text:
Substituent Effects on Cyclopropylcarbinyl Solvolysis Rates. Evidence
Preferential formation of a symmetrical rather than an unsymmetrical cyclopropylcarbinyl cation. Vicinal vs. transannular hydride shift in the tricycl...
Cyclopropylcarbinyl 3,5-dinitrobenzoate solvolysis. 1-Ring substituent
Substituent effects on cyclobutyl and cyclopropylcarbinyl cations
Transmission of substituent effects in heterocycles. Rates of solvolysis
Correlation of the Rates of Solvolysis of Cyclopropylcarbinyl and
Substituent Effects on Thermal Decolorization Rates of
Cyclopropylcarbinyl pentamethylbenzenesulfonate solvolysis. A study
Cyclopropylcarbinyl p-Naphthalenesulfonate Solvolysis. Solvolytic
Substituent Effects on 2-Norbornyl Solvolysis Rates. The 6, 6-Dimethyl
Substituent Effects on Cyclopropylcarbinyl Solvolysis Rates. Evidence for Symmetrical Transition States Sir : The renowned conjugative interaction of cyclopropane rings with adjacent carbonium ions' continues to be demonstrated impressively. Cyclopropylcarbonium ions are unusually stable. Cyclopropylcarbinyl derivatives solvolyze with markedly enhanced rates 'v4-'0 to give rearranged and position scrambled products of the allylcarbinyl, cyclobutyl, and cyclopropylcarbinyl There must be extensive charge delocalization from the carbinyl carbon of the cyclopropyl carbonium ion to the cyclopropane ring, but the nature and the extent of this delocalization is still not generally agreed upon. Many structures for the cyclopropylcarbonium ion have been considered. 1--3,12,15-17 The classical representation, I,lb implies to us localization of the charge to the 1' position in a manner similar to that in the isobutyl or in the cyclohexylcarbinyl cation. We regard I as unsatisfactory in view of the abundant evidence for conjugation; some kind of "dotted line" formulation appears to us preferable. In certain cases the homoallylic cation, 11, with charge distributed between C-1 ' and C-2, may be f a v ~ r e d , ' ~but ? ' ~this structure seems unlikely for simple cyclopropylcarbinyl systems. ~ 1 5 -l7 (1) Reviews: (a) R. Breslow in "Molecular Rearrangements," Vol. 1, P. de Mayo, Ed., Interscience Publishers, Inc., 1963, Chapter 4;(b) N. C. Deno, Chem. Eng. News, 42 (40), 88 (1964); Progr. Phys. Org. Chem., 2, 129 (1964); (c) M. J. S . Dewar and A. P. Marchand, Ann. Reu. Phys. Chem., 16,321 (1965),and references therein cited. (2) C. U.Pittman, Jr., and G. A. Olah, J . Am. Chem. Soc., 87, 2998, 5123 (1965). (3) N. C. Deno, J. S. Liu, J. 0. Turner, D. N. Lincoln, and R. E. Fruit, Jr., 87, ibid., 3000 (1965);N. C. Deno, H. G. Richey, Jr., J. S. Kiu. D. N. Lincoln, and J. 0. Turner, 87, ibid., 4533 (1965). (4) (a) K.B. Wiberg and A. J. Ashe, 111, Tetrahedron Letters No. 21, 1553 (1965);(b) ibid., No. 47, 4245 (1965);(c) K. B. Wiberg, G. M. Lampman, R. P. Ciula, D. S. Connor, P. Schertler, and J. Lavanish, Tetrahedron, 21, 2749 (1965). ( 5 ) (a) D. D. Roberts, J . Org. Chem., 29, 294 (1964);(b) ibid., 30, 23 (1965). (6) (a) S. BorEiC, M. NikoletiC, and D. E. Sunko, J . Am. Chem. Soc., 84, 1615 (1962); (b) M. NikoletiC, S. BorriC, and D. E. Sunko, Proc. Natl. Acad. Sci. U.S . , 52, 893 (1964). (7) W. D. Closson and G. T, Kwiatkowski, Tetrahedron, 21, 2779 ( 1965). (8) E. F. Cox, M. C. Caserio, M. S. Silver, and J. D. Roberts, J. Am. Chem. Soc., 83, 2719 (1961). ( 9 ) (a) R. A. Sneen, K. M. Lewandowski, I. A. I. Taha, and B. R. Smith, ibid., 83, 4843 (1961);R. A. Sneen and A. L. Baron, ibid., 83, 614 (1961); (b) R. Breslow, J. Lockart, and A. Small, ibid., 84, 2793 (1962). (10) H. Hart and J. M. Sandri, ibid., 81, 320 (1959); H. Hart and P. A. Law, ibid., 84, 2462 (1962);86, 1957 (1964). (1 1) F. T. Bond and L. Scerbo, Tetrahedron Letters, No. 48, 4255 (1965). (12) (a) J. D. Roberts and R. H. Mazur, J . Am. Chem. Soc., 73, 2509, 3542 (1951); R. H. Mazur, W. N. White, D. A. Semenow, C. C. Lee, M. S. Silver, and J. D. Roberts,ibid.,81,4390(1959); M. C. Caserio, W. H. Graham, and J. D. Roberts, Tetrahedron, 11, 171 (1960); E. Renk and J. D. Roberts, J . Am. Chem. Soc., 83, 878 (1961); M. S. Silver, M. C. Caserio. H. E. Rice, and J. D. Roberts, ibid., 83, 3671 (1961); K. L. Servis and J. D. Roberts, ibid., 86, 3773 (1964); (b) ibid.. 87, 1331 (1965). (13) M. Hanack and K. Gorler, Chem. Ber., 96, 2121 (1963); M. Hanack and H. J. Schneider. Tetrahedron. 20, 1863 (1964). (14) C. F. Wilcox, Jr., an-d M. E. Mesirov, J . Am. Chem. Soc., 84, 2757 (1962);C. F. Wilcox, Jr., and D. L. Nealy, J . Org. Chem., 28, 3450, 3454 (1963); J. B. Rogan, ibid., 27, 3910 (1962);R. S. Bly and R. T. Swindell, ibid., 30, 10 (1965);D.E. Applequist and J. A. Landgrebe, J . Am. Chem. Soc., 86, 1543 (1964). (15) M. Simonetta and S. Winstein, ibid., 76, 18 (1954);S. Winstein and E. M. Kosower, ibid., 81, 4399 (1959);R. L. Piccolini and S . Winstein, Tetrahedron Suppl., 2, 423 (1963). (16) M. E. H. Howden and J. D. Roberts, ibid., 2,403 (1963). (17) R. Hoffmann, J . Chem. Phys., 40, 2480 (1964); Tetrahedron Letters, N o . 43, 3819 (1965).
The "tricyclobutonium ion", '2 with CSvsymmetry and essentially no charge on the methine group ((2-1) (111), has received neither experimental12 nor theoretica11b-17 support. 6 f IC
vIII*c IX Two different structures are favored by two schools of investigators: the unsymmetrical "bicyclobutonium ion" (IV-V),6p8p12v17 and a symmetrical "bisected" form (VI-IX).2r3117 These two structures have different charge distribution. All four carbons bear charge in VI-IX, but IV and V predicts instantaneous delocalization only onto C-1 ', C-1, and C-2, but not onto C-3. Jn support of VI-IX analogies with cyclopropane~arboxaldehyde'~~~~" cyclopropyl methyl ketone,'8bcyclopropanecarboxylic acid chloride,lsband phenylcycloproThese molecules prefer bisected pane l9 are ~ i t e d . ' ~ J J J ~ conformations (like IX) which, presumably, permit maximum overlap of the p orbital of the carbon adjacent to the ring with the cyclopropane "bent bonds."' We report here the simple approach to this problem of using methyl groups as probes for charge delocalization in the transition states of cyclopropylcarbinyl solvolyses (Table I). The rate enhancements produced by substitution of a single methyl group in various positions is summarized in XVIII. The effect of a second methyl group is shown in XIX and XX. The CH3
xx (18) (a) L. S. Bartell, B. L. Carroll, and J. P. Guillory, ibid., No. 13. 705 (1964); L. S. Bartell and 3. P. Guillory, J . Chem. Phys., 43, 647, 654 (1965). However, cf. G. J. Karabatsos and N. Hsi, J . Am. Chem. SOC.,87. 2864(1965); (b) L. S. Bartell, J. P. Guillory, and A. P. Parks, J. Phys. Chem., 69, 3043 (1965). (19) G. L. Closs and H. B. Klinger, J. Am. Chem. Soc., 87, 3265 (1965).
Communications to the Editor
2322 Table I. First-Order Rate Data for Solvolysis of Cyclopropylcarbinyl 3,5-Dinitrobenzoates in 60 Cyclopropylcar binyl 3,5-dinitrobenzoate 1 2 3 4 5 6 7 8 9 10 11 12
Parent I-Methyl 1 '-Methyl truns-2-Methyl cis-2-Methyl 2,2-Dimethyl
X,n X,n X,n X,n XI X,n XI1 XIII XIV
truns,frunL-2,3-Dimethyl cis,cis-2,3-Dimethyl cis,truns-2,3-Dimethyl truns-2,3,3-Trimethyl 2,2,3,3-Tetramethyl truns-2-Ethoxy = 8 = 7 = 6 = 5 =
XVI-PNB7 XVII-PNB
Aqueous Acetone at 100"
Relative rates
ki, SE-'
Obsd
4.30 x 10-7 1 .o 2.13 X 10-6 5.0 4.37 x 10-4 1020 4.75 x 10-6 11.0 3.50 x 8.2 3.97 x 10-6 92 5.33 x 1 0 - 5 124 3.53 x 10-6 82 3.45 x 10-6 80 2.12 x 10-4 490 6.75 x 10-4 1570 4.03 x 10-4 940 Polycyclic Compounds 3.77 x 10-6 88 2.20 x 10-5 51 9.65 X 220 1 . 7 0 X 10-6 40 3.78 X 10-6 8.8
Calcda 1.0
1.0 4 . 7brc4.8,' 5. 5,a 50'
(11 .O) (8.2)
121 67 90 1000 8100
4.00 x 10-4 5.42 x 10-4 6.00 X 10-6 4.43 x 10-6 2.17 x 1 0 - 6 7
1.3*
930 1260 14 103 3 m lO0Oj
Calcd by eq 1 . * Methanesulfonates in 96% ethanol at 20".eb Tosylates in acetic' acid at 25".68 dp-Methoxybenzenesulfonates in acetic acid at 25".58 e Benzenesulfonates in acetic acid at 25°.56 Chlorides in 50% ethanol. Rough comparison; rate constants were not reported at the same temperature. This ratio seems suspect. 0 Tosylates in acetic acid with added KOAc at 25°.4a Comparison made with data for the parent compound in acetic acid alone.& Tosylates in acetic acid at 17".4b i Comparison assumingp-nitrobenzoates solvolyze six times slower than 3,5-dinitrobenzoates. i p-Nitrobenzoates in 90% acetone at 118.6". 40
2- and 3-methyl substituents have a remarkably constant multiplicative effect. Each additional group enhances the rate independent of the number and location of its neighbors; the factor for a trans-2 or 3-methyl(ll.0) is slightly larger than the cis factor (8.2) (eq 1). ksubst/kparent = 8.2scis-2 Or 3-CHs x 1 1~ ~ L r o n s or - 23-CHa (1) I-IX differ in their prediction of the extent of charge delocalization. Our methyl results are clearly most consistent with symmetrical structures VI-IX for the
X, R = H XII, R = CH3
explicable on this basis: the unexpected decrease in rate in the series 15 * 18, with an increase in ring strain. Structures VI-JX predict a shortening of the C-2,3 bond in the ion. A small, strained ring attached to these positions would experience an increase of strain during ionization. Perhaps the small deviations of the relative rates of 10 (twofold) and of 11 (fivefold) from their calculated values (Table I) can be attributed to the same effect. Compounds 23 and 24 are accelerated by an increase of strain of the second ring due to the opportunity for C-1,2 bond lengthening in the transition state. Acknowledgments. We wish to thank the National Science Foundation and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research. (20) A. P. Sloan Research Fellow, 1962-1966.
(21) American Machine and Foundry Fellow, 1963-1964.
Paul von R. Schleyer,lo George W. Van Dinez1 Department of Chemistry, Princeton University Princeton, New Jersey 08540 Receiwd January 13, 1966
~ C H ~ O D N B
-Y
XI11
XIV The Electronic Multiplicity of Thermally Generated Cyanonitrene. A Thermochemical "Heavy-Atom" Effect
CHzODNB
XVI, n = 5 XVII, n = 3
cyclopropylcarbinyl cation transition state and are not consistent with the bicyclobutonium formulations IV and V. An additional curious structural effect is easily Journal of the American Chemical Society
88:lO
Sir : We have recently reported 1 that cyanonitrene (NCN) generated from thermal decomposition of cyanogen azide,2 in the absence of a solvent, inserts* into the C-H (1) A. G. Anastassiou, H. E. Simmons, and F. D. Marsh,/. Am. Chem. Soc., 87, 2296 (1965).

redpajama_set_name: RedPajamaCommonCrawl


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text:
by Shopping on FatCat Records
Formed in East London in 2012 by members Rachel Aggs (guitar), Billy Easter (bass) and Andrew Milk (drums), Shopping forge an itchy, angular explosion of propulsive bass lines, primitive disco-not-disco drums and guitar lines sharp as broken glass. Having done time in a plethora of UK DIY bands including Trash Kit and Wet Dog, they draw from a well of late '70s / early-'80s post-punk with a voraciousness seldom seen these days, bringing to mind the jagged aggression of Gang of Four, the pure, raw yelp of The Slits and the dance-inducing thrust of Delta 5, The Au Pairs and ESG.
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Shopping - Wind Up
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Shopping - 12345
The Official Body
Unexpected Item
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For Posterity
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Salon Des Amateurs (Remixes)
Waiting for the Light to Find Us
FatCat HyperCat Logo Sweater


text:
Q: PHP Multiple Image Resize and Upload Script I cobbled together a script out of one I found ealier. I wrote it to store 2 different sizes of each image that gets parsed (one for web one for mobile). Which it does but, problem is, its resizing images but they are larger (in kbs) than the original... A lot larger..
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redpajama_set_name: RedPajamaStackExchange


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Doing the hustle is an ongoing mindset to go out and hustle for the roles, and pay, you deserve, so we've now set up Do The Hustle as a resource bank versus a 4-week course, meaning graduates can dip into the content they need, when they need it. After 350+ hours of intensive social media training, this will be music to many training fatigued ears!
We've given our content a complete overhaul and added in new sections such as how to approach a 'discovery session' to specifically help graduates secure clients as soon as possible after graduation.
We've added in additional templates which can be used for pitching to clients and a ready-made presentation slide deck.
Content is now made up of 50% podcasts to enable easier access on the go and to suit different learning styles. Below is a taste of what that sounds like!
What does Do The Hustle cover?
Getting started: The fundamentals for setting up as a freelancer including podcasts from graduates on how they found work.
Finding Clients: How and where to find, approach and convert a steady stream of clients both on- and offline.
Managing clients: How to manage the client relationship, including creating a successful social media strategy, setting boundaries and working productively.
Templates: Access to dozens of templates, including slide deck presentations, social media audits, user personas and client pitches.
Altogether, Do The Hustle provides you with everything you need to set up and then thrive as a freelancer - and it's free for every student that joins our vocational training!


Congratulations to Chico Dennis on his upcoming 60th anniversary of working at Combined Insurance! Chico started selling insurance for Combined Insurance on February 20, 1957, and since then he's become somewhat of a legend at Combined Insurance.
He became close to Combined Insurance's founder, W. Clement Stone, and he always has an encouraging comment or a word of wisdom to share. When we posted about him recently on the company's LinkedIn and Facebook pages it became clear from the comments that he is widely loved and respected.
After emigrating from Cuba, Chico did not have the funds to go to college, so he started working in a bakery on the east coast. He baked cakes for several years, but he decided he wanted more out of his career. He thought sales may be just what he was looking for. His wife found a Combined Insurance recruiting sales ad, and Chico didn't hesitate to seek the opportunity. He got the job, and while he still loves baking cakes, he has never looked back.
Chico realized what a great opportunity he was being given to sell supplemental insurance at Combined. To ensure success, he learned as much as he could about the industry and about selling. One of the first books he read was W. Clement Stone's Success Through a Positive Mental Attitude, co-authored by Napoleon Hill. One of Chico's biggest claims to fame is that he hired the famous author and motivational speaker, Augustine "Og" Mandino II to sell insurance at Combined. Og went on to write The Greatest Salesman in the World, a favorite among many sales professionals.
Chico credits his success with hard work and never giving up and always having PMA.
He also wants people to know that he had to overcome big obstacles in his life, including the loss of one of his sons tragically and supporting another of his sons who is ill. For him, success in his career and in his personal life are linked, and his positive attitude is what helps him in both.
Being an insurance sales agent at Combined Insurance presents a unique opportunity for people in the workforce who are striving to improve their earning potential and who want a satisfying career.
Customers can choose to communicate with the company through the phone, internet, or through the mail in English or Spanish. Some business forms are also available in Spanish, and the website goes from English to Spanish with the toggle of a button.


All of our Gemologists are graduates of the Gemological Institute of America (GIA) and have many years of industry experience. Our staff are required to continually improve upon their education and training by regularly attending seminars, lectures, and advanced gemological studies, including the coveted and highly regarded, Fellowship (FGA) through the Gemological Association of Great Britain (Gem-A).
The colour evaluation of most gem-quality diamonds is based on the lack of colour. A pure and structurally perfect diamond has no hue, similar to a drop of clear water, which gives a diamond a higher value. The D to Z colour-grading assess the presence or lack of colour by comparing to master stones, stones that are of established colour value.
Diamonds are known for being able to transmit intense light and sparkle. We think of a diamond's cut as it's shape, either round, emerald, pear shaped. If a diamond's cut grade is about how well a diamond's facets interact with light, precise artistry and workmanship are needed to shape a stone so its proportions, symmetry and polish to deliver the magnificent return of light only possible in diamonds.
Natural diamonds are carbon exposed to tremendous heat and pressure, caused by volcanic activity in the earth. This process results in internal characteristics called inclusions and external characteristics called blemishes. Evaluating a diamonds clarity involves determining the size, relief, nature, and position of these characteristics and how this affects the overall appearance of the diamond, no diamond is perfectly pure, the closer it is to be pure, the higher the value.
A diamond's carat weight is the measurement of how much a diamond weighs. A metric carat is defined as 200 milligrams. Each carat can be divided into 100 'points. This allows very precise measurements to the hundredth decimal place, a jeweller will describe the weight of a diamond which is below one carat by its points alone.


We are very excited for the re-release of "Sudden Awakening." As Hampton Roads eagerly expressed interest in this project, we now have a beautiful new cover, poetry written by Eli and a foreword written by Gangaji.
Self-realization, true freedom, is available to all who seek it; this is Eli Jaxon-Bear's message. Based on his own wide-ranging spiritual journey, Sudden Awakening is a practical guide that answers essential questions and assists spiritual seekers in awakening to what is already present.


March 9, Friends of Arbor Lodge held a work day at Harper's Playground.
Around 45 people showed up, many from the Timbers Army, to provide some TLC to the neighborhood park. Volunteers weeded tree wells, laid fresh wood chips, painted picnic tables and benches and performed many other beautifying upkeeps.
Harper's Playground opened last fall in Arbor Lodge Park in North Portland. Cody and April Goldberg led the effort to build the new playground, inspired by their daughter Harper. Harper's Playground builds community by providing a completely inclusive playground where children and adults of all abilities can play together.
To stay in the know about Arbor Lodge volunteer events "like" Friends of Arbor Lodge on Facebook. For upcoming work days at Harper's Playground, "like" Harper's Playground on Facebook, too!


On behalf of Farmer, Cline & Campbell, PLLC posted in Car Accidents on Monday, September 24, 2018.
Research shows that most drivers tend to overestimate their driving abilities. This is true of drivers all over the world, but it is especially true of those in West Virginia and around the country.
A report released by Motus, a vehicle management platform, indicates that the rate of car accidents has increased significantly alongside the rate of smartphone use. In its 2018 Distracted Driving Report, the company says smartphone ownership grew to 77 percent in 2017 from just 55 percent in 2013. During that same period, the number of car crashes in West Virginia and across the country rose to 6.4 million from 5.7 million. That represents a 12.3 percent increase.
On behalf of Farmer, Cline & Campbell, PLLC posted in Car Accidents on Monday, September 10, 2018.
West Virginia has a rainy season like every other state, which poses several challenges on the road. One of the dangers that drivers must always be alert for is hydroplaning, where a vehicle slides or slips uncontrollably over a wet surface. The thin layer of water that develops between a vehicle's tire and the road could become thicker, making the tires lose traction.
On behalf of Farmer, Cline & Campbell, PLLC posted in Car Accidents on Tuesday, September 4, 2018.
West Virginia residents, especially those who are thinking about purchasing a new car, should know that current safety tech is cutting down on the number of backup crashes. While backup collisions are only one type of accident, the fact remains that they can lead to serious injuries and even fatalities, particularly among children.
On behalf of Farmer, Cline & Campbell, PLLC posted in Car Accidents on Friday, August 31, 2018.
Car accidents cause many injuries and deaths in West Virginia every year. Unfortunately, traffic signals and speed limits are not enough to stop negligent drivers from causing serious collisions. Experts suggest that roundabouts may save lives and be more effective than traffic lights at preventing serious accidents.
On behalf of Farmer, Cline & Campbell, PLLC posted in Car Accidents on Monday, August 27, 2018.
When summer days in West Virginia wind down, kids go back to school and major holidays loom ahead on the calendar. These forces increase traffic, especially with the addition of school buses, bicyclists and pedestrians. Hazards can pop up in urban, suburban or rural environments, and safe drivers observe best practices in all situations.
On behalf of Farmer, Cline & Campbell, PLLC posted in Car Accidents on Wednesday, August 22, 2018.
On Aug. 7, the Insurance Institute for Highway Safety warned drivers in West Virginia and elsewhere that Tesla, BMW, Mercedes and Volvo vehicles can be dangerous when operated in semi-autonomous mode. The agency encouraged drivers to use extreme caution when placing their car or truck under semi-automated control.


text:
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Manchester City were in exhibition mode, winning this 10th Premier League outing of the season with ease. Kevin De Bruyne, Raheem Sterling, Riyad Mahrez particularly sparkled in a fine team display, their play at times sublime and just too good for Fulham. Pep Guardiola's side are in admirable form as they approach next weekend's visit to Manchester United for the derby.
John Stones was retained by Guardiola, meaning no place again for Aymeric Laporte, Phil Foden also missing out and thus extending his spell out of the league XI to six weeks, while Kyle Walker was completely rested. Fulham arrived with their confidence boosted by beating Leicester last time out, though they were still a place above the drop zone.
City were soon ahead, though it could have come even earlier than the fifth minute, Mahrez putting Sterling in only for his shot to be too close to Alphonse Areola, who saved his team. Seconds later the Cottagers did go behind. Jonathan Moss denied a City handball appeal to wave play on and they could thank the referee, as De Bruyne collected and rolled possession to Sterling. This time the finish was true, to Areola's right.
The visitors' responded by winning a corner on their right but Harrison Reed's delivery yielded nothing. City's high-speed pass game was then evident when Benjamin Mendy flipped the ball to Mahrez, who passed instantly to De Bruyne and his first-time effort was saved at the near angle by Areola.
Parker had his team trying to press from the front, where Ruben Loftus-Cheek, the most advanced midfielder, joined Ademola Lookman and Ivan Cavaleiro, Fulham's front two. The problem here was obvious: City are so accomplished at moving the ball that they could – and did – attack at will.
Rodri, Ilkay Gündogan, João Cancelo and Mahrez strung one series of passes together that ended with a corner. Nothing came of that but De Bruyne then slipped Mendy in and his rocket of a delivery was repelled for a throw-in. City were not to be denied for long, though.
Cancelo's pass found Gabriel Jesus, who teed the ball back around the corner to the right-back. The Portuguese roved towards goal and hit a firm pass to the effervescent Sterling. The No 7's Fred Astaire act had Joachim Andersen lunging and down went the England man; Moss awarded a spot-kick and De Bruyne buried it.
Fulham were overwhelmed yet City's grip came close to being loosened by the kind of calamity defending that caused Stones to be dropped previously. As he went to pass back to Ederson, the centre-back beat the advancing keeper and nearly rolled the ball into the empty goal, Stones failing to take a look to confirm where the Brazilian was.
Guardiola stamped his feet in anger and Stones wore a haunted expression. Still, City were soon up the other end, a delightful Mahrez chip looping on to Sterling's foot; his volley required a flying save from Areola.
The half ended with one more Sterling attempt, which ricocheted out for a corner.
Fulham faced a long 45 minutes. Following a brief foray in which yellow shirts flooded City's half, they were soon back by their own goal, barely scrambling away a Mahrez cross aimed for Jesus. Next, the west London side were bewitched by De Bruyne's ability to glide in possession, the Belgian doing so then releasing Jesus, who tapped the ball back to the No 17: his left foot hit pinged off the bar.
City were rampant. De Bruyne again shot powerfully with his left foot, though again Areola was up the challenge. Rúben Dias then spooned over a De Bruyne corner as City reached the closing stages still searching for a third. They failed to find one but Guardiola can be delighted with his side.
Original source: Guardian
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Cost of Mumbai metro III soars by Rs 10,000 crore in five years
The escalation proposal was submitted to the state finance department by the Mumbai Metro Rail Corporation (MMRC), which is implementing the 33.5km rail link between Cuffe Parade and Seepz, in February. The finance department is yet to clear it.
Nauzer Bharucha
MUMBAI: The cost of the underground Metro 3 project has escalated by over Rs 10,000 crore to Rs 33,406 crore from the original estimate of Rs 23,136 crore in 2016. When tenders were invited in 2016, the cost was based on the 2011 estimate.
The escalation proposal was submitted to the state finance department by the Mumbai Metro Rail Corporation (MMRC), which is implementing the 33.5km rail link between Cuffe Parade and Seepz, in February. The finance department is yet to clear it. "There is a perception that no further cost should be approved till the controversy over the location of the car shed is resolved," a government source said.
It is also learnt that the Japan International Cooperation Agency (JICA), which is funding almost 60% of the total project cost, has not released funds for Metro 3 for the past year. "It is not JICA's fault. The agency is waiting for the cost escalation approvals by the state and Centre," a source said.
Even as the project cost has shot up, there is growing uneasiness within government circles at the inability of the ruling MVA to shift the metro car shed from Aarey to Kanjurmarg.
Last December, the Bombay high court stayed the suburban collector's decision to hand over the Kanjurmarg land for the car shed. "Since then, there has been virtually no initiative on the part of state agencies to vacate the stay," a source said.
The high court had fixed the matter for final hearing in February, but the state sought time to file replies and the case was adjourned to March. "Between March and April 2021, the case came up five times in the HC. But each time the matter came up, the state constantly sought more time," an official said.
On February 2, the Mumbai Metropolitan Region Development Authority (MMRDA), too, filed an application seeking that the stay order be vacated as a "public project was being gravely affected".
"After filing the application, the MMRDA has done little to push the case in the court for an early hearing," an official said.
A senior bureaucrat ascribed the cost escalation to various reasons, the controversy over the car shed being one of them.
"The original project cost was based on the terrain of the Delhi metro. It was later found that Mumbai has a different terrain," he said.
The land acquisition cost for Metro 3 also drastically increased once the project commenced. The original estimate for land acquisition was fixed at Rs 590 crore, which has now increased to Rs 1,483 crore.
The largest cost escalation component is for construction of the tunnel, stations and car depot. It was initially pegged at Rs 10,708 crore, but the revised cost estimate is Rs 18,711 crore.
Early this year, a nine-member government panel headed by the then chief secretary Sanjay Kumar said an integrated metro depot at Kanjurmarg will save the government Rs 1,580 crore against land and construction costs. The committee appointed by the state government said the Metro 3 car shed at Aarey can accommodate only 30 rakes, while the Kanjurmarg one is large enough to hold 55.
The panel report also concluded that the 41-hectare Kanjurmarg plot is big enough to be an integrated depot for three Metro lines: 3, 4 and 6.
The 20-page report mentions that "if the integrated depot is planned at Kanjurmarg, an interchange station of Line 14 and Line 6 can be proposed at Kanjurmarg, facilitating better interchange between Lines 3, 6 and 14".
The Shiv Sena-led alliance government also has to cope with another obstacle on the Kanjurmarg land. Construction giant Shapoorji Pallonji has invested Rs 471 crore on the 500-acre Kanjurmarg sprawl with the Garodia family, which has claimed ownership over the plot.
Mumbai Metro Rail Corporation
MMRDA
MMRC
Mumbai metro


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MS Office 2016 is now available
By owner|2015-09-24T10:08:06+12:00September 24th, 2015|Blog, News|
Office 365 - MS Office 2016 is now available As part of your office 365 subscription you are automatically entitled to upgrade to latest version of office when it is released. As of 22nd September [...]
A Celebration of Sallys Life
By Paul Starling|2019-11-07T17:48:50+12:00November 6th, 2019|Blog, News|
Since we opened almost nine years ago, many of our customers have become friends and know that Sally has been battling ovarian cancer for the last six years. On November 5th the cancer won. A [...]
Is Your Old Technology Dragging You Down?
By Paul Starling|2019-03-05T13:08:43+12:00March 5th, 2019|Blog, News|
Is Your Old Technology Dragging You Down? For most people, technology is both a blessing and a curse. It makes life easier, we can now do and see things that even a generation ago [...]
Are You Backing Up The Right Way?
Are You Backing Up The Right Way? The 31st of March is World Backup day and it's a great time to put a backup in place. Businesses are losing huge amounts of data every day, [...]
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Why Spam is a Small Business Nightmare 15 years after the world united to crack down on spam emails, we're still struggling with overloaded inboxes. All that unwanted email continues to flood the internet, much [...]
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Word Search Competition March 2019
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It's Competition Time ! We are giving away a Canon Printer. All you have to do is find the computer related words hidden in our Word Search,. Print off and fill in your entry and [...]
Promote Your Community Group or Business For Free
By Paul Starling|2018-10-17T10:04:35+12:00October 17th, 2018|Blog, News|
Have you come across the Rangiora High Street Facebook page? The Rangiora High Street Facebook page is a growing page for Rangiora gossip, discussions, debates and promoting Rangiora community organisations and businesses. If you wish to [...]
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What are the benefits of Office 365? Most software companies have changed their business models from selling a packaged product to 'Software as a Service' (SaaS) or in simple terms they are selling a subscription [...]
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Currency converter result page of conversion 7840 New Zealand Dollar in Turkish Lira. Exchange rate of this pair updated every day. FXConvert.net is free, fast and easy to use online tool which give latest rates of pair NZD-TRY.
Price of seven thousand, eight hundred and forty New Zealand Dollar, cost 30465.83 Turkish Lira and converted with today exchange rate.
This graph show how much is 7840 NZ Dollars in Turkish Liras - 30465.83265 TRY, according to actual pair rate equal 1 NZD = 3.8859 TRY. Yesterday this currency exchange rate was on 0.00528 TRY higher than today. On the last week currencies rate was on TL0.02112 TRY higher. Last month was lower on - TL 0.13252. Price for 1 NZ Dollar was 3.75343 Turkish Lira, so 7840 New Zealand Dollar was worth 29426.907982306 in Turkish Lira. On this graph you can see trend of change 7840 NZD to TRY. And average currency exchange rate for the last week was TL 3.884 TRY for NZ$1 NZD.


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ORLANDO, FLORIDA-You've built a website with high-quality content that is search-engine friendly, done the on-page optimization and invested the time in a link-building campaign, but your site still isn't getting the rankings you want.
According to our CEO Ali Husayni, the site may be missing one of the essential parts of ranking well on Google: fresh content.
The majority of our site's traffic each month is generated through the content we post on the blog. If we fall short of our goal for number of posts in a month, we can expect to see a significant decrease in traffic within a week or two as Google begins to place other sites with fresher content on search results.
Freshness hasn't always been as big a part of Google's search algorithm as it is now. Their ultimate goal is to provide their users with the best search results, so they are constantly adjusting the algorithm. The freshness factor was one of those changes and now it is essential to rank well.
"We've always believed that the perfect search engine should understand exactly what you mean and give you back exactly what you want," says Amit Singhal, who is a senior vice president at Google.
They made 52 changes to the search engine algorithm in April, according to a blog post summary from Matt Cutts, who is part of the search quality team at Google. Three of those specifically related to content freshness and made minor adjustments to promote content that appears to be fresh while excluding what is fresh but low-quality. Last year's big update named Panda made the biggest difference, though.
Panda was Google's way of assessing website quality and penalizing low-quality sites using black-hat and gray-hat SEO practices like cloaking, content scraping and keyword stuffing. Panda and its subsequent updates were bad news for black-hat SEO. Cutts said Panda affected about 12 percent of queries to a significant degree, meaning a regular user might notice.
Google never reveals the exact algorithm used to rank pages, but Husayni maintains that the key to SEO success in general is a combination of quality content, popularity and relevance.
"Those same characteristics-the ones that drive the most traffic to a website on Google, generate the most conversions and invite the best engagement from users-are just as important in determining freshness," he says.
But just because content is freshly published doesn't guarantee it is going to be on the first page of a Google search results page. Clearly Google will look at more than just a time stamp or they didn't solve any spam problems at all. Businesses should keep time stamps and their XML sitemaps up to date, but content still has to be high-quality to make it to the top.
"The best way for small businesses to keep their site fresh-and therefore relevant in Google's eyes-is with a blog, an excellent way to distribute the high-quality content they created," Husayni says.
Unfortunately there is no magic number of times a business has to post to stay fresh. It just depends on too many factors for a one-size-fits-all answer, including the competitiveness of their market and their type of business.
"Fast-paced industries like SEO require very frequent updating, but others may be able to post twice a month to stay fresh," says Husayni.
If deciphering Analytics' reports is something you don't have the time to do or something you want a little training in, you can also schedule a free SEO consultation with our SEO expert, Ali Husayni .
A common objection heard from small businesses is that coming up with high-quality content on a regular basis is too time-consuming, but good content doesn't have to take a long time. It helps to start with a good understanding of exactly what Google deems high quality content, which we've talked about in many of our previous posts. You may be surprised to find that choosing topics for articles and press releases is easier than you think. These posts not only fulfill the freshness component they also give you an opportunity to optimize anchor text for search engines and build up backlinks to your site that contribute to overall ranking. Just be sure that you're not hurting rankings by making the most common mistakes in generating site content.
thanks for great post, like always,keep on great for us.


Professional Reference articles are designed for health professionals to use. They are written by UK doctors and based on research evidence, UK and European Guidelines. You may find the Asthma article more useful, or one of our other health articles.
See also separate Diagnosing Childhood Asthma in Primary Care article.
Asthma is the most common respiratory disorder of children. Chronic inflammation of the bronchial mucosa and hyper-reactive airways results in bronchoconstriction and reversible airway narrowing. It typically presents with wheeze, dry cough, difficulty breathing and/or chest tightness.
Dr Hayley Willacy recently read a cautionary abstract looking at antibiotic prescriptions for children with asthma.[Baan E, et al. Antibiotic use in children with asthma. Abstract no: OA3449. European Respiratory Society International Congress. Milan, Italy. 2017.] The study included 1.5 million children from the UK, including around 150,000 with asthma, and a further 375,000 from the Netherlands, of whom around 30,000 had asthma. They compared antibiotic prescriptions for children with and without asthma and compared the situation in the Netherlands with that in the UK. The researchers found that children with asthma were approximately 1.6-times more likely to be prescribed antibiotics, compared with children who did not have asthma. They also found that antibiotic prescription rates were almost twice that in the UK overall. These results may show that asthma symptoms are being mistaken for respiratory tract infections, or that antibiotics are being given as prevention, even though guidelines do not support this.
Transient early wheezers where wheezing is commonly associated with viral upper respiratory infections. This is most likely to be grown out of by about the age of 3 years, particularly in those children without a family or personal history of atopy.
Non-atopic wheezers who again are likely to outgrow symptoms by early school age.
Children who go on to develop a more persistent, atopic asthma, associated with raised immunoglobulin E (IgE) levels.
Acute asthma is a relatively common paediatric emergency. Treat acute asthma as severe until proven otherwise and refer children who respond inadequately to community treatment urgently to hospital. Severe asthma in children is the third most common cause of hospital admission and the most common cause of paediatric intensive care unit (ICU) admission[2, 3].
It is vital to recognise the severity of an acute asthma attack. Clinical signs are a poor indicator of the degree of airways obstruction and some with acute severe asthma may not appear distressed.
Degree of breathlessness (eg, ability to complete sentences, and to feed).
Use of accessory muscles of respiration (feel the neck muscles for involvement in breathing).
Amount of wheezing (with increasing severity, wheeze may become biphasic or less apparent).
Degree of agitation and conscious level.
Pulse >125 in those aged over 5 years or >140 in 2-5 year-olds.
Respiratory rate >30 in those aged over 5 and >40 in 2- to 5-year-olds.
Use of accessory neck muscles.
Peak expiratory flow rate (PEFR) 33-50% best/predicted (age over 5 years).
PEFR 33-50% best/predicted (age over 5 years).
Most infants are audibly wheezy with intercostal recession but not distressed. Life-threatening features include apnoea, bradycardia and poor respiratory effort.
Children should be monitored carefully and assessed repeatedly to determine the need for admission to secondary care or for transfer to a high-dependency unit (HDU) or paediatric intensive care unit (PICU), where there are features of poorly responsive severe asthma or life-threatening asthma.
Peak expiratory flow rate (PEFR) in children aged over 5 years (use best of three readings, expressed as a % of personal best PEFR).
Oxygen saturation - should be available in primary care, as low oxygen saturations (<92%) after initial bronchodilator therapy indicate a more severe subgroup of patients, in whom inpatient treatment may be required.
CXRs and arterial blood gases are not routinely indicated, as their information yield is rarely high.
Children with severe or life-threatening asthma should be transferred to hospital urgently.
Asthma attack in late afternoon or at night.
Recent hospital admission or previous severe attack.
Concern over social circumstances or ability to cope at home.
Beta2 agonist 2-10 puffs via spacer and (face mask for age 2-5 years; mouthpiece if over 5 years); give one puff of beta2 agonist every 30-60 seconds up to 10 puffs according to response. Consider oral prednisolone (20 mg for age 2-5 years; 30-40 mg for age over 5 years).
If there is a poor response: arrange hospital admission.
If there is a good response: continue beta2 agonist via spacer or nebuliser, as needed but not exceeding four hourly. If symptoms are not controlled, repeat beta2 agonist and refer to hospital. Continue prednisolone for up to three days. Arrange review within 48 hours. Consider referral to a secondary care asthma clinic if there is a second attack within 12 months.
Oxygen via face mask; 10 puffs of beta2 agonist or nebulised salbutamol (2.5 mg for age 2-5 years; 5 mg for age over 5 years), oral prednisolone (20 mg for age 2-5 years; 30-40 mg for age over 5 years).
If there is a poor response: repeat beta2 agonist and arrange hospital admission.
Oxygen via face mask, nebulise with salbutamol (2.5 mg for age 2-5 years; 5 mg for age over 5 years) and ipratropium 0.25 mg; oral prednisolone (20 mg for age 2-5 years; 30-40 mg for age over 5 years) - or intravenous hydrocortisone (50 mg for age 2-5 years; 100 mg for age over 5 years) if vomiting. Stay with the child while awaiting ambulance for immediate transfer to hospital.
Current evidence does not support increasing the dose of inhaled corticosteroids (ICS) as part of a self-initiated action plan to treat exacerbations in adults and children with mild-to-moderate asthma. Increased ICS dose is not associated with a statistically significant reduction in the odds of requiring rescue oral corticosteroids for the exacerbation, or of having adverse events, compared with a stable ICS dose.
For children aged 2 years and over, give oral steroids early in the treatment of acute asthma attacks. For children aged less than 2 years, consider steroid tablets early in the management of severe asthma attacks in the hospital setting. However, systemic corticosteroids do not affect the long-term prognosis in children with their first viral-induced wheezing episode and should be used cautiously during acute episodes.
Much of the management of asthma has been delegated to asthma nurses - either within the practice or within the community.
It is very important to consider the upper respiratory tract when treating asthma. It is much more difficult to treat asthma successfully if co-existing allergic rhinitis (perennial or seasonal) is not adequately controlled .
Removing soft toys from the bed.
High-temperature washing of bed linen.
Pet allergy - there are no controlled trials looking at removing domestic pets. There is varied anecdotal evidence with some experiencing no benefit on removing the pet and others, with continuing exposure to the pet, developing some tolerance. However, it seems sensible not to have a cat or dog if someone in the family already has asthma.
Dietary manipulation - studies looking at supplementation with vitamin C, vitamin E, magnesium and fish oil have not shown significantly beneficial effects.
There is insufficient evidence to recommend acupuncture, herbal or Chinese medicines, homeopathy, hypnosis or relaxation therapies.
Smoking cessation advice to caregivers and teenagers with asthma. Direct or passive smoking reduces lung function and increases the need for rescue medication and long-term 'preventer' treatment.
Physical exercise therapy - may increase overall fitness but is of no specific benefit to asthma.
Family therapy - where asthma is difficult to control, this may be a useful adjunct.
Consider care links - eg, to school and transition to adult services. Schools should have their own asthma policy; staff are not required to administer asthma drugs except in an emergency but most are supportive of children with asthma and receptive to training in managing asthma and the correct way to administer inhaled drugs.
Links to local and national patient groups for support and information.
As for adult management of chronic asthma, current national guidelines advocate a stepwise approach. Start at the step most appropriate to the initial severity of symptoms. Aim to achieve early control and then decrease treatment by stepping down to the lowest controlling step once stable. Always check concordance and reconsider diagnosis if response to treatment is poorer than anticipated.
Step 1: mild intermittent asthma - inhaled short-acting beta2 agonists as needed.
Step 2: regular preventer therapy - add inhaled steroid 200-400 micrograms/day (beclometasone diproprionate or equivalent) or a leukotriene antagonist if inhaled steroid cannot be used. Start at the dose of inhaled steroid appropriate to the severity of the disease.
Step 3: add-on therapy - for children aged over 2 years, consider the addition of a leukotriene antagonist or inhaled steroid 200-400 micrograms/day (dependent on what drug they received already as Step 2). For children under 2 years, consider proceeding to Step 4.
Step 4: persistent poor control - refer to a respiratory paediatrician.
Step 2: regular preventer therapy - add inhaled steroid 200-400 micrograms/day (beclometasone diproprionate or equivalent). 200 micrograms is an appropriate starting dose for most patients but judge according to the severity of disease.
Step 3: add-on therapies - add in a long-acting inhaled beta2 agonist (LABA) but if response is poor, stop. If the asthma is still not controlled, increase the dose of inhaled corticosteroid to 400 micrograms/day (beclometasone diproprionate or equivalent) and then add either a leukotriene receptor antagonist or slow-release theophylline.
Step 4: persistent poor control - increase inhaled steroid to 800 micrograms/day (beclometasone diproprionate or equivalent).
Step 5: continuous or frequent use of oral steroids - use in the lowest dose to provide control whilst maintaining high-dose inhaled steroids and refer to respiratory paediatricians.
Management of those aged over 12 years is as for adults. See separate Management of Adult Asthma article.
Short-acting beta2 agonists work quickly and provide symptomatic relief. No benefits have been shown from regular dosing. Good asthma control is associated with little or no need for short-acting beta2 agonists. Using two or more canisters of beta2 agonists per month or >10-12 puffs per day, is a marker of poorly controlled asthma that puts individuals at risk of fatal or near-fatal asthma. Thus, patients overusing inhaled short-acting beta2 agonists should have their asthma management reviewed.
LABAs are useful in symptomatic control, particularly in the treatment of nocturnal asthma; however, they should not be used as relief for an acute attack. Any child using a LABA should also be using regular inhaled corticosteroid, as failure to do this increases the risk of life-threatening attacks. LABAs are the first-choice add-on therapy where control on normal-dose inhaled steroids remains sub-optimum in children aged over 5 years.
Oral preparations of beta2 agonists have been used extensively in the past with children but are less effective than inhaled preparations and have more side-effects.
Beta2 agonists are being used more than two times per week.
Symptoms disturb sleep at least once a week.
A child has had an exacerbation in the previous two years, requiring systemic corticosteroids.
They should be taken regularly and concordance may be an issue. Improvement in symptoms usually takes 3-7 days.
No impact on later development of asthma has been shown by early intervention with regular inhaled steroids in episodically wheezy children aged under 5 years.
High doses of ICS used for prolonged periods can induce adrenal suppression. ICS have occasionally been associated with adrenal crisis and coma in children.
Excessive doses should therefore be avoided and the dose of an ICS should be no higher than necessary to keep a child's asthma under good control.
Growth restriction associated with systemic corticosteroid therapy does not seem to occur with recommended doses of ICS; although initial growth velocity may be reduced, there appears to be no effect on achieving normal adult height.
Candidiasis of the throat and mouth may occur, particularly with higher doses of ICS. Strategies to reduce the risk include use of a spacer and rinsing the mouth with water or cleaning the teeth following inhalation.
These are an option as 'add-on' therapy to poorly controlled asthma. In children aged over 5 years, a LABA and ICS to a dose of 400 micrograms beclometasone diproprionate or equivalent should be trialled before their use.
Leukotriene receptor antagonists improve lung function, decrease exacerbations and improve symptoms in some patients but there appears to be wide individual difference in response.
They should not be considered 'steroid-sparing'.
These are another option as 'add-on' therapy for children aged over 5 years.
There is little evidence demonstrating the increased benefit of one particular 'add-on' approach (further increase dose of ICS 800 micrograms beclometasone diproprionate, leukotriene receptor antagonist, oral theophylline or slow-release oral beta2 agonist) to guide choice.
Theophyllines and oral beta2 agonists are associated with higher risk of side-effects.
With any add-on therapy, have a trial for a predetermined time period and stop the therapy if, on assessment, it has no benefit.
The National Institute for Health and Care Excellence (NICE) recommends omalizumab as an option for treating severe persistent confirmed allergic IgE-mediated asthma as an add-on to optimised standard therapy in children aged 6 years and older who need continuous or frequent treatment with oral corticosteroids (defined as four or more courses in the previous year). Omalizumab should only be initiated by a specialist.
Optimised standard therapy is defined as a full trial of and, if tolerated, documented compliance with high-dose ICS, LABAs, leukotriene receptor antagonists, theophyllines and oral corticosteroids.
Unexpected clinical findings (for example, abnormal voice, focal chest signs, dysphagia, inspiratory wheeze, stridor).
Symptoms present from birth, or a perinatal lung problem.
Severe upper respiratory tract infection.
Family history of unusual chest disease.
Inadequate response to maximum guideline treatment, particularly if oral corticosteroids are needed frequently, or use of the maximum dose of ICS.
Influenza vaccine - children with asthma who require continuous or repeated use of inhaled/systemic steroids or with previous exacerbations requiring hospital admission should be immunised. If children receive repeated systemic steroids sufficient to cause immunosuppression they also require pneumococcal vaccination.
See the separate Which Device in Asthma? and Nebulisers in General Practice articles.
A metered dose inhaler (MDI) plus spacer device is the first-line choice for the delivery of ICS therapy in those aged over 5 years.
Where poor compliance with MDI and spacer is likely to jeopardise good asthma control, alternative devices should be considered whilst still looking to minimise systemic absorption.
For those aged less than 5 years, corticosteroid and bronchodilator therapy should be delivered via MDI/spacer and face mask combination. Nebulisers may be considered where MDIs and spacers are not effective or if the child's clinical condition is poor.
Children and their carers need to be trained in the use of their chosen device prior to prescribing and should be suitability reviewed looking at compliance and technique.
Reduced growth, usually as a result of poor control rather than treatment.
Psychological morbidity - although differences appear to be the result of poor health rather than asthma itself.
Absence from school and educational disadvantage.
In one study of children admitted to the PICU, there was a 22% complication rate (eg, aspiration pneumonia, ventilator-associated pneumonia, pneumomediastinum, pneumothorax and rhabdomyolysis), increased by intubation.
Russell G; Wheeze in preschool children. BMJ. 2008 Jun 16.
Mannix R, Bachur R; Status asthmaticus in children. Curr Opin Pediatr. 2007 Jun19(3):281-7.
Carroll CL, Zucker AR; The increased cost of complications in children with status asthmaticus. Pediatr Pulmonol. 2007 Oct42(10):914-9.
Kew KM, Quinn M, Quon BS, et al; Increased versus stable doses of inhaled corticosteroids for exacerbations of chronic asthma in adults and children. Cochrane Database Syst Rev. 2016 Jun 7(6):CD007524. doi: 10.1002/14651858.CD007524.pub4.
de Benedictis FM, Attanasi M; Asthma in childhood. Eur Respir Rev. 2016 Mar25(139):41-7. doi: 10.1183/16000617.0082-2015.
Currie GP, Devereux GS, Lee DK, et al; Recent developments in asthma management. BMJ. 2005 Mar 12330(7491):585-9.
Gotzsche PC, Johansen HK; House dust mite control measures for asthma. Cochrane Database Syst Rev. 2008 Apr 16(2):CD001187.
Thoonen BP, Schermer TR, Van Den Boom G, et al; Self-management of asthma in general practice, asthma control and quality of life: a randomised controlled trial. Thorax. 2003 Jan58(1):30-6.
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Scheduling for the 2018-2019 School year will take place June 4th – June 8th. Please use the Sign-up Genius link to schedule a time for your scholar to come in and pick their classes for next year! If you have a current transcript, report card, IEP or 504, please bring that along. Having those items will expedite the process.


White Fiberlite modular sofa with burnt orange corduroy upholstery designed in 1966 by Mario Bellini and manufactured by C&B Italia. The sofa consists of four separate modular units that can be configured in many different ways making these chair extremely versatile and able to work in both large and small spaces, the possibilities are endless. These chairs are extremely comfortable and would grace any Vintage, Mid Century, Retro or Modern interior. Each chair measures 85cm wide x 85cm deep x 68cm high to the top of the back. The Fiberlite shells are in fantastic vintage condition.
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This 1940's Mexican silver pin shows a man in a sombrero leading a burro through the desert. The man is carrying a staff with a small inlaid turquoise on top. The pin measures about 2" wide and 1.5" high and has a standard clasp. The piece is marked "Plata Suo Anton." There are some additional words ("Silver Mexico"?), which have been rubbed out over time. Unmarked, but this may be sterling. In very good condition.


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text:
Scientology library: "812 S.W. Washington Street Portland Oregon United States"
812 s.w. washington street portland oregon united states • aaron spencer • church of scientology of portland • daily journal of commerce (oregon) • gwen mayfield-barnard • ideal org • james pitkin • janie har • lawsuit • membership • oregon • portland • portland business journal • real estate • sherlock building @ 320 south west oak street portland oregon united states • stephen beaven • steven roy crandell • teresa barney • the oregonian (portland) • wendy culverwell • willamette week
Reference materials 812 S.W. Washington Street Portland Oregon United States
8 matching items found.
Tough time for Scientologists: A Story in The New Yorker and a lawsuit in Portland — Willamette Week
Author(s): James Pitkin
Source: Willamette Week
It's shaping up to be a tough month both in Portland and nationwide for the Church of Scientology. On a national level, a takedown published this week in The New Yorker can't be good for the religion founded by sci-fi writer L. Ron Hubbard. And locally, Scientologists face a lawsuit filed Feb. 4 by a woman claiming exposure to toxic fumes in a downtown Portland building owned by the Church. The suit filed in Multnomah County Circuit Court claims Teresa Barney ...
Tag(s): 812 S.W. Washington Street Portland Oregon United States • Gwen Mayfield-Barnard • James Pitkin • Lawsuit • Teresa Barney • Willamette Week
Church of Scientology buys Sherlock Building — Daily Journal of Commerce (Oregon)
Author(s): Aaron Spencer
Source: Daily Journal of Commerce (Oregon)
The Church of Scientology last week completed the purchase of the historic Sherlock Building in downtown Portland. The church purchased the building for $6.4 million. Portland-based Butler Brokers managed the sale. The Sherlock Building, at 309 S.W. 3rd Ave., is six stories and 61,430 square feet. It was built in 1894 and is listed on the National Register of Historic Places. The church purchased the building from Seattle-based Urban Renaissance Group, which bought the building in 2007 for $9.75 million. The ...
Tag(s): 812 S.W. Washington Street Portland Oregon United States • Aaron Spencer • Daily Journal of Commerce (Oregon) • Gwen Mayfield-Barnard • Membership • Oregon • Real estate • Sherlock Building @ 320 South West Oak Street Portland Oregon United States
The Church of Scientology of Portland says old digs don't work, buys bigger digs downtown — The Oregonian (Portland)
Author(s): Janie Har
Source: The Oregonian (Portland)
The Church of Scientology of Portland is moving into a larger building at Third and Oak. Community affairs director Gwen Barnard said the 12-story Stevens Building at 812 S.W. Washington Street, which the church bought in 2008, lacks the open space needed for a chapel and architects couldn't make it work. The church purchased the 6-story Sherlock Building at 320 S.W. Oak Street for $6.4 million from the Urban Renaissance Group, an investment partnership based in Seattle. Office space on floors ...
Tag(s): 812 S.W. Washington Street Portland Oregon United States • Church of Scientology of Portland • Gwen Mayfield-Barnard • Janie Har • Membership • Oregon • Real estate • Sherlock Building @ 320 South West Oak Street Portland Oregon United States • The Oregonian (Portland)
Church of Scientology selling Stevens Building in Portland — Daily Journal of Commerce (Oregon)
When the Church of Scientology bought the Stevens Building in 2008, it told tenants to vacate when their leases ended. Most of them did. Now the Portland building is 42 percent vacant, another 20 percent is used for storage, and the church no longer plans to move in. "It would be nice to have it back to where it was in 2006 - about three-quarters full," said Steven Ballinger, who has maintained a Princeton University Press sales office in the building ...
Tag(s): 812 S.W. Washington Street Portland Oregon United States • Aaron Spencer • Daily Journal of Commerce (Oregon) • Gwen Mayfield-Barnard • Ideal Org • Membership • Oregon • Real estate • Steven Roy Crandell
Real estate roundup — Portland Business Journal
Source: Portland Business Journal
... The Church of Scientology of Portland leased 16,000 square feet at the Century Building and Century Tower after moving out of its long-time home at the Western Building in downtown Portland. The Western Building, home to the Scientology church since 1974, is being renovated for a bank tenant. The Century Building will be the church's temporary home while it prepares to renovate the Stevens Building, which it acquired in January. ...
Tag(s): 812 S.W. Washington Street Portland Oregon United States • Oregon • Portland • Portland Business Journal • Real estate
$5M purchase paves way for Helmer building renovation — Portland Business Journal
Author(s): Wendy Culverwell
The Church of Scientology is out and California-based First Republic Bank is in as a new owner takes control of the historic Helmer building in the heart of downtown Portland. The Goodman family, which owns or controls numerous commercial sites in downtown, closed its purchase of the Helmer building at 969 S.W. Broadway on July 25 in a deal worth about $5 million. The two-story building takes its name from its most prominent retail tenant, John Helmer Haberdashery, and also is ...
Tag(s): 812 S.W. Washington Street Portland Oregon United States • Gwen Mayfield-Barnard • Oregon • Portland Business Journal • Real estate • Wendy Culverwell
Scientologists' tall new home — The Oregonian (Portland)
Author(s): Stephen Beaven
Tag(s): 812 S.W. Washington Street Portland Oregon United States • Church of Scientology of Portland • Gwen Mayfield-Barnard • Ideal Org • Membership • Oregon • Portland • Real estate • Stephen Beaven • The Oregonian (Portland)
Church of Scientology buys Stevens Building — Portland Business Journal
After a years-long search for a building to call its own, The Church of Scientology of Portland has acquired the historic Stevens Building in an all-cash deal for $5.38 million. The sale was fueled by donations from church members. At 12 stories, it is the tallest building ever acquired by a local chapter of the Church of Scientology, according to Butler Brokers Commercial Realtors, which handled both sides of the transaction. In November, former owner Joseph Weston donated the building, which ...