You will be shown the title of a chemistry paper, together with sections excerpted from the body of the paper. The paper sections may include HTML tags like `<p>` and `</p>`; please ignore these. Your task is to write an abstract for the paper. Your response should include the abstract and no other text.

Title:
Chemical and radioanalytical investigations of 106Ru-containing air filters from Vienna in fall 2017: searching for stable element anomalies

Paper sections:
Introduction
<p>The release of radioactive materials into the environment is inherently associated with great public concern. The radioactive fallout from atmospheric nuclear explosions in the 20th century has been largest contributor to anthropogenic radionuclides in the environment. At the height of the cold war in the early 1960s, global fallout reached a magnitude that was no longer irrelevant for the public health. These concerns ultimately triggered diplomatic attempts to ban atmospheric nuclear tests by establishing the Partial Test Ban Treaty (PTBT; sometimes also referred to as Limited Test Ban Treaty, LTBT), which was opened for signature in 1963. In 1996, the Comprehensive Nuclear-Test-Ban Treaty (CTBT) opened for signature [1], aiming to terminate nuclear testing in any environment. For the verification of the CTBT, the international monitoring system (IMS) was installed, designed to detect any violations of the CTBT by geophysical and radionuclide monitoring of the globe. The establishment of the IMS coincided with increased attempts of national governmental efforts to set up monitoring networks that would allow the detection and public risk assessment of undeclared nuclear releases such as the Windscale or Kyshtym accidents in 1957 [2] or the Chernobyl accident in 1986.</p><p>Two unusual incidents of radionuclide releases occurred in 2017. In January/February of that year, an unusually long episode of 131I was observed [3]. In fall 2017, European monitoring stations reported an unusual and unprecedented detection of radioruthenium in air [4]. Rapid gamma measurements revealed the presence of radioactive 106Ru (T½ = 373.6 days), and in some stations also 103Ru (T½ = 39.2 days) in air. Relatively little is known about the release at this point. However, several monitoring stations reported of futile attempts to detect other radionuclides in addition with the radioruthenium. This indicates that the source of the radioruthenium was probably not an accident of a nuclear reactor. Until today, the source remains uncertain and intensely debated [4]. Although 103Ru may be produced by neutron activation of stable 102Ru, both radioruthenium nuclides are prominent fission products. The fission yield, however, largely depends on the type of fissile material, as 239Pu based nuclear fuel produces 106Ru at a higher yield than 235U. For 103Ru, this difference in the yield is not so pronounced. More on the nuclear background of the production can be found elsewhere [5].</p><p>In the present study, we aim at the analysis of stable element analysis in order to establish a chemical fingerprint of the airborne particulate matter at the time of the release. We are interested in the elemental composition of the particulate matter as the released radioruthenium may have been associated with some anomalous stable elements that went unnoticed so far. Such anomalies may be represented on the 106Ru containing air filters. Therefore, we performed instrumental neutron activations analysis (INAA) in Vienna and electron microscopy to elucidate the chemical composition and morphology of the particulate matter contained within the filter materials.</p>

Location and sampling
<p>The high-volume air filter system used filters made of polypropylene (PP) and was stationed in Vienna, Austria during the 106Ru episode. Collection time was nearly 140 h, namely from the 28 Sep. 2017 12:24 to 04 Oct. 2017 8:14. A total volume of 94,444 m3 air passed through the PP filter during this time, during which the maximum of the 106Ru plume passed Vienna. After collection, the filter was pressed to a round sample with 5.0 cm diameter, a height of 0.55 cm and a mass of 9.7 g. The round filter was measured by gamma spectrometry and then split in half (5.4 g). This segment was used in this study. The total activities collected on the filter were 546 Bq 7Be, 461 Bq 212Pb, 0.66 Bq 103Ru, and 2030 Bq 106Ru, respectively. Activities are decay-corrected to 04.10.2017, 08:30. Radioberyllium (7Be) and radiolead (212Pb) are typical naturally occurring radionuclides, which are continuously produced in the earth's higher atmosphere (7Be) or by decay of primordial 232Th, respectively. Their presence in the air filter hence comes expectedly [6, 7].</p>


<p>Elements, activation products, half-lives, gamma energies, and reference materials used for quantitative analysis</p><p>x certified reference value used for quantitative analysis</p><p>*233Pa and 239Np are produced by β-decay of the activation products of 232Th and 238U, respectively. Neutron capture forms short-lived 233Th (T1/2 = 22.3 min) and 239U (T1/2 = 23.5 min), respectively</p>

Instrumental neutron activation analysis
<p>A short-time (2 min) and a long-time irradiation (32 h) was performed at the 250 kW TRIGA Mark II research reactor of the Atominstitut in Vienna, Austria. The short-time irradiation was performed with the pneumatic sample transfer system into the F-ring of the reactor (thermal neutron flux density 2 × 1012 cm−2 s−1). The long term irradiation took place in a dry irradiation tube in the graphite reflector, with a neutron flux density of about 1 × 1012 cm−2 s−1.</p><p>For the analysis of short-lived, activatable radionuclides such as 28Al, 49Ca, 51Ti, 52V, 56Mn, and 156Dy, the sample vials were transferred into the irradiation position by means of a pneumatic transfer system (neutron flux density of approx. 3 × 1012 cm−2 s−1). After 2 min irradiation, sample vials were cleaned on the outside (adding up to 5 min cooling time) and measured immediately by gamma spectrometry with a measurement time of 5 min, yielding the activities of 28Al, 49Ca, 51Ti, and 52V. Following a 3 h decay, another measurement was performed with a measurement time of 12 min, yielding the activities of 56Mn and 156Dy. Gamma spectrometry was performed with a 151 cm3 HPGe-detector (1.8 keV resolution at the 1332 keV 60Co peak, 50.1% relative efficiency), and a multi-channel analyzer with a preloaded digital filter and loss-free counting system [8, 9].</p><p>After the short-time irradiation, samples were irradiated for 32 h in the dry irradiation tube of the TRIGA Mk II in Vienna. After a decay time of 5 days, the medium-lived activation products 24Na, 42K, 76As, 140La, and 239Np (U) were measured. After 21 days of cooling, the long-lived activation products 46Sc, 51Cr, 59Fe, 60Co, 65Zn, 86Rb, 95Zr, 124Sb, 131Ba, 134Cs, 141Ce, 147Nd, 152Eu, 160Tb, 169Yb, 177Lu, 181Hf, 182Ta, and 233Pa (Th) were measured. The measurement time was 1800 s and 10,000 s, respectively. All quantifiable elements, including their neutron activation products, their half-life and gamma energy is listed in Table 1. Additionally, it is noted which reference material has a certified value for which element. Further information on the measurement can be found elsewhere [10–12].</p>

Particle size and main elemental composition
<p>For a microscopic inspection of the particles collected on the filter surface, scanning electron microscopy (SEM) was used. Without further preparation, the surface of the pressed PP filter samples was imaged with the Philips SEM XL30 ESEM, which is coupled with an energy dispersive X-ray spectroscopy (EDXS) system by EDAX. SEM pictures were taken in back-scattered electron mode and a voltage of 20 kV. With this method, an overview of existing particles and their general size was obtained to check for any apparent anomalies. Furthermore, it allows the investigation of the elemental distribution of the particles by using the EDXS.</p>


<p>Distribution pattern of elemental mass fractions of two PP filters from Vienna (2007 and 2017, respectively). All values are normalized to the average elemental abundance of the upper continental crust [13]</p>

INAA
<p>For comparison of the determined elemental concentrations to other urban areas, the elemental mass fraction values from reference materials NIST SRM 1648a Urban Particulate Matter can be used. The comparison shows that there are no anomalies or uncommon occurrences of certain elements in unusual concentrations or ratios in urban living areas.</p><p>Please note that the the mass fractions of the reference filter from 2007 are constantly lower than from the 106Ru containing filter sample from 2017. It is apparent that the amount of filtered air has been much lower in 2007, although the actual amount remains unknown. This clearly indicates that a lower amount of particulate matter had been sampled in 2007 compared with 2017. The differences in the mass fraction range are mainly shifted to lower amounts with a factor of less than 10. In addition to the elements that have been displayed in Fig. 1, the following elements have been detected, but could not be quantified (due to a lack of certification values in the reference materials we used): gold, chlorine, bromine, osmium, and magnesium. No stable ruthenium isotopes were detected, because ruthenium is determined with low sensitivity in INAA. In addition, a spectral interference with activation products of barium raised the detection limit. With the exception of osmium, INAA did not reveal detectable amounts of other platinum group elements (Rh, Pd, Ir, and Pt), which are characterized by a similar chemical behavior like ruthenium. Although uranium is a common finding in INAA of geological materials [7–9], no traces have been detected in the filter.</p>


<p>SEM pictures and EDXS spectra of three different spots found on the filter material</p><p>SEM pictures and EDXS spectra of three different spots on a larger agglomerate</p>

Conclusions
<p>In this study, attempts have been undertaken to reveal possible anomalies in the chemical (including trace element) composition and the morphology of particles contained in an air filter that previously collected radioactive 106Ru in Vienna in fall 2017. By using the SEM/EDXS a general overview concerning the particle shape and major element composition was obtained. Neither particle shape nor composition revealed uncommon or unusual characteristics that may be indicative of an unusual carrier phase of the anthropogenic radionuclide 106Ru. No unusual heavy metal spots were found in the SEM imaging.</p><p>Instrumental neutron activation analysis was used to provide more comprehensive and thus more reliable chemical information on the stable element composition of the 106Ru-containing filter. By INAA, the chemical fingerprints of activatable major and trace elements of the 106Ru filter (2017) have been determined and compared to a filter that had been in operation 10 years ago in the same urban environment. This method generated values for 28 elements, however no uncommon element appearance or scale of mass fraction was determined. All values for 2017 are comparable with 2007. So no hint was found for a chemical/stable element irregularity or anomaly in the filtered, radioruthenium containing air from 2017 compared to 2007.</p>
Related to the recent nuclear release of radioactive ruthenium isotopes in fall 2017, we analyzed air filters from Vienna for irregularities in the (stable) elemental composition of particulate matter from this period. Methods were SEM/EDXS and INAA. For comparison, a reference filter from 2007 and blank filters were used. The chemical fingerprint encompassed 28 elements. The results show no indication for a considerable change in the elemental composition of the suspended matter. For example, no anomalies in the abundance of platinum group elements were found. The results suggest that the release of 106Ru had not been accompanied by a release of detectable amounts of (activatable) stable elements.