtosecond time domain. This corresponds to the definition of classical (cl) mechanics, jcl =υcl ρcl , with almost constant velocity vcl . For the other case E<B, however, that is, in the domain of coherent tunneling, we discover the opposite trend, that is, 〈j〉 has maximum value close to the barrier where ρ is a minimum (in fact where ρ is close to zero). The general conclusion is that quantum mechanical nuclear flux densities may be at variance from traditional expectations based on classical trajectories. This prediction calls for experimental demonstration. The counter-intuitive proof-of-principle is demonstrated for a simple, one-dimensional model of the Cope rearrangement of semibullvalene.
{"Chemical": []}