You will be shown an abstract from a biomedical research paper. Given this abstract, your task is to extract all unique entities of the following types: ["Chemical"].

Please return the output as a JSON object of the format: {"Chemical": ["Arsenic", ...]}. The keys should be entity types and values should be lists of extracted entities belonging to the corresponding type. If you cannot find entities belonging to a specific type, the value should be [].

Only output the JSON object and do not include any additional text.

Abstract:

The gas-phase reaction of methane sulfonic acid with the hydroxyl radical without and with water vapor. The gas phase reaction between methane sulfonic acid (CH3SO3H; MSA) and the hydroxyl radical (HO), without and with a water molecule, was investigated with DFT-B3LYP and CCSD(T)-F12 methods. For the bare reaction we have found two reaction mechanisms, involving proton coupled electron transfer and hydrogen atom transfer processes that produce CH3SO3 and H2O. We also found a third reaction mechanism involving the double proton transfer process, where the products and reactants are identical. The computed rate constant for the oxidation process is 8.3 × 10(-15) cm(3) s(-1) molecule(-1). CH3SO3H forms two very stable complexes with water with computed binding energies of about 10 kcal mol(-1). The presence of a single water molecule makes the reaction between CH3SO3H and HO much more complex, introducing a new reaction that consists in the interchange of H2O between HO and CH3SO3H. Our kinetic calculations show that 99.5% of the reaction involves this interchange of the water molecule and, consequently, water vapor does not play any role in the oxidation reaction of methane sulfonic acid by the hydroxyl radical.
{"Chemical": ["H2O", "MSA", "methane sulfonic acid", "HO", "CH3SO3", "CH3SO3H", "hydroxyl", "hydrogen"]}