I'm so happy you like Sedovic.
Pam is going to have to take better care of himself.
They say that Price was a great singer when she was young.
I just told Jorge what time he needs to be here.
Nicolette sat down beside Randall.
Why does Jean want to go there?
Carl loved playing dress-up with her doll as a child.
Caroline assigned Ofer to do the job.
Clyde is a strong man.
Did you tell Butler where you and Jinchao first met?
Pascal and Simon spent a year traveling around the world.
Jeffery blushed when he saw Irvin naked.
Martyn doesn't want us to do that.
My real name is Rudy.
Laurie doesn't have to help Daryl.
Lin rummaged through the contents of her purse, but couldn't find what she was looking for.
Hitoshi has got to be in this building somewhere.
Does Dannie know Matthieu is here?
Spass thinks Marcos is beautiful.
Lenora isn't as happy as he should be.
What should Panacea do now?
Kathleen said Mac was his daughter.
Kiki wants to take Shutoku out tomorrow night.
Kriton just can't stay away.
I know how to handle kids like Sandip.
I lent Slartibartfast a book about Germany.
Ask Tyler to call me. He has my number.
Kory was struck by lightning.
Sridharan said he had a lot of money.


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Tag Archives: Mind Space
Mind Space Volume 1: Conspiracy / Book 3: Mind Space by David S. Moore
October 14, 2014 by rachelauthorbarnard in Author Tuesdays, Book Review and tagged David S. Moore, Mind Space, Science Fiction | 3 Comments
A Science Fiction Novel published on amazon.com (01/10/2014)
Book three of the Mind Space Series follows the last years in the race to ready the planet for Mind Space on the target date of 2084. Jaimeson-Cale is doing everything in their power to reach their target percentage of Mind Shield hosts planet-wide. The Mind-Freedom Alliance is still in the game to take down Mind Space, the Mind Shield, and Jaimeson-Cale with their increasingly threatening tactics. "…No, the problem wasn't the Mind Shield itself. The problem was with the people who were behind it– the people who were determined to use it to assert control over all of humanity." (Page 400).
Science Fiction, Mind Control, America 2070's and 2080's, Technology, Resistance Movement, Rival Product, Monopoly, Free Market, Restoration
The Mind Space Series has a powerful message: Is it ok to enslave the mind for the good of the masses? "'War will cease,' Daniel added. 'Hatred and prejudice will be gone. Drug abuse, obesity, domestic violence– the self-destructive behaviors that ruin lives in every country– they will all quickly become things of the past.'" (Page 303). The Mind-Freedom Alliance and almost all who had a Mind Shield removed, believe that it isn't alright to enslave the mind no matter the results. Adam True and the Defenders of the True believe the opposite, but they are also deluded enough to think that the Mind Shield doesn't enslave the mind, only frees it from the tyranny of its own doubt and confusions (Page 79). Those who are in control of their own thoughts and not under the influence of the sales pitch of the Mind Shield propose individual freedoms over any alternative. Many people, though, cannot discount the life saving and wonderful characteristics the Mind Shield has to offer. That's where the Limbic Freedom comes in. It offers all that the Mind Shield offers, plus a thought sharing network to boot. Yet, the masses are still being converted by the millions to Mind Shield, but not through completely moral sales tactics.
As this is the third book in the series, it brings the finale. Throughout the third book I began to change my allegiance from rooting for the underdogs and those trying to free the mind to Jaimeson-Cale, but for a unique reason. I wanted the Mind Space to happen because I kind of wanted to see how a society without drug addiction, eating disorders, racism, hate or violence would look like. The world building for this type of world is silent, as we are only given one side of it: the planning, development, marketing, scheming world but what would a Mind Space world be like? What kind of world would David Moore build for his readers?
The vision of Jaimeson-Cale for humanity with the Mind Shield and Mind Space is warped, though, and I really would never want them to win the fight. Moore brings up an interesting point when he says, "The Mind Shield exerted a moderating influence on all behavior, even otherwise harmless behavior. It made one wonder what the masters of the Mind Shield thought ideal human behavior should be." (Page 84).
I almost didn't notice the fact that Moore had seamlessly given women and men equal roles in his novel. Women (just like the men) were in positions of power, they were victims and saboteurs, security guards and leaders.
I very much enjoyed the Mind Space series and look forward to more science fiction from David Moore. He brings up thought-provoking questions in his novels, can describe a world stirringly, and flows through his story seamlessly from beginning to end.
I recommend this book for anyone who enjoys a well written novel and easy-to-read science fiction novel. This book reminds me of Childhood's End by Arthur C. Clarke in it's sweeping narration through long periods of time with a focus on a single aspect of society.
This novel was published through Createspace Independent Publishing Platform 01/10/2014 and is available on Amazon here.
TLDR Star Rating: 4.75
David S. Moore's Website
FreeValley Publishing's David S. Moore
Book Review: Mind Space Volume 1: Conspiracy / Book 2: Restoration by David S. Moore
September 9, 2014 by rachelauthorbarnard in Book Review, Free Valley Publishing, Local Authors and tagged David Moore, Mind Space | 1 Comment
Mind Space Volume 1: Conspiracy / Book 2: Restoration by David S. Moore
Book one of the Mind Space Series ended with the Alliance broken apart and the giant corporation Jaimeson-Cale taking a hit from a terrorist attack that cut off their ability to use the mind control aspect of the Mind Shield while still being able to monitor for certain health conditions. Version 3 of the Mind Shield is introduced in this novel Restoration as the ability of the Mind Shield to eliminate drug addiction. Sounds great, right? Not if you are forced to get a Mind Shield. This second book in Moore's series introduces the more nefarious sales tactics of Jaimeson-Cale. They will do anything to get the sale, but not just to build their bottom line or please their investors. Moore gives us more background into the ultimate purpose of the Mind Shield in this second book: Mind Space. Mind Space will be version 7, the final version, of the Mind Shield that will create a sense of community bond in order to bring about spiritual purity. The catch is that Mind Space cannot exist unless 73% of the population of the world have Mind Shields. On top of that number, Jaimeson-Cale already promised Mind Shield users that version 7 and Mind Space will be available in 2084. The projection of sales doesn't even come close after the attack of '55, but they have strategies to build up their user base and with the release of each version hope to convert new followers to their cause. The only problem is the introduction of competition in the market in the form of the Limbic Freedom. Limbic Freedom's endgoal is simple: to combat the Mind Shield and keep Mind Space from happening
"The Mind Shield was a nemesis. The best tool that they had to defend against it was Limbic Freedom — of that she was certain. It had a mass appeal, it was simple to use, and most importantly it was based on freedom of choice. Let the user decide what to do. The Mind Shield was designed to mold the user to its purposes — or rather, those of its masters. Mind Space is the promised future for those who enjoy the privileges of Mind Shield." (Page 217).
Science Fiction, Mind Control, America 2050's, Technology, Resistance Movement, Rival Product, Monopoly, Free Market, Restoration
This series speaks to me in so many ways. It deals with business, marketing, medical devices, manipulating the public into buying a product, regulatory concerns, bureaucracy, underdogs, good versus evil, gray areas, consumer psychology, etc. I get angry when Jaimeson-Cale uses underhanded (and at times) illegal business practices to make a sale of the Mind Shield. I root for the Limbic Freedom and the Alliance to shut down sales of the Mind Shield. I get nervous when Jaimeson-Cale has the upper hand. Moore is so adept at pulling me emotionally into the book on so many levels and yet, he doesn't answer all my questions. How much does the Mind Shield or the Limbic Freedom cost? How is there no health concern with the transmittal of information from the nanites in the brain to the monitoring database at jaimeson-Cale? Are there no side effects at all from either device?
Moore answered some of the questions in this second book that I had brought from reading the first book. He delves into the past of Jaimeson-Cale and how they developed the nanite technology and how they created their model of different versions unveiled every six years and ultimate plan of development. Moore introduces us to Adam True, an ingenious scientist with so much potential, he just had to develop a stunted philosophy (or is it?) about community and freedom. True's philosophy and his mindset on humanity and community are similar to the concept in the series Left Behind by Tim LaHaye and Jerry B. Jenkins. If you haven't converted, you get left behind. The difference between Left Behind and Adam True's vision of Mind Space is that no one will be left behind because anyone who has not chosen to get a Mind Shield would invariably be forced to have one or be killed.
Mind Space might seem like utopia, but anyone who is not currently hosting a Mind Shield would think differently. I envision Mind Space as a great connection between all Mind Shields, except that individuality is censored and the collective consciousness is just the nice version of that collective conscious in Do Androids Dream of Electric Sheep by Philip K. Dick. Mind Space is like teeth in a comb, all the same parts of a whole instead of like pine cones on a tree, mostly similar but uniquely different. That sounds perfectly wretched to me, to be forced to think the same as everyone else. To Mind Shield hosts and Adam True followers, Mind Space is like Ragnarok, with a cult following ready for a specific day's event in the ever-nearing future.
Moore begins gearing up his characters for war. There has already been the terrorist attack at the end of book one and the underhanded sales techniques in book two. "Eventually the polite competition of products in the marketplace would be transformed into an all out war for the minds of the masses." (Page 392).
Hopefully Limbic Freedom can combat the Mind Shield, it monitors the same health conditions that versions 1 and 2 of the Mind Shield monitors and allows the user complete freedom of choice and control of thought. There is a key difference between the two devices, more than just the lack of mind control capabilities in the Limbic Freedom. Moore most likely has faith in humanity and I do not. Limbic Freedom requires configuration, learning, and training and Mind Shield does not. I'm assured that most people would rather the convenience of control than the inconvenience associated with the freedom of choice and thought. If it takes time to make the Limbic Freedom device capable of the same things as the Mind Shield, it won't appeal to a large portion of society. Isn't that why the Limbic Freedom was such a hit in the first place, because it treated obesity/overweightness by buffering the user from their own lack of willpower?
Moore throws short detailed scenes throughout the book, where the reader is presented a first-hand account of a character's experience with the Limbic Freedom or the Mind Shield. This was very Stephen Kingesque of him and I rather enjoyed the brief evidence each scene brought to my side of the fence, where both the Mind Shield and Jaimeson-Cale are evil.
A new depth is introduced in book two regarding the type of Mind Shields produced. There are levels of Mind Shields with levels of controls built in, as if they are directives for robots. Moore also connects the Mind Shield and its directives specifically to the Way of Truth, gearing up for the big finish in his next novel of the series, Mind Space.
Is it truly bad to be a sheep in society if there were no addictions, anxiety, depression, hate, envy, etc? Mahatma Ghandi said, "Freedom is not worth having if it does not include the freedom to make mistakes."
FreeValley Publishing Authors: Upcoming Live Event at Snoqualmie Days
September 4, 2014 by rachelauthorbarnard in At One's Beast, Ataxia and the Ravine of Lost Dreams, Author Thursdays, Free Valley Publishing, Local Authors, Local Events and tagged David Moore, Dawn of Steam, Jeffrey Cook, Kathleen Gabriel, Linda Garcia, Mind Space, Reflections on Water, Secret Order of the Overworld, Sheri J. Kennedy, Stars in the Texas Sky, Stephen Matlock, Sunrise Meets the Star, The Kansas Connection, the Reverent Atheist, Victoria Bastedo | 3 Comments
Remember that countdown timer on my blog? it's for this event! Come see FreeValley Publishing's booth and snag all those books you haven't read yet. Check out new books by Rachel Barnard (At One's Beast), Victoria Bastedo (Roots Entwine) and Jeffrey Cook (Dawn of Steam Gods of the Sun). For more information on FreeValley Publishing, check out their website here!
Authors will be available to meet you and to sign books. The event is at Center Blvd SE, Snoqualmie, WA from 10-5. Hope to see you there!
Aftermath of the North Bend Block Party This Past Saturday
July 23, 2014 by rachelauthorbarnard in Author Tuesdays, Free Valley Publishing, Local Authors, Local Events and tagged David Moore, Dawn of Steam, Jeffrey Cook, Kathleen Gabriel, Linda Garcia, Mind Space, North Bend Block Party, Secret Order of the Overworld, Sheri J. Kennedy, Stephen Matlock, Sunrise Meets the Star, T. Tommia Wright, The Kansas Connection, the Reverent Atheist, Thomas Alexander, Victoria Bastedo | 4 Comments
I always have fun at these local festivals and enjoy spending time chatting with my local author buddies. We had such great support from the FreeValley Publishing authors, see how many we stuffed back in our space? My favorite booth was ours of course! Second was two booths down with the fresh picked blueberries from Cle Elum.

redpajama_set_name: RedPajamaCommonCrawl


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104 // not be abused by third party extensions.
218 'locallangXMLOverride' => , // For extension/overriding of the arrays in 'locallang' files in frontend and backend. See 'Inside TYPO3' for more information.
273 // Static mapping for file extensions to mime types.
274 // In special cases the mime type is not detected correctly.
275 // Use this array only if the automatic detection does not work correct!
304 'nodeRegistry' => , // Array: Registry to add or overwrite FormEngine nodes. Main key is a timestamp of the date when an entry is added, sub keys type, priority and class are required. Class must implement TYPO3\CMS\Backend\Form\NodeInterface.
305 'nodeResolver' => , // Array: Additional node resolver. Main key is a timestamp of the date when an entry is added, sub keys type, priority and class are required. Class must implement TYPO3\CMS\Backend\Form\NodeResolverInterface.
884 // String (exclude). Enter lines of default backend user/group TSconfig.
978 // String (exclude).Enter lines of default Page TSconfig.
981 // The control of file extensions goes in two categories. Webspace and Ftpspace. Webspace is folders accessible from a webbrowser (below TYPO3_DOCUMENT_ROOT) and ftpspace is everything else.
982 // The control is done like this: If an extension matches 'allow' then the check returns TRUE. If not and an extension matches 'deny' then the check return FALSE. If no match at all, returns TRUE.
989 'customPermOptions' => , // Array with sets of custom permission options. Syntax is; 'key' => array('header' => 'header string, language split', 'items' => array('key' => array('label, language split','icon reference', 'Description text, language split'))). Keys cannot contain ":|," characters.
1004 'FE' => [ // Configuration for the TypoScript frontend (FE). Nothing here relates to the administration backend!
1059 'MAIL' => [ // Mail configurations to tune how \TYPO3\CMS\Core\Mail\ classes will send their mails.
1070 'HTTP' => [ // HTTP configuration to tune how TYPO3 behaves on HTTP requests made by TYPO3. Have a look at http://docs.guzzlephp.org/en/latest/request-options.html for some background information on those settings.
1072 'max' => 5, // Integer: Maximum number of tries before an exception is thrown.
1073 'strict' => false // Boolean: Whether to keep request method on redirects via status 301 and 302 (TRUE, needed for compatibility with RFC 2616) or switch to GET (FALSE, needed for compatibility with most browsers).
1082 'headers' => [ // Additional HTTP headers sent by every request TYPO3 executes.
1083 'User-Agent' => 'TYPO3' // String: Default user agent. Defaults to TYPO3.
1110 'SC_OPTIONS' => [ // Here you can more or less freely define additional configuration for scripts in TYPO3. Of course the features supported depends on the script. See documentation "Inside TYPO3" for examples. Keys in the array are the relative path of a script (for output scripts it should be the "script ID" as found in a comment in the HTML header ) and values can then be anything that scripts wants to define for itself. The key "GLOBAL" is reserved.


Denise has been working in the property tax consulting industry for over twenty years. Seventeen years ago she began Accurate Tax Management. She is a Level III Certified Indiana Assessor-Appraiser and a Certified Tax Representative.
They work on a contingency fee basis so no one pays them anything unless they are able to save them money. All reviews, the filing of appeals and representation at all hearings is at no charge until a positive result has been reached.
Specialties: reducing real estate taxes for commercial buildings, fixed asset reviews for companies, training, speaking.


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Jim Carrey calls lawsuit over ex-girlfriend's death 'heartless'
By Rob Mackay
LOS ANGELES (AP) — Jim Carrey says a wrongful death lawsuit filed by the husband of his ex-girlfriend is a "heartless" attempt to exploit him.
Mark Burton sued Carrey in Los Angeles Superior Court on Monday, accusing the actor of providing the prescription drugs Cathriona White used to overdose in September 2015. The wrongful death lawsuit contends Carrey improperly obtained prescriptions for Ambien and the powerful opioid oxycodone under the alias Arthur King.
Carrey wrote in a statement that he loved White and said the suit was an attempt to profit from her death.
"What a terrible shame," Carrey said in his statement. "It would be easy for me to get in a back room with this man's lawyer and make this go away, but there are some moments in life when you have to stand up and defend your honor against the evil in this world.
"I will not tolerate this heartless attempt to exploit me or the woman I loved. Cat's troubles were born long before I met her and sadly her tragic end was beyond anyone's control. I really hope that some day soon people will stop trying to profit from this and let her rest in peace."
The suit accuses Carrey of giving White the medications days before she was found dead in one of Carrey's homes. White and Carrey dated in 2012 and were photographed together in May 2015.
Coroner's officials later ruled the 30-year-old makeup artist's death a suicide.
Burton and White married in 2013.


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Home>Business>10 Best Window Brands of 2023
10 Best Window Brands of 2023
December 2, 2022 January 16, 2023 PB TeamLeave a Comment on 10 Best Window Brands of 2023
Your windows do more than maintain a comfortable temperature in your home; they also add aesthetic value to your house. Balancing functionality, aesthetics, and budget, however, can be tricky. Fortunately, we've researched for you and compiled ten window brands that insulate your home, look great, and won't break the bank!
1. Milgard Windows
Popular among homeowners for the quality of their customer support, Milgard Windows offer durable, low-maintenance window options. Milgard windows run the gamut regarding price, with options from $385 to over one-thousand dollars per window.
2. Castle Windows
Castle windows are known for their premium lifetime warranty and offer energy-efficient window options with a no-nonsense sales approach, pricing ranges from $200 to $900 per window.
3. Champion Windows
Champion windows are known for its sunroom window installation and offer quality windows and reliable service. Champion windows are not the cheapest option, running from $400 to $700 per window, but their products are high quality.
4. Marvin Windows
Marvin Windows is famed for its skylight installations, available in fifty states, and offers Energy-Star-certified products. Marvin Windows vary quite a bit in cost and range from $250 to $800 per window.
5. Andersen
Loved by customers for their white-glove service, Andersen windows are one of the few companies to offer a transferable limited warranty. Andersen windows are not the most affordable on our list, however, at between $680 and $2,700 per window – in fact, they are the most expensive by a couple of hundred dollars!
6. Pella Windows
Most recognized for its energy-efficient products, Pella Windows is best known for its insistence on using Cardinal glass. Pella offers windows to fit virtually every budget, from $450 to $1,200 per window.
7. Harvey Windows and Doors
Praised by customers for the durability of their products, Harvey Windows and Doors is a preferred window installer for those looking for middle-of-the-road window options. Harvey Windows and Doors cost anywhere from $250 to $2,800 per window.
8. Ply Gem
Preferred by customers looking for budget windows with discounts of up to 33% over competitors, Ply Gem offers friendly and prompt customer service. Ply Gem windows cost anywhere from $200 to $2,000 per window.
9. Jeld-Wen
Jeld-Wen windows is a reputable company known for giving their customers an incredible experience and is frequently utilized by builders and contractors. Jeld-Wen windows range in price from $200 to $500 per window.
10. Simonton Windows
Simonton windows are known for their ease of availability and are popular among DIYers looking to do their own installation. These windows are available in ten different styles and are sold at big box stores. Simonton windows cost anywhere from $280 to $1,500 per window.
If you are looking for efficient home windows that add to your home façade but won't cost a small fortune, we recommend: Milgard, Castle, Champion, Marvin, Anderson, Pella, Harvey, Ply Gem, and Simonton. Just remember to hire a reputable installation professional to get the most out of your new window purchase!
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If being able to see your breath was ever an excuse not to ride, no one's ever tried to use it on Castelli. The Castelli Zoncolan Jacket gives you a tangible advantage over Mother Nature. As tough as the legendary Italian climb, the Zoncolan is windproof, water-resistant, and warming in temperatures as low as 0/-10degrees (C). The Zoncolan is an excuse-killer of a jacket that leaves no reason to avoid putting in your base miles.
Castelli's Zoncolan Jacket is made from the legendary Windstopper X-Fast 2 fabric. Both windproof and water-resistant, this W.L. Gore fabric is also highly breathable -- providing dependable warmth in frigid conditions without making you a sweaty mess. For extra protection on wicked winter descents, Castelli added a flip-up, fleece-lined Thermoflex collar to keep the wind from biting your chest and neck. The Zoncolan also features three external back pockets for your portables, and has an elastic band to keep the jacket from riding up. The Zoncolan is the go anywhere, do anything jacket for winter.


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Now Available on Kindle, Amazon.com & CreateSpace E-Store!!
We are proud to announce the release of our book, "Active Defense". We have put together information that supports the ever growing need for protection in our churches. Lighthouse Investigations has partnered with Manis Tactical Systems to provide all aspects of protection training, from background screenings to the personal protection techniques you will need if you are ever faced with violence. Lighthouse Investigations is available to speak to your church, school, or business about the exciting things we offer. It's a great opportunity to get answers to questions you may have about getting started. Active Defense is available on Kindle, Amazon.com and CreateSpace e-store. Call us today to schedule a time to meet with us personally at (405) 387-9480.
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Lighthouse Investigations is a full service private investigations agency. Lighthouse excels in providing in-depth expertise in all investigative areas. We have "online" data based information systems to expedite information retrievals, background screenings, locating people, and assets. We take great pride in keeping our investigations strictly confidential and secure, keeping our clients updated throughout its course. You need investigators who are experienced, dependable, trustworthy, and efficient. Investigations can be complicated and even dangerous. Trust seasoned professionals when you want the job done right.


An author of a new study associating the hypnotic zolpidem (Ambien) with higher rates of patient falls says hospitalists should keep the popular drug's risks front of mind.
The retrospective cohort study in the Journal of Hospital Medicine, "Zolpidem is Independently Associated with Increased Risk of Inpatient Falls," found that the rate of falls increased nearly six times among patients taking the sleep agent. The research team at the Center for Sleep Medicine at the Mayo Clinic in Rochester, N.Y., calculated one additional fall for every 55 admitted patients who were administered the treatment.
Dr. Morgenthaler says zolpidem is the most commonly prescribed hypnotic at his hospital, and believes it to be the most common treatment in the U.S. He began studying the issue after nurses reported that it appeared patients were falling after taking the agent. In response to the study, Mayo Clinic removed zolpidem from many of its admission order sets and attempted to help improve patient sleep via other methods, including noise reduction.
Visit our website for more information about HM's approach to patient falls.


The 1 troy oz gold hei matau coin is New Zealand Post's first-ever 0.9999 gold coin, as well as the world's first coin issue to have pounamu (New Zealand greenstone) set into the design.
The hei matau depicted on the 2012 Māori Art coin was hand-carved by renowned Rotorua Māori artist, Lewis Gardiner. The piece was especially commissioned for the 60 cent stamp in New Zealand Post's 2011 Matariki stamp issue, and represents an outstanding example of modern hei matau design.
The significance of the hei matau and its associations with navigation, abundance of seafood, mana and knowledge are reflected in the themes of the coin design. The raised pattern on the coin behind the hei matau is based on a traditional Māori kōwhaiwhai (frieze) pattern called 'koiri' (to sway/bend) combined with the traditional whakairo (woodcarving) pattern unaunahi (fish scales).
Koiri suggests the swaying of seaweed and the changeable nature of the wind, while unaunahi suggests the movement of shoals of fish. The combination of designs gives rise to the image of a fishing waka (canoe) traversing the ocean's waves and currents.
Set to the right of the hei matau is a round cabochon of pounamu. Pounamu is a taonga (treasure) held in high esteem by Māori, and the export of pounamu from New Zealand is restricted. The pounamu cabochon is symbolic of the moon, which governs the rise and fall of the tides in the realm of Tangaroa (god of the sea). The notches on the edge of the coin, some say, are the oldest type of carving recorded. The groups of two notches represent strength and abundance, while the groups of three notches refer to three stages of creation (epochs of time): Te Kore (the nothingness), Te Pō (the darkness) and Te Ao Mārama (the world of light).
For the first time, these New Zealand legal tender coins feature the face value of the coin in both English and Te Reo Māori (the Māori language).
The lid design of the waka huia continues the navigational theme of the coin in the form of a contemporary pattern called 'pai arahi' (fortuitous ocean journeys). On either side of the handle are three koru/pïtau (unfolding curls symbolically representing new growth/new beginnings). The handle on the lid represents the barb of Lewis Gardiner's hei matau rising out of the sea, while the two notches on the barbs symbolise strength and abundance.


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Home › Business › UK and World
PZ Cussons boss to leave as profit dips in tough six months
The company said it had been hit by poor conditions on Britain's high streets.
PZ Cussons's products include the St Tropez tanning range (PZ Cussons/PA)
By August Graham, PA City Reporter
PZ Cussons is to part with its long-serving chief executive after warning that profit and revenue fell in the first half of the financial year.
https://www.belfasttelegraph.co.uk/business/uk-world/pz-cussons-boss-to-leave-as-profit-dips-in-tough-six-months-38777510.html
https://www.belfasttelegraph.co.uk/business/uk-world/08a6b/38777509.ece/AUTOCROP/h342/bpanews_de468d0a-a696-4346-8ce0-e6c5d8bcae8a_1
Alex Kanellis will step down from his role at the Imperial Leather maker at the end of January, after 13 years in charge.
His retirement will come just days after the company is due to present its results for the six months to the end of November.
I am proud to have worked with so many fantastic people across the business over many years Alex Kanellis, chief executive, PZ Cussons
In a trading update on Thursday, management warned that challenging market conditions in some of the company's key areas have pushed revenue and operating profit lower in the first half.
It came in a period when PZ Cussons sold its Greek and Polish businesses in an attempt to streamline operations.
But challenges on the UK high street "adversely impacted overall revenue and profit", it said.
The next six months are expected to be better, unless economic conditions worsen.
However, "full-year revenue and adjusted profit before tax is expected to be modestly below the prior year on a like-for-like basis", the company said.
Mr Kanellis said: "I am proud to have worked with so many fantastic people across the business over many years.
"The company has a stable of great brands and enjoys strong long-term relationships with partners across all regions."
By Holly Williams, PA Deputy City Editor London's FTSE 100 Index finished in the red as worries over the spread of a new coronavirus in China sent global stock markets lower.
Aviva chairman steps down amid major overhaul
By August Graham, PA City Reporter The chairman of Aviva will make room for new blood at the top as the business embarks on a major plan to cut costs.
Eve Sleep breaks even after shares nightmare
By August Graham, PA City Reporter Investors in Eve Sleep have given the company a vote of confidence, sending shares soaring as it said it could continue to break even in 2020, after balancing its books for the first time.
Joules blames Black Friday timing for first-half hit
By Holly Williams, PA Deputy City Editor British retailer Joules has revealed a half-year hit due to the timing of Black Friday, less than two weeks after poor Christmas trading saw it warn over annual profits.
Hovis strike could cause disruption to supply of bread in Northern Ireland Northern Ireland
Approval granted for £250k 20-pod glamping site outside Belfast Northern Ireland
Naturelle's £4m expansion in Tyrone to create 50 jobs Northern Ireland
DUP man slams Tory over Belfast City Airport closure claims Northern Ireland
Finance Minister Murphy rules out corporation tax cut in Northern Ireland Northern Ireland


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There is an absolutely fab choice of flowers in the summer months; and if you are a summer couple you really will be spoilt for choice! Although, sometimes couples can get overwhelmed with the choice available; not only with the quantity and variety of flowers but with the choice of colours also. Colour has such a huge impact on the overall feel of a wedding.
Colour inspiration is everywhere. From nature to interiors to catwalk fashion which often feeds through into the wedding world. As a general rule the colours chosen for a wedding are generally dictated by the choice of bridesmaids' dresses. The colour palette should complement the venue; it should also add to the beauty of the space rather than fight for attention. If your wedding reception is being held in a marquee or a warehouse, this is an ideal backdrop for a bolder colour palette; the good thing about blush pinks is that a pastel colour can suit almost any style venue from modern to vintage.
A BLUSH pink wedding theme is one of the most popular colour schemes in 2017; brides and grooms adore it, because blush is romantic, feminine and can match with any themed wedding; bohemian, modern or even rustic. Blush pink wedding gowns are also big news in recent months, particularly dresses with flower embroidery! This style of wedding dress is completely romantic and is a perfect choice for a feminine bride who wants to embrace the pink colour palette.
So the flowers! Where does one begin in choosing all the amazing pretty pink flowers there are? Well, the first step is to visit your wedding florist who can show you examples of their wedding work with hopefully examples of pink floral designs with mixes of complementary colours to enhance; and talk through the different colour palettes that can be used for a pink wedding. Pink peonies 'Sarah Bernhardt' or 'Sweet Avalanche' roses are a must-have when it comes to the wedding flowers, depending of course when you're getting married, peonies are seasonal and are available around March/April up to early-mid July.
Other flowers worth considering are the upright, soft, feathery and romantic astilbe (also known as False Goats Beard) – available between June and November – of which there are a couple of good varieties of pinks available 'Erika' and the more blush pink 'Europa'.
Another very popular choice with brides are the fabulous David Austin roses; the popular blush/light pink varieties include 'Kiera' and 'Rosalind'. The really great thing about these roses is they look very similar to peonies with their frilly petals, so for brides getting married outside the peony season they are the perfect choice! The incredible scent is worth the price of these more expensive than usual roses, as commercial roses tend not to be fragrant. Sometimes, if budget does not allow for these throughout the entire wedding.
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Callum, Toronto Blue Jays April 4, 2014 April 8, 2017
The Toronto Blue Jays' first home opener: as told by the late Doug Ault
by Callum Hughson
The first Toronto Blue Jays player to ever hit a home run, the late Doug Ault discusses the fickleness of Toronto fans and the pitfalls of having a loaner car to drive around the city:
Doug Ault was the Jays' rookie first-baseman and his two home runs helped to propel the Blue Jays to a 9-5 victory in their inaugural home game at Exhibition Stadium. Ault went on to hit 15 more home runs in his Major League career before playing in Japan, and finally the Mexican League. At the conclusion of his playing career, Ault managed the Blue Jays' AAA affiliate Syracuse Chiefs, winning the International League's manager of the year award in 1985. It was his first time managing a baseball team at any level.
The full story on the first Toronto Blue Jays home-opener can be found at 1:29 in the video below:
Images courtesy of the Toronto Public Library archives
Callum Hughson
Callum Hughson has written for Mopupduty.com since 2006. Follow Callum on Twitter, LinkedIn and Instagram
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There are people all over who love cycling and the ranks are growing all the time. People who are interested in cycling should take the time to consider that there are hazards involved, but if you take the proper measures you can cycle safely. Here are some great tips that will help you stay safe and enjoy your time on your bike.
The first thing you need to know to improve your cycling experience is the local laws regarding cycling. Be sure to obey all traffic laws. Avoid running red lights and stop signs. Cyclists have the right of way over motorists, it is still important to be respectful and follow rules. You are at a disadvantage on your bike so take care and motorists will show you the same respect.
In most places, riding on the sidewalk or against traffic is illegal. When you are riding down the street, be sure to keep as far right as possible. Be careful of curbs. You want to leave enough space between you and the curb that you don't accidentally hit it and wreck. There are exceptions to staying right, such as making a left turn, but always be sure to use proper hand signals.
If you are riding in traffic and they are proceeding as the same speed as you, it might be best to join in with them. This will make you more visible to them. No matter what you do, be sure that you avoid passing anyone on the right. Not only is this illegal, but it is dangerous. Motorists aren't used to having someone approach and pass on that side so they are less likely to see you.
Whenever you are out cycling, always be sure to wear bright colored clothing. This will make you more visible to motorists, especially at night. Also be sure that you wear a helmet. In the event of a collision or a wreck this will protect you from head injuries.
One of the best ways to make sure people notice you is to make eye contact with them. This way they are aware that you are a person and they need to be more cautious when you are passing. Making eye contact carries a lot of weight so make sure that you make eye contact with as many people as possible while staying safe and paying attention to the road.
When you are cycling in traffic, be sure to make moves that are predictable by motorists around you. People who weave around and make erratic movements are more likely to be in an accident because motorists are not sure what to expect. Never ever leave the street for a moment and quickly return to it a few feet later and definitely do not weave through cars that are parked.
No matter what is going on, be sure that you keep at least one hand on your handlebars at all times. This is where the break and steering mechanism are located. If you remove your hands you are putting yourself at risk for in the event that something dangerous happens. Also be sure to keep your breaks in good condition, you never know when they can save your life.
Always keep your eyes peeled for potential obstacles when cycling. Know if a car is coming behind you and watch for hazards that may be in the road. Being aware of things makes you more prepared if one of them presents a problem that must be avoided.


The overall condition of 1's overall body and also the places the place pockets of Body fat have a tendency to build up are mainly based on genetics. For a lot of people, the bothersome flab that gathers inside the abdominal location may not be reflective in their genuine standard of exercise and Conditioning.
As said higher than, tummy tucks are usually not weight loss processes, Even though it's possible you'll look as though you may have missing an important amount of weight. next abdominoplasty, you could lose a negligible degree of excess weight With all the removing of excess skin.
if the abdominoplasty surgical procedures is comprehensive, the pores and skin is sutured alongside one another working with surgical stitches. Along with the stitches in position, the skin cells will coalesce at the location of incision, closing the wound Obviously as time passes. A surgical drain may also be inserted at the website of incision concurrently that the stitches are place into area. Surgical drains increase the therapeutic method and infrequently alleviate pain with the buildup of fluids beneath the pores and skin.
Completely! in truth, since moms that have experienced C-portion usually struggle with unfastened abdominal skin helpful hints and broken muscles, tummy tucks may be great treatment plans abdominoplasty for these Females.
prolonged tummy tucks entail the elimination of abdominoplasty 'appreciate handles' on both side of the waistline in addition to the removing of Fats and excess pores and skin through the belly space. The incision is normally minimal to ensure whether or not the scar extends behind the hips, it won't be noticeable, even if a single is carrying small-rise outfits.
Additionally, a leaner, much more competently operating body might help to circumvent fat acquire in the months adhering to medical procedures when patients will have to keep away from intense Actual physical exercise. eventually, as with diet regime, beginning an work out schedule establishes good behavior in order that patients can get pleasure from lengthy-lasting success immediately after their tummy tucks.
using a thigh elevate, a plastic surgeon can tighten and contour this spot through incisions about the groin or outer thigh. Following the operation, these incisions are often hidden less than outfits and swim fits.
The drainage tubes continue being in spot for a single week, and so are effortlessly eliminated at your very first write-up-operative check out. you're going to be proven how to take care of them at home.
they'll also will need to alter their bandages quite a few moments a day. Most surgeons also suggest their sufferers to don a compression garment all around their stomachs. Compression stockings can also support abdominoplasty to attenuate the risk of blood clots in the course of the sedentary Restoration time.
Some Medical practitioners schedule the very first appointment months ahead of the process, while some much like the resource consultation as well as tummy tuck to abide by in near succession. Regardless of the timeline, pre-surgical consultations involve numerous factors.
In addition to abdominoplasty swelling and discomfort, it is typical for people to knowledge click here bruising inside the cure area. The bruising abdominoplasty usually fade in just two months of surgical procedure.
Hydration can be important. suitable hydration tends to make us feel better, speeds healing, and likewise helps prevent postoperative troubles. Surgery improves the want for fluids, so it is necessary to consume loads of liquids in the course of recovery.


Home » Mortgage Loan » FHA Loan – Upfront Mortgage Insurance and monthly premium for 5 years. Is this true?
FHA Loan – Upfront Mortgage Insurance and monthly premium for 5 years. Is this true?
I checked with my loan officer. For a FHA loan (over $ 500,000 in bay area, Califorina), there is a upfront mortgage insurance (about 1.5 to 1.75%) that can be mortgaged and monthly premium for 5 years ($ 150.00 to $ 200.00) irrespective of how much down you put. Is this true? So even if you put 20% down (or even more) you have to pay upfront MI and monthly MI for 5 years!!
What is a "PLUS Score" on CCT?
Have you had success self- negotiating your credit card debt?
mortgage loans do itake and equity or a second mortgage on a hous that is paid for.?
Can mortgage interest be deducted from AMT when loan is used to purchase rental property?
Do unpaid phone/utilities collections effect your credit score?
why are debt consolidation companies bad?
Once my car loan is paid off by next year, what will happen to my credit score or history?
should i put my extra money in my ROTH account or pay towards my mortgage principle?
how do you check your credit score with a star card, military?
How can I be appointed to sell insurance through another company?


Sunday just after 2pm Co. 50, Engine 46, and Riddle EMS were dispatched to US 1 Southbound for a vehicle fire. Engine 50 arrived to find a van well involved and went in service with a 1 3/4″ hose line. Crews from Engine 50, Squad 50, and Engine 46 were in service approximately 20 minutes extinguishing the vehicle fire and small brush fire. Thank you to Fred Mason for the photos.


In English the term epiphany indicates the manifestation of a supernatural or divine reality, a sudden intuitive leap of understanding, especially through a visible ordinary yet striking occurrence. The term comes from the Greek epiphaneia, which means "manifestation" or "appearance".
In the Anglican, Eastern, and Roman Catholic Churches the Epiphany is also a traditional feast held on 6 January, celebrating the divine manifestation of Jesus Christ to the three Magician-Astrologer-Shaman Kings, who brought the gifts of gold, frankincense and myrrh. In the United Kingdom the monarch still commemorates the day by offering gold, frankincense and myrrh at the altar in the Chapel Royal at St James's Palace in London.
The Epiphany exemplifies the alignment of the Three Magi, representing the height of human wisdom, spirituality and power, with our higher multidimensional nature, as represented by the Christ.
The Epiphany occurs 12 days after Christmas, following the Twelfth Night (the eve of Epiphany), exemplifying the complete retrieval of the 12 strategic pieces of the soul, the signs of the zodiac, and their alignment with multidimensional self.
Besides the adoration of the three Kings, the Epiphany also commemorates two additional events: the Baptism of Christ and the wedding in Cana, at which Jesus manifested his first miracle, the transformation of water into wine. All these episodes are related with the initiation into the multidimensional power of manifestation and are associated with similar events described in other traditions.
Epiphany is also an esoteric Gnostic ritual of the feminine. It is documented that the Gnostics celebrated it in the sanctuary of Kore, the Maiden goddess, who they equated to the Holy Virgin. They said that on the day of the Epiphany the feminine consciousness of the Virgin gave birth to the messianic power of the Christ.
The Epiphany was once the original date of birth of the Christ and is still celebrated as such by the Eastern Christian Church. This second birth of the Christ esoterically relates with his multidimensional body and is associated with the Baptism, which is the exemplification of multidimensional birth, as opposed to physical birth.
The Epiphany is a festival of most ancient origin and is meant to indicate the alignment between physical third-dimensional and multidimensional reality. It is connected with the first stage of intention, the phase when we stretch into the multidimensional realm, connecting with tour higher self and catching a glimpse of our true nature with all its potentials fully accomplished. It is the experience of the apex of power, which is then either grounded in our life or vanished as a passing dream.
The first stage of the intention is an epiphany, an ecstatic experience with potential effects in our physical human and ordinary reality. Ordinary reality is a separated hallucinatory reality, based on the denial of other dimensions. Although it operates to strictly preserve the separation, its illusory structure has gaps which cannot totally prevent the multidimensional from manifesting, at least from time to time.
These manifestations have only provisional tangible effects, since when consensus reality becomes aware of multidimensional interferences, it immediately annihilates them, amputating their perception from human awareness and memory. The first stage of intention setting involves acknowledging the epiphany related to an intention and preserving its power despite the censorships of ordinary reality.
The epiphany of the intent may be the result of a great inspiration and insight over your potential and something that you deeply wish. It may be the development of a vision achieved during a shamanic journey, a trance experience, a dream or an ecstatic state of consciousness. It can also emerge from an event occurred in everyday reality, when you see in other people or situations a perfect model of what you are, or you may experience it directly in your ordinary life, becoming aware of an unknown potential, as you express it, and receiving unexpected recognition from others.
Whatever the case during an epiphany there is a strong inner resonance so that you say or feel something like: "Yes! This is my intent! This is what I am! This is what I want to be!" In the first stage of the intention there is a strong sense of power and feeling supported. It is an epiphany, the experiential and tangible awareness of a multidimensional reality.
The second stage brings about a radical shift in perception for it involves having the epiphany coming to terms with the ordinary reality. The second stage occurs once the honeymoon of the epiphany is over, i.e. when ordinary reality becomes aware of the multidimensional interference and tends to block it. This stage entails confronting a setting where the intention is not manifested yet and I need to get down to work if I do aim at implementing it.
The time of the epiphany is apparently over. It belongs to the past, which according to ordinary reality is gone. Hence after the epiphany I may not feel the same resonance, trust and intensity I experienced in the first stage. I may also feel depressed, disillusioned and fearful, believing that the epiphany was merely an illusion.
Falling into this pitfall is typical for most folks on the multidimensional path. There is no way I can avoid it unless I understand the basic difference between ordinary and non-ordinary, third-dimensional reality and multidimensional realms.
Our ordinary reality is a linear setting based on a single frequency of time where beings move in strict conformity with a given speed, which is measured by our ordinary watches. The movement cannot be accelerated or slowed down and only proceeds in one direction with no reverse gear.
Ordinary reality is therefore fixed in a time-space line with no possibility of venturing elsewhere. On the other hand whatever is beyond the third dimension contemplates movement through time, which means that I can move into the past or future at will. It follows that if I have an experience of epiphany on 6 January, I can return to that experience also on 17 January and any other possible time, if I decide to do so.
The reawakening of our multidimensional nature implies the retrieval of our capacity to live through time, which means becoming aware that the epiphany I once had continues to exist somewhere even if it is not apparently happening in my ordinary perception of time. This capacity is not gained overnight. It involves a gradual stretching of our dormant multidimensional nature and the exercise of our faculties of memory and imagination, which hold the key to the retrieval of our power of epiphany.
The brain does not know the difference between what it sees in the ordinary environment and what it remembers from the past or anticipates about the future. It merely processes information contained in neuronets, which are the linking devices of our nerve cells (neurons).
All our human thoughts and feelings are built up in neuronets. Ordinary reality controls the basic setting of neuronets determining what is real and not real. The epiphany process aims at bombarding this setting allowing emergence of alternative configurations and free viability through other time-space frequencies.
Happy Epiphany! Up with the Three Kings!


Numbers will be handed out starting at 7:00 am the morning of the first day, for those who want to guarantee a place in line for entering the sale at opening time.
This sale offers 6,600 sq. ft. of beautiful, uncommon and highly collectible, antique and contemporary decorative furniture and accessories, china, glass, art, textiles, jewelry, silver and more!
Here is a sampling of what we'll have for you - more photos to be published as we we're preparing the sale.
Grandfather's clock by A. Stowell Clock Co., Boston . . . and much more!
Custom made pool table by Delmo Billiards Mfg. Co.
A large variety of antique, vintage and contemporary linen and textiles - all in unbelievable condition!
. . . and SO MUCH MORE . . .
. . . additional photos will be posted in the days to come. Check back regularly and prepare yourself for a very unique sale, definitely not to be missed!


The UK Government is undergoing a digital Transformation and Microsoft Office 365 is a popular platform for UK Public Sector Organisations looking to modernise, with its revolutionary cloud services. However, security concerns still remain barriers to adoption to the state of the art services for some public sector IT buyers. Trend Micro's white paper looks at what is driving organisations to enhance this environment with additional security layers, sandboxing for zero-day malware and advanced compliance controls.
Let Trend Micro shed more light on Office 365 security: where Microsoft helps out, useful guidance from the National Cyber Security Centre (NCSC), and where third-party experts like Trend Micro can be brought in to enhance protection.
Trend Micro incorporated is a pioneer in secure content and threat management. Trend Micro has been a Microsoft Gold Partner for 20 years and bring extensive experience in protecting on-premises email and collaboration systems to the cloud. Trend Micro™ Cloud App Security™ integrates with Office 365 and other cloud sharing environments to bring you state of the art threat and data protection.
SBL is a cybersecurity specialist and a Trend Micro Gold Partner.
Together, SBL and Trend Micro are proud to be the Presidential Partner of Socitm for 2018, which provides us with the opportunity to showcase our experience and expertise within Local Authorities and the wider UK Public Sector. Our dedicated Local Government team are committed to understanding and helping to address the challenges faced by IT departments in this sector. Working in collaboration with the Local Government Team, SBL have a dedicated Microsoft business team who can offer exceptional advice on Microsoft technology, as well as the often complex licensing options. Alongside this advice we offer a number of professional services to support our customers with all Microsoft technology.
SBL is a vendor independent, enterprise level specialist in the supply of security and software solutions, hardware and professional services including training and consultancy.
Since 1987 SBL has worked in partnership with customers to understand their priorities and to help them achieve their goals. Our services portfolio is continuously optimised to support customers with objectives such as information security, compliance, efficiency and cloud migration.
As cyber security specialists, we work closely with academia, government, vendors and customers to understand how the IT landscape and our engagement with technology is evolving. Our customers can trust us with tomorrow.


The city's utility billing has been divided into two cycles. Cycle 1 is billed on the 10th of the month and it includes all residents and businesses located west of Jefferson Avenue. Cycle 2 is billed on the 23rd of the month and it includes all residents and businesses located east of Jefferson Avenue.
Payment not received on the due date will be assessed a 10% penalty on the balance owed. If payment is not received within approximately 15 days after the penalty date, service will be disconnected.
The day before disconnection, the city will make a courtesy call to the phone number on the account, giving the date of disconnection and amount owed. The past due amount must be paid before 9:00 a.m. on the disconnection day to avoid disruption of service. Customers are allowed two (2) extensions per year.
At 9:00 a.m. on disconnection day, there will be an additional $30.00 reconnection fee to have service reinstated during normal hours of operation. Any reconnections made after normal hours, on city holidays or weekends will require a $50.00 call out fee to be paid along with the outstanding balance by the conclusion of the next normal business day.
The city offers electronic bank drafting service for monthly utility bill payments. This can be arranged with no additional costs. Customers wishing to pay by bank draft will continue to receive a bill in the mail.The bill will state: Bank Draft-Do Not Pay, the account will be drafted on the due date.
Customers wishing to pay by bank draft must come by the office and complete a bank draft authorization form that must have attached a voided check. The form may be downloaded, but must be returned to the utility billing department in person or by mail.
Customers may also set this on a credit/debit card draft online by logging onto the City's online bill pay system.
The city also receives payments of utility bills by credit card or debit cards (Mastercard, Visa, Discover, Amex). This can be paid in person at the water office. Customers may also pay on the city website or by phone.


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The data we collect helps us determine crop yields, soil fertility, time to maturity for various crops, total yield of the garden, and other garden performance parameters. Our record keeping also helps us manage the process of improving the fertility of each bed, and supports our efforts to manage the use of our planting space efficiently.
What's planted, when, and how many square feet of it went in.
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Send an e-mail to Jeff.
Post a description to the Garden Blog.
Add data to the on-line Activity Log file.
Thanks for helping us collect the data that we need to manage the garden.


text:
Identifying the Structure of an Unknown Impurity in a Topical Gel
Richard Durham, Jerry Neal, Jerry Mizell, Matt Casteen
Pharmaceutical Technology, Pharmaceutical Technology-04-02-2020, Volume 44, Issue 4
This case study highlights analytical instrumentation and techniques that were used to identify an unknown impurity detected during routine release testing of a topical gel drug product.
It is not uncommon for pharmaceutical analytical chemists to observe unknown impurities during routine drug product testing using general chromatographic methods such as high-pressure liquid chromatography/ultraviolet or gas chromatography/flame ionization detection. Discovery of an unknown impurity triggers an investigation, along with a shift in priorities from routine to more specific specialized testing in order to be able to answer key questions about the impurity. This case study highlights analytical instrumentation and techniques that were used to identify an unknown impurity detected during routine release testing of a topical gel drug product.
Impurities in pharmaceutical products are defined as "substances in the product that are not part of the API itself or the excipients that are used to manufacture the drug product" (1). These impurities are unwanted chemical entities that remain with the API or finished drug product and may develop during manufacturing or upon storage.
An impurity can be inorganic or organic. In some cases, impurities can be residual traces of solvents that are used in synthesis or manufacturing. During routine drug product testing using general chromatographic methods such as high-pressure liquid chromatography/ultraviolet (HPLC/UV) or gas chromatography/flame ionization detection (GC/FID), discovering an unknown impurity triggers investigations and specialized testing in order to answer several basic questions about the unknown, including:
Is it toxic?
How much of it is present?
Where is it coming from?
Answering these questions can be difficult without access to specialized instrumentation and analytical techniques that can provide structural information about the unknown, allowing a useful toxicological assessment to be made.
Classifying impurities
The impurity may be classified either as a degradation product resulting from chemical reaction of the API during manufacturing and storage, or as a foreign substance that was introduced into the product by contamination or adulteration. Classification of impurities permits the development of adequate control measures to minimize unwanted impurities in the final product. It is important to note that the presence of an impurity, in and of itself, is not necessarily problematic. The introduction of trace levels of impurities is inevitable during the manufacturing or storage of pharmaceutical products.
In fact, scientists expect impurities to be present, hence the requirement that any and all of them be identified and controlled and their presence and concentrations monitored. In many cases, the presence of an impurity may not pose any safety, quality, or efficacy issues for the drug product. In theory, however, the presence of any impurity could influence the efficacy and safety of the finished product. At the very least, impurities confer no therapeutic benefit. In the worst case, they can be toxic. Several authorities, including the International Council for Harmonization (ICH) and FDA, regulate impurity levels in all pharmaceutical products.
Ensuring the purity of an API or finished drug product requires identifying, quantifying, and controlling any impurity once it has been observed. An impurity can be controlled by establishing appropriate control methods at all points where they enter or form during the manufacturing process. According to ICH guidelines on impurities in new drug substances and new drug products (1), identification of impurities below the 0.1% level is not necessary unless the potential impurities are expected to be unusually potent or toxic.
This case study used the following analytical instrumentation and techniques to identify an unknown impurity that was detected during routine release testing of a topical gel drug product. The impurity was detected by a validated HPLC/UV method with a known impurity profile (Table I) and was out of specification for the product. The following analytical methods were used:
Liquid chromatography–mass spectrometry/quadrupole time-of-flight (LC/MS/Q-TOF)
Gas chromatography mass spectrometry / electron impact mass spectrometry (GC/MS EI/MS)
Fraction collection
Infrared spectroscopy.
After detecting an unknown impurity during routine release testing, a pharmaceutical company requested that investigational testing be performed on its topical gel drug product to identify the impurity and determine whether it was an API degradation product, a process impurity, or a contaminant that had been introduced during the manufacturing process.
The HPLC/UV chromatographic impurity profile of the topical gel release lot is shown in Figure 1. When comparing the known impurity profile (Table I) to the HPLC/UV chromatogram (Figure 1), scientists observed that a single unknown impurity eluted past Impurity 11 (55.7 min.) at approximately 71 minutes. Other chromatographic peaks that were observed eluting after the unknown itself were considered evidence of impurities from solvents that were used to prepare the sample for HPLC testing and considered to be blank-related.
Outlining the process
One of the most challenging problems encountered is the identification of unknowns at trace levels in pharmaceutical drug products. This is due mainly to the significant differences in detection limits for each analytical technique that is used to confirm unknown impurities. In this case, the first step in identifying the unknown impurity was testing the drug product by LC/MS using Q-TOF detection. This method provides key information about the identity of the unknown by generating highly accurate mass data. Having highly accurate mass information for the unknown significantly reduces the number of possible molecular formulas or compound identities generated by the molecular formula software.
While this testing provides key information about the unknown, it does not always provide positive identification of the unknown, because hundreds of compounds may share the same molecular formula. Additional experimental data are needed to rule out other compounds and eventually identify the unknown. With this impurity, the mass (M+1) of the unknown was determined to be 447.3476 from Q-TOF LC/MS experiments (Figure 2).
Using the unknown's accurate mass information and the molecular formula generator, the unknown was determined to have the molecular formula C28H46O4. The exact mass calculation for the molecular formula was 446.3396.
Using the exact mass from the Q-TOF LC/MS experiments and the molecular formula, scientists performed a National Institute of Standards and Technology (NIST) database search and identified a total of 88 potentially matching species within the database, with the top search result being diisodecyl phthalate (DIDP) (2).
Knowing the impurity's exact mass and having a molecular formula from the LC/MS data is invaluable in helping narrow down its identity from hundreds of potential compounds with the same molecular formula. Other analytical techniques must then be used to rule out or confirm the impurity's structural identity.
One disadvantage of using LC/MS data is that database libraries with searchable mass spectral data do not exist. However, extensive searchable database libraries are available for GC/MS testing. Thus, the next step in identifying the unknown was to test it by GC/MS. Obtaining electron impact (EI) mass spectra of the unknown would allow for positive identification with a database match.
The LC/MS Q-TOF experiments indicated that the unknown was potentially identifiable as diisodecyl phthalate, which is volatile and thermally stable enough to be detected by GC/MS. A potential problem associated with GC/MS testing, however, was the fact that, if the unknown proved not to be DIDP, it might not be sufficiently volatile to be detected by GC/MS.
In addition, if the unknown were not present at a high enough concentration, it would not be possible to obtain electron impact mass spectra of sufficient quality to search against the database library. To enhance the probability of performing a successful GC/MS run, scientists prepared a concentrated sample of the drug product to ensure that the impurity could be adequately detected, since the sensitivity of the various analytical techniques used to confirm identity can vary significantly.
Multiple injections of both dilute and concentrated sample were made onto an HPLC/UV system to generate a chromatographic profile similar to that in Figure 1. The HPLC eluent from multiple injections was collected for approximately one minute on either side of the expected retention time of the impurity. The fractions were combined and further concentrated at least 10,000-fold to ensure adequate sensitivity for detection. Injections of the concentrated solution were made on the GC/MS using the conditions outlined in Table II.
GC/MS results (Figure 3) confirmed that concentrated unknown electron impact (EI) mass spectra were consistent with the best database match for DIDP and the exact mass obtained by LC/MS Q-TOF experiments.Scientists used infrared spectroscopy to test the concentrated impurity, and the results further supported the probability of the unknown being DIDP.
Fourier Transform-Infra-Red (FT-IR) spectra of the unknown did not contain spectral elements that contradicted the mass spectroscopy data and were also consistent with NIST reference spectra of diisodecyl phthalate (Figure 4).
As a final confirmation, a known standard of DIDP was prepared as a marker at multiple concentrations to estimate the concentration of unknown observed in the sample. The DIDP markers, along with a sample preparation, were injected using the original HPLC/UV assay conditions (Figure 5).
Evaluation of all the experimental data collected from the investigational experiments demonstrated that the unknown impurity detected in the topical gel drug product during release testing was DIDP (Figure 3c).
It should be noted that commercially available DIDP actually is a mixture of two phthalates. The other component is diisononyl phthalate (DINP). DIDP is composed of a complex mixture of branched C9-C11 isomers containing mainly C10 isomers of C28H46O4. Significant amounts of toxicological data for DIDP are available for review (3).
DIDP is one of eight individual phthalate esters that the US Environmental Protection Agency (EPA) has deemed appropriate subjects for developing assessment and management strategies. It is the main plasticizer used for polymers in wire and cable applications. It also is used in anti-corrosion and anti-fouling paints, sealing compounds, and textile inks (4). Major identified sources of DIDP internationally include food and pharmaceutical packaging as well as printing inks (5). DIDP also is used as an additive in the production of plastics to make them more flexible.
In this case, the source of the impurity was not definitely determined; however, scientists believe it was unlikely to be a degradation product of the API, since the molecular weight of DIDP is higher than that of the API. Instead, the impurity was most likely a contaminant that resulted when the API or drug product came in contact with a source of plastic that was introduced during the manufacturing process. To date, no other batches of this drug product have contained this impurity.
1. ICH, Q3B(R2), Impurities in New Drug Products, 1-12, June 2, 2006.
2. NIST, Chemistry WebBook, NIST Standard Reference Database Number 69 (2017).
3. US Consumer Products Safety Commission (CPSC), Toxicity Review of Diisodecyl Phthalate (DIDP); 1-29, April 07, 2010.
4. EPA, Phthalate Action Plan; 1-16, March 14, 2012.
5. The Minister of the Environment and the Minister of Health Canada, State of the Science Report (SOS), Long-chain Phthalate Esters DIDP and DUP; 1-144, August 2015.
When referring to this article, please cite J. Neal et al, "Identifying the Structure of an Unknown Impurity in a Topical Gel," Pharmaceutical Technology 44 (4) 2020.
Download Issue: Pharmaceutical Technology-04-02-2020
AnalyticsQuality Assurance/Quality ControlPeer-Reviewed ResearchManufacturing, Topical DrugsPharmaceutical Technology-04-02-2020
Agilent and Quest Diagnostics to Collaborate on Lung Cancer Diagnostic
Finding the Right System for Moving Pharmaceutical Machinery
Nova Biomedical Launches Cell Density and Viability Analyzer


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Q: What is a C++ equivalent for "Environment.MachineName" under linux? It is defined in .NET Framework to get the NETBIOS name of the local computer. Reference: http://msdn.microsoft.com/en-us/library/system.environment.machinename.aspx
If the solution is cross-platform it would be way better. :)

A: Use gethostname. Here is the documentation:
http://msdn.microsoft.com/en-us/library/ms738527%28VS.85%29.aspx

redpajama_set_name: RedPajamaStackExchange


text:
Q: Unit Test not running Angular4 I am trying to run unit test in Angular 4 using Chrome, There are some error thrown in the chrome console, no idea how to fix this issue, have looked at Google not much help found.
this is the error I am getting, If anybody have a solution will be highly appreciated.
thanks in advance.
Uncaught TypeError: fs.existsSync is not a function
    at :9876/_karma_webpack_/webpack:/node_modules/selenium-webdriver/lib/devmode.js:33
    at Object.<anonymous> (:9876/_karma_webpack_/webpack:/node_modules/selenium-webdriver/lib/devmode.js:34)
    at Object../node_modules/selenium-webdriver/lib/devmode.js (devmode.js:34)
    at __webpack_require__ (:9876/_karma_webpack_/webpack:/webpack/bootstrap 60e3023d24bd9e093b52:54)
    at Object.<anonymous> (:9876/_karma_webpack_/webpack:/node_modules/selenium-webdriver/lib/http.js:32)
    at Object../node_modules/selenium-webdriver/lib/http.js (http.js:567)
    at __webpack_require__ (:9876/_karma_webpack_/webpack:/webpack/bootstrap 60e3023d24bd9e093b52:54)
    at Object.<anonymous> (:9876/_karma_webpack_/webpack:/node_modules/selenium-webdriver/http/index.js:29)
    at Object../node_modules/selenium-webdriver/http/index.js (index.js:255)
    at __webpack_require__ (:9876/_karma_webpack_/webpack:/webpack/bootstrap 60e3023d24bd9e093b52:54)


text:
Man, 20, arrested on statutory rape warrant
FALMOUTH — Mashpee police arrested a 20-year-old local man Wednesday who was sought on two counts of statutory rape.
Devon Almeida-Paul was arrested at Best Buy Beverage in Mashpee. He was transferred to Falmouth, where the statutory rape case was being investigated, Falmouth police said.
A warrant was issued for the arrest of Almeida-Paul Wednesday. He also had outstanding warrants: one from Plymouth District Court and four from Falmouth including the two counts of statutory rape.
The other warrants were on charges of possession of marijuana and malicious damage to a motor vehicle.
Statutory rape is a felony in Massachusetts. The statutory rapes allegedly occurred in February and earlier this month, according to court records. Almeida-Paul pleaded not guilty yesterday in Falmouth District Court. Bail was set at $10,000.


Lady Alexandra MacIntyre has made up her mind. Having grown up in near poverty, she''s marrying for money-a lot of money-and she'll do anything to achieve her goal...even get herself caught in a compromising situation by her overprotective and smugly conventional-although achingly handsome-new stepbrother, Lord Evan Xavier.
Evan, the second son of the Earl of Brighton, considers Alexandra a genuine pain in his arse. She''s beautiful, yes, but also headstrong and lacking in social graces and respect for authority. Unfortunately, while his father and her mother are away on their wedding trip, she is his responsibility. When she announces her plan to travel to London, he has no choice but to go along as her protector.
love this collection and how the stories are based on characters through out the collection. left me wanting more.
I just never could feel a connection between the 2 lead characters.


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text:
Federation of Catholic Family Associations in Europe
Fafce in a nutshell
Fafce's Board
Family life & Work balance
Press Release | Rebuilding Europe Restarting from the Family
FAFCE Board Resolution
Mdina, Malta, International Day of the Family, 15 May 2019
The European Elections are a unique occasion for all families to make their voice heard and to affirm that the family is the first starting point for rebuilding relationships and community in Europe. For that reason, FAFCE ran the Vote for the Family Campaign, with a Manifesto titled "Stronger Families for Flourishing Societies", which has been proposed to the candidates to the European Elections. The names of the signatories are published from today on http://voteforfamily2019.eu.
Recalling its Board Resolution for a Demographic Spring (Vienna, 13 April 2018), asking to put the family at the centre of national policies, so that the demographic winter could become a demographic spring and to shape the future of Europe;
Recalling its 20th Anniversary Declaration - Families' are Europe's Treasure and building block for the future (Rome, 31 May 2017), calling on the Governments of the European States to promote and create family policies at the national level and promote family friendly EU policies, whilst respecting the principle of subsidiarity;
Considering that families should grow in awareness of being "protagonists" of what is known as "family politics" and to assume responsibility for transformation of the society (Apostolic Exhortation Familiaris Consortio 44, 22 November 1981);
Considering that the family capital is called to impregnate the economic, social and political relationships of the European continent (Speech of Pope Francis to FAFCE, 1st of June 2017);
Considering the COMECE Bishops' Statement in view of the 2019 European Elections(12 February 2019), stating that the issue of demography has to regain central stage. The subject concerns natality as well as ageing;
our Board, gathered in Malta, one of the very few European Countries still protecting the human dignity of pre-born children, invites with great hope all European families:
1. To check the names of the candidates who signed the FAFCE manifesto who have committed themselves to systematically recognize the fundamental role of the family as the basic unit of society and its importance in the development of children.
2. To make their voice heard during the upcoming European Elections and to vote in their respective Countries in accordance to their well-formed conscience.
3. To make it their own responsibility to become actors of the family policy locally, by taking part in family associations and by raising awareness about the demographic Spring at all levels.
4. To be protagonists of innovative family policies, considering the family as the generative nucleus which gives life to all sectors of the society, in relation to education, economy and employment.
5. To make their contribution to the European public debate, reminding that the only society capable of a future is the one which respects the human dignity of the person and the family, which takes care of the poor and of the environment.
Mail : FAFCE Federation of Catholic Family Associations in Europe
Email : please use our contact form
Couldn't find list with id : 1a824e626a
The Federation of Catholic Family Associations, FAFCE, is acknowledged by the Council of Europe as a Non‐Governmental Organisation with a participatory status. It represents family interests in the political arena from a catholic perspective, on the basis of the Catholic Church's Social and Family teaching as well as on the testimony of faith and experimental knowledge of Christians in Church and society.