Neda Nikvash 
  
Redelf Kraft 
  
Alireza Kharazipour 
  
Markus Euring 
  
  
  
  
COMPARATIVE PROPERTIES OF BAGASSE CANOLA AND HEMP PARTICLE BOARDS

Keywords: Ernterückstände der Einjahrespflanzen Bagasse (Saccharum officinarum Die Ergebnisse zeigen, dass nahezu alle mechanisch-technologischen Eigenschaften der Spanplatten die Anforderungen der Vergleich der Ergebnisse der Dickenquellung und Wasseraufnahme zeigt sich, dass zwischen Platten mit Bagasse-und Hanfanteilen in der Mittelschicht von bis 50 % und den Referenzplatten kaum Unterschiede bestehen, während Platten mit zunehmenden Rapsanteilen hier immer deutlicher abfallen. Zusammenfassend zeigen die Untersuchungen, dass sich Ernterückstände von Einjahrespflanzen zur Herstellung von normgerechten Spanplatten

come    

INTRODUCTION

In recent years the importance of wood and waste wood as a source of energy has increased due to soaring energy prices on the one hand. On the other hand, this situation has caused a sharp increase in the price of manufactured materials (EPF, 2006).

Agricultural residues are an excellent alternative to using virgin wood chips for many reasons. At present some agricultural residues such as wheat and rice straws, sorghum stalks and some annual plants such as hemp and jute are used as raw materials for pulp and paper production [START_REF] Rousu | Sustainable pulp production from agricultural waste[END_REF][START_REF] Ashori | Nonwood fiber-A potential source of row material in paper making[END_REF][START_REF] Schöpper | Production of innovative hemp based three-layered particle boards with reduced raw densities and low formaldehyde emissions[END_REF]. Moreover numerous studies have been performed to introduce new lignocellulosic resources for paper and wood industries.

One of the most abundant natural resources is the by-product of the sugar industry, the bagasse [START_REF] Chen | Producing Nonwoven Materials from Sugarcane[END_REF]. Bagasse ( Saccharum officinarum L.) -a fibrous material -is one of the main by-products of sugarcane manufacturing plants which is obtained after the glucose syrup is leached out of the sugarcane. One developing application for bagasse fibers is in the manufacturing of material products, such as automobile interior trim parts [START_REF] Chen | Comparative Study on Kenaf Nonwoven for Automotive Headliner[END_REF][START_REF] Rowell | Fiberboards Made From Acetylated Bagasse Fiber[END_REF].

Another raw material of interest for the wood industry is canola. Canola (Brassica napus L.) is widely cultivated throughout the world and used as a major oilseed for vegetable oils and biodiesel production. In addition to oil production from the canola seed, the leaves of canola can be used as an animal feed (Banuelos et al. 2009). Thus, it can be concluded that at least 34 million tons of canola stalks are available annually which could be used in various products, including particle boards.

Actually the wood costs are generally rising with demand surpassing supply [START_REF] Kharazipour | Holz als Werkstoff[END_REF]. In fact, the international wood-supply balance is now beginning to shift in favor of alternative non-wooden materials, including industrial hemp. Hemp is a plant called `cannabis sativa L. which is the most durable plant that has been used since pre-history for various applications. The hemp plant consists of long, strong fibers. The long fiber is hemp's best feature, even when ground up it is still two to three times stronger than comparative annual plants fibers [START_REF] Osburn | Hemp plywood becomes a Reality[END_REF]. Another component of hemp is the sheaves. The sheaves amount to up to 60% of each hemp plant. In the past this material was only used as litter in animal stables. Especially in these studies the sheaves are used to produce particle boards [START_REF] Karus | Europäische Hanfwirtschaft 2001 bis 2004: Anbau, Rohstoffe, Produkte und Trends[END_REF][START_REF] Ohlhauser | Beschichtete Hanfspanplatte -Cannabis Excellent. Entstehung und Marktpotential der ökologischen Leichbauplatten[END_REF][START_REF] Cescutti | Hanf in technischen Anwendungen: Gegenwart und Zukunft[END_REF][START_REF] Schöpper | Production of innovative hemp based three-layered particle boards with reduced raw densities and low formaldehyde emissions[END_REF]. Today the goal of hemp farming is to use it for the production of wood composites [START_REF] Karus | Europäische Hanfwirtschaft 2001 bis 2004: Anbau, Rohstoffe, Produkte und Trends[END_REF][START_REF] Ohlhauser | Beschichtete Hanfspanplatte -Cannabis Excellent. Entstehung und Marktpotential der ökologischen Leichbauplatten[END_REF].

In light of these changes, hemp sheaves may become increasingly competitive in price relative to wood, particularly since fast-growing tree species such as aspen, poplar and grand fir are the only alternatives to conventional wood sources in northern latitudes such as Europe (Lloyd 1996 Vos and[START_REF] Voß | Properties of light particle boards manufactured using abies grandis (grand fir)[END_REF]. Combining wood with other materials from renewable resources creates new functional properties for wood composites (COST Action E20 2003).

This study is mainly focused on the research of properties with regard to wood chips with different percentages of hemp sheaves, bagasse and canola chips.

MATERIALS AND METHODS Board Manufacturing

Three-layer particle boards with a different percentage of wood chips and annual plant materials were manufactured in the pilot plant of Buesgen-Institute, Department of Molecular Wood-Biotechnology and Technical Mycology, Georg August University of Goettingen. The boards were made in different series from one year old bagasse material, agriculture residues canola chips and hemp sheaves. The chips and sheaves had been stored prior to the particle board manufacturing. They were hammer-milled to reach a size of ca. 6-mm, and were dried in a dryoven to about 3-4% moisture content (MC). The materials were finally mixed with different combinations of bagasse, canola and hemp and wood chips in the middle layer. The surface layer was of 100% wood chips. Both layers were glued with Urea Formaldehyde (UF) resin from BASF, Germany, formed into mats, and pressed into particle boards at 200° C (70 cm x 46.5 cm x 2 cm) with target conditions listed in Table 1. For each annual plant material (bagasse, canola and hemp) 15 particle boards were made.

Table 1. Technical information for the manufacture of particle boards with bagasse, canola and hemp material in the middle layer (ML) and 100% wood chips in the surface layer (SL).

Tabelle 1: Herstellungsparameter der Spanplatten aus Bagasse, Raps und Hanf in der Mittelschicht und 100 % Holzspänen in der Deckschicht.

Preparation of materials:

The materials were industrial wood chips, ordered from Pfleiderer AG, Guetersloh, Germany. The annual plants bagasse (Saccharum officinarum) were received from Iran, hemp (Cannabis sativa) from Germany (Nordhanf GmbH) and canola [Brassica Rapa (syn. Brassica campestris)] from an agriculture company from southwest Germany.. Three samples of each series of particle boards were produced. The fibers of the surface layer, in all series, consisted totally of industrial wood. The middle layers were a combination of 10, 20, 30, 50 and 100 percent of bagasse, canola or hemp with industrial wood chips (see Table 1). The samples for various tests were prepared from the experimental boards according to the specifications shown in Table 2. Bending MOE/MOR and internal bond (IB) strengths were tested with a Universal Testing Machine (ZWICK/ROELL) according to EN-310 and EN-319 standards respectively.

Sample preparation and testing mechanical-technical properties of the particle boards

Thickness swelling (TS) tests were done by means of the 24-hour water soaking procedure according to the EN 317 standard. Conditioned samples, square shape, having side lengths of 50 mm ± 1 mm for the evaluation of thickness swelling (TS) were prepared according to EN 317 standard.

The measured properties were compared with the corresponding specifications listed in EN-312-2 (European committee for standardization 2003) for particle boards (category: particle boards for interior fitments including furniture EN 312-2:2003).

RESULTS AND DISCUSSION

Bending MOE and MOR MOE and MOR as a function of sample strengths were measured. According to EN-312-2 the minimum requirement of modulus of rupture (known as bending strength) is 13 N/mm² (> 13 to 20 mm thickness of particle boards). Figure 1 shows the bending properties of the bagasse, hemp, and canola particle boards. Various percentages of bagasse and hemp in the boards obtained higher values than those of boards containing canola. Based on these results, all bagasse, hemp and canola boards fulfill the minimum requirement of the EN standard. Figure 2 shows the modulus of elasticity of the particle boards. Boards containing hemp gained considerably better bending strength than the two other series (canola, bagasse). Based on the results, with a density of 700 kg/m³, the values of boards are higher than those values which are required in EN-312-2. The bar chart of the IB strength as a function of mechanical strengths is shown in Figure 3. Similar to the MOE and MOR data, bagasse and hemp's IB strengths fulfilled the minimum requirement of European standards. In all combinations of bagasse with wood chips in the middle layer the requirements of EN 312-2 could be highly fulfilled.

The results of the hemp particle boards show the best IBs. They are nearly two times higher than the standard value. The case of this strong difference can be mentioned by the usage of hemp sheaves in the middle layer of the boards. In contrast to hemp sheaves, the use of more than 50% of canola material could not meet the standard value. The achieved value in canola 30% was 0.35 N/mm², which is the minimum value requirement in EN 312-2. 

Thickness Swelling

The TS and water absorption (WA) data for all series are summarized in Figures 4 and5. The values for thickness swelling after immersion in water are shown in Figure 4. In comparison to the reference, all values from 10% to 30% for the series of hemp and bagasse are very similar (Figure 4). Increasing usage of canola in the boards' middle layer shows more and more negative effects.

The mean WA for hemp series, except in the mixture of 100%, was less than reference value. The WA average for bagasse from 10% to 30% in mixture was lower than the value of the reference. The particle boards with a middle layer mixture of 50% and 100% bagasse were higher than the reference value. All mixtures of canola show higher WA in comparison to all other boards (Figure 5). 

Conclusion

These studies show that particle boards with a middle layer of annual plants such as bagasse, hemp and canola in different mixtures with wood chips indicate good mechanical-technological properties. The particle boards made with hemp and bagasse in mixtures of up to 50% fulfill the EJWWP465_source requirements of EN 312-2. In the case of hemp sheaves, even the use of 100% is possible. The mechanical-technological properties of particle boards produced with canola chips in mixtures with wood chips did not meet all specifications of EN 312-2.

The additional measured water absorption and thickness swelling reveal that using hemp and bagasse of up to 50% leads to similar results in comparison to the references. In the presence of canola the TS and WA are poor.

The achieved results of particle boards containing canola show that further investigations for better mechanical-technological properties are necessary. In the same case also the usage of bagasse in higher amounts for the production of particle boards has to be improved.

The main reason for these disadvantages could be the inhomogeneous structure of the milled and sized bagasse and canola chips. Therefore, for future works the use of residues of annual plants should be adapted to the process of producing particle boards.

Figure 1 ;Figure 2 :

 12 Figure 1; Comparison of the bending strengths of particleboards, containing bagasse, hemp and canola, each in mixture with wood in the middle layer Abbildung 1: Vergleich der Biegefestigkeiten der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holz in der Mittelschicht.

Figure 3 :

 3 Figure 3: Comparison of Internal Bond Strength of particle boards, containing bagasse, hemp and canola, each in mixture with wood in the middle layer Abbildung 3: Vergleich der Querzugfestigkeiten der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holz in der Mittelschicht.

Figure 4 :Figure 5 :

 45 Figure 4: Comparison of thickness swelling of particle boards, containing bagasse, hemp and canola, each in mixture with wood after 24 hour soaking Abbildung 4: Vergleich der Dickenquellung der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holz in der Mittelschicht

Table 2 :

 2 Test criteria, size and number of samples of the produced particle boards Tabelle 2: Testkriterien, Maße und Anzahl der Spanplattenproben

	Test	Sample Size	Number of samples
		[mm]	for each series
	______________________________________________________________________________________
	Bending MOE/MOR	50 x 360 x 20	9 / 9
	Internal Bond (IB) Strength	50 x 50 x 20	24
	Thickness Swelling (TS)	50 x 50 x 20	24
	Water absorbance	50 x 50 x 20	24
	______________________________________________________________________________________

EJWWP465_source