The majority of Americans—55 percent—see American democracy as weak, and two-thirds of Americans believe it is getting weaker, according to The Democracy Project, a national survey jointly commissioned by Freedom House, the George W. Bush Institute, and the Penn Biden Center for Diplomacy and Global Engagement. How did we get here, and what role should philanthropy play in building and strengthening American democracy?
Join your fellow AGF members to hear from Freedom House President Michael J. Abramowitz and Chief Development Officer Nicole Surber who will highlight key findings drawn from 10 focus groups across the country including Arizona and place United States democracy in a global perspective.
Together, we will delve into philanthropy's role in reinforcing the values of democracy, discuss how we define democracy building and civil society, and explore how AGF members support these areas.
Staff at all levels from AGF member organizations that currently fund or are interested in funding issues related to democracy and civic engagement are encouraged to attend.
Before joining Freedom House in February 2017, Michael was director of the U.S. Holocaust Memorial Museum's Levine Institute for Holocaust Education. He led the museum's genocide prevention efforts and later oversaw its public education programs.
Nicole brings more than 20 years of nonprofit fundraising experience to her role at Freedom House. Most recently, she served as senior director of philanthropic partnerships at the Pew Charitable Trusts. At Pew, Nicole managed a portfolio of her own and was responsible for a team of 14 frontline fundraisers representing all of Pew's core programmatic areas (environment, domestic policy programs and the Pew Research Center) with annual philanthropic revenue of more than $50 million.
Prior to Pew, Nicole worked as the inaugural director of partnerships at the German Marshall Fund of the United States. Nicole has a bachelor's degree in sociology with a minor in religious studies from the University of Maryland, Baltimore County.
Freedom House is an independent watchdog organization dedicated to the expansion of freedom and democracy around the world. Freedom House analyzes the challenges to freedom, advocates for greater political rights and civil liberties, and supports frontline activists to defend human rights and promote democratic change. Founded in 1941, Freedom House was the first American organization to champion the advancement of freedom globally.
Thank you to Virginia G. Piper Charitable Trust for making this AGF program possible.
If you are an AGF member located outside Maricopa County interested in participating in this program via teleconference, please contact Director of Member Engagement and Operations Kalisha Bass.
This entry was posted in Uncategorized on January 1, 2019 by Kim Garbacz.


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The Late Adam West at the Height of His Post-Batman Glory
Buzz Adams Published: June 14, 2017
Adam "The One True Batman" West passed away on Friday at the age of 88. Adam West is beloved by many generations of Batman fans. And he's always been genuinely appreciative of his fans. A true gentleman. He will be sorely missed.
You may not know this, but Adam West continued to appear as Batman for years after the show was cancelled.
Like in the following clip from 1976 when he appeared on local wrestling in Memphis to promote a car show that both he and Jerry "The King" Lawler would be appearing. Either he wasn't allowed to wear the actual costume or he had long outgrown the original suit from eating too many Bat-snacks. One of those has to explain why he's wearing a warm-up suit. Oh, also he's about halfway in the bag which explains his slightly slurred speech and his willingness to mix D.C. and Marvel references. Enjoy this video. It's a classic.
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redpajama_set_name: RedPajamaCommonCrawl


• (a.) Having to duct or outlet; as, a ductless gland.
(dukt´lәs) having no excretory duct.
Duct'less adjective Having to duct or outlet; as, a ductless gland.
Type: Term Pronunciation: dŭkt′les Definitions: 1. Having no duct; denoting endocrine glands having only an internal secretion.


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What Is A Video Game Walkthrough? (2)
May 27, 2018 January 11, 2017 Richard Andrew
MajorSlackVideos is my Youtube channel committed to GENUINE video game walkthroughs. An instructional video recording by a dedicated gamer who is playing by means of a video game following learning how to play the game properly with reside running commentary of precisely why he is performing what. That's due to the fact 5 years from now, Youtube will be so inundated with blind playthroughs masquerading as walkthroughs (as if it is not currently) that gamers the globe over will have adopted (A) as the only definition they ever knew. Depending on the game for which you build a walkthrough, it s critical to aid your viewers fully grasp which character, car, weapon or accessory is very best and why.
Game Walktroughvideo, walkthrough
Fun While Working Together as a Team
Pokemon Sun & Moon Pokedex QR Codes! Entries 1
Uncover All Hidden Orb Collectibles And The Secret Ending
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Browsing for recommendations and walkthroughs for something from Skyrim to League of Legends? This, above all,...
Day Journey By means of Social Engineering
We've got 1,709 Cost-free walkthroughs, guides and options on all formats which includes PS2, PS3, Xbox...
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Who is not a victim of procrastination, specifically when it comes to World-wide-web usage? The guide...


The tortilla española is a fan favorite at La Diosa Spanish Bistro.
LUBBOCK, Tex.—With over 1,000 eateries within the Lubbock city limits, there is always an abundance of good food to choose from. The quandary then becomes what type of experience do I want? After speaking with a number of Lubbock restaurant owners, I found starting such a business isn't always about the money. It's about purpose, service and of course good food.
It's no secret that I'm a big guy. To look at me, you would not expect me to be a persnickety eater. Whatever I sit down to needs to appeal in concert to my eyes, nose and taste buds. The atmosphere needs to be calming and or inviting.
Finally, once a meal is served I, have three rules. (1) Don't stare at me or my food. (2) Don't ask me about my food. (3) Matter of fact, don't talk to me at all until my meal is masticated and digested.
I broke all three on a recent trip to Lubbock.
Cast Iron Grill patrons place their meal order.
Many patrons know the Cast Iron Grill for the boots, pies and chicken fries. Owner Teresa Stephens says the hometown restaurant with pretty girls in boots has a divine mandate.
As fate would have it, another diner in the same location had closed and was up for grabs. A family member first offered the restaurant as a co-venture to Stephens' husband. Already too busy with his automotive dealership, he politely declined. Teresa thought maybe this was the opportunity she had been waiting for.
Four weeks later, with a $13,000 investment from her husband, the 55 seat diner was open for business. The Cast Iron Grill's menu has a wealth of country homestyle food for modest prices.
Pies are their specialty at Cast Iron Grill. Regular customers say if you don't get there by Noon these sweet treats are gone.
One thing the Cast Iron Grill has become famous for is their assortment of pies. A novice baker at the time, Stephens' first inclination was to never serve the sugary staple in her diner.
As time passed, Stephens perfected her culinary craft and demand for her pies grew like yeast. During the 2015 Christmas season, Cast Iron Grill sold more than 700 pies.
Personal Note: I'm not a pie person; but I found something on her menu that I thought was even better than the pie I never put my fork to… a knockout brownie.
After being stuffed by a deceptively light vegetable omelet and wheat toast, I decided to get my dessert to go. My very helpful server recommended the Mississippi Mud Brownie. I consented and thought nothing more of it. Later that night I was in chocolate heaven. In my experience, any baked chocolate concoction is always too dry, too sweet, not sweet enough or falling apart. There's just no pleasing me.
Until now. Even in a standard styrofoam container, the generous cut of brownie drenched in marshmallow, fudge, a light garnish of coconut shavings and pecans was more decadent than one would expect at some four star resorts. Matched with a steaming cup of decaf and the 500 thread count sheets at the Overton Hotel, made for very sweet dreams.
Opened in 2007, Cast Iron Grill now employees 25 cooks and servers..
When Stephens and her brother-in-law opened the doors of the Cast Iron Grill on September 11, 2007, it was in a very different part of town than her current 167 seat location. Some would call the area undesirable. She called it home.
There were a number of homeless individuals outside the building. At that time, it was known as 'tent city'. Looking out over of the landscape of urban blight seven years ago, Teresa knew that her year long prayer for divine purpose had been answered.
Her job was to feed body and soul. She met Father Barry Ferguson of St. Benedict Chapel. In 2007, St. Benedict began feeding the homeless on a consistent basis once a week. They partnered and began to feed about 30 men on a weekly basis.
These aren't your run of the mill dinners for the transient. Now the ministry is numbering about 160 meals each day. There are no paper plates, no buffet lines or hermetically sealed TV dinners. Diners are welcomed to the facility and seated and served.
Everyone is welcome at St Benedict on any feeding night.
"Everyone just wants to have dinner with friends," Stephens said. Meals are not limited to the homeless. There is no sign in sheet. Anyone having financial difficulties who desires a good meal without the fuss is welcome.
"They [working poor] can barely pay their rent and cover their utilities, but they can't feed their families," she explained.
Meals have increased from just Mondays to every day of the week at 5 p.m. Six other Lubbock churches have now sponsored days to serve the community.
"The Lord brought me eight additional people from other congregations to help serve." Stephens beamed even more when talking about her nonprofit work than when talking about her thriving restaurant that employs 25 people.
"We are the only Lubbock business to serve there, so the other congregations just call us St. Cast Iron," she laughed.
Cast Iron Grill isn't the only Lubbock locale with great food, atmosphere and history. Below are some other stops I would recommend.


DMW Records presents it's second track of the year titled "Aje" the track features DMW frontman Davido, Singer Peruzzi, DMW Producer Fresh and Yonda who dropped Sexcellency recently.
Shockingly just few DMW Crew did the "AJE" song, Davido who's the brains behind the track show monstrous melodic ability on "Aje" trailed by DMW Deepest Singer Peruzzi and Yonda, Fresh delivered the beat, "Aje" was debuted continuation of the achievement of "Mind" which enrolls Mayorkun, Dremo and Peruzzi.
DMW Aje Mp3 Download Feat. Davido Peruzzi, Yonda and Fresh and Stream below.


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토글 내비게이션 Menu
단체 후원 방법
New Legal Defense Fund Helps Defend Self-Managed Abortion
Wednesday, June 23, 2021 블로그 Share
Will cover legal fees for people prosecuted for ending their own pregnancies
If/When/How, the non-profit that runs the Repro Legal Helpline, has just launched a $2 million Repro Legal Defense Fund to help pay the legal expenses of people who face expensive, invasive court battles over self-managed abortion.
Even in states that are supposedly solidly pro-choice, aggressive police and prosecutors have twisted existing laws to investigate, arrest, and prosecute people for ending their own pregnancies or helping other people end theirs. The people who are usually targeted for this are – surprise! – low-income, non-white, LGBTQ+, or otherwise marginalized, and they often struggle to find and afford a lawyer to defend them. As the first fund of its kind, the Repro Legal Defense Fund will cover costs like bail, expert witnesses, court fees, and attorney fees and ensure they have a robust defense.
Given the increasing restrictions across the US on abortion access through clinics, it's likely that more and more people will choose DIY abortion with pills or other methods. And that means more and more people will be at risk of being prosecuted for ending their own pregnancies – not just in the five states that have explicit laws against it, but anywhere with laws that can be contorted into criminalizing a pregnancy that doesn't result in a live birth.
If you're being targeted by the legal system for self-managing your own abortion or helping someone else self-manage their care, you can contact the fund directly for help from its legal experts and advocates, whether or not you already have an attorney. And if you have some cash to spare, please donate to make sure the Repro Legal Defense Fund can help as many people as possible!
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Don Keough was a hugely influential executive who helped shape Coca-Cola as it is today. Keough, who died on Feb. 24, was involved in many pivotal events during his long career. But no incident was bigger and more challenging than the ill-fated launch of New Coke 30 years ago today.


POQUOSON, Va. – Friday night lights brought more than just two local high school football teams together, it also brought out local veterans among the community to honor the sacrifices made once upon a time.
At Poquoson High School's home win over Warhill High School in Williamsburg, the community honored members of the Poquoson Veterans Project.
According to the Poquoson Veterans Project's website, the goal of the project is to bridge the gap and build relationships between the high school students and their veterans, while educating both the students and the community of the significance of these and all veterans' sacrifices.
The founder of the Poquoson Veterans Project's is Becky Morrison, an 11th grade U.S. history teacher at Poquoson High School.
As part of the project, Morrison's Advanced Placement United States History students are paired with American military veterans, whereby students "adopt" a veteran. The students interview their assigned veteran and create a written, video, and map history of their veteran's journey through military service and his or her impact on world events that the students learn about in the classroom, according to Poquoson Veterans Project's website.
To learn more about the Poquoson Veterans Project, click here.


There have been times since I created this blog that I have been curious about my place in Internet searches for images of a shrunken man. My blog used to be a blip in the vastness of results, but now I'm at the top, baby! Well, trinket is at the top, since it's one of his images, but it's in my blog! Yeah, take that, er… other sites!
Who better to become the soundtrack of this post than one of my all-time favorite groups, Foreigner. I remember when I was a young girl and boys would be shocked that I knew who Foreigner was, and what the word meant. Seriously, parents of tomorrow, stop reading Cosmo, because some women are from Mars, and they know Storm Troopers are not robots. In fact, some of them know Yoda's first name. And don't miss my next episode of Soap Box! The topic will be, "Why J. J. Abrams is an idiot that doesn't know anything about women".
Congratulations! It's nice to play the game of "Google Likes Me" and come up a winner.
Congrats, Undersquid! Fantastic. You do indeed have a great site, and it's only fitting that you're above all others. 🙂 Well done!
our queen and owner is the best!
I already knew you were number one, but now it's official since google has finally recognized it!


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Review: The Family Next Door
Summary: Small, perfect towns often hold the deepest secrets.
From the outside, Essie's life looks idyllic: a loving husband, a beautiful house in a good neighborhood, and a nearby mother who dotes on her grandchildren. But few of Essie's friends know her secret shame: that in a moment of maternal despair, she once walked away from her newborn, asleep in her carriage in a park. Disaster was avoided and Essie got better, but she still fears what lurks inside her, even as her daughter gets older and she has a second baby.
When a new woman named Isabelle moves in next door to Essie, she is an immediate object of curiosity in the neighborhood. Why single, when everyone else is married with children? Why renting, when everyone else owns? What mysterious job does she have? And why is she so fascinated with Essie? As the two women grow closer and Essie's friends voice their disapproval, it starts to become clear that Isabelle's choice of neighborhood was no accident. And that her presence threatens to bring shocking secrets to light.
The Family Next Door is Sally Hepworth at her very best: at once a deeply moving portrait of family drama and a compelling suburban mystery that will keep you hooked until the very last page. -- St. Martin's Press
I could have easily chosen to review THE FAMILY NEXT DOOR by Sally Hepworth for my Mystery Mondays feature because there is definitely an element of mystery surrounding the main characters in this novel. However, I think this book will appeal more to readers who appreciate well-crafted novels about families and suburban drama.
Essie seemingly has it all -- a great husband, two beautiful daughters, a nice house and a mom who lives nearby and helps with her kids. What more could a woman ask for, right? But things aren't quite what they seem. Essie suffered from a serious breakdown after the birth of her first child, and she even left her baby behind at a public park. She got the help she needed, but with the birth of her second child, she lives with the fear that she will have another breakdown.
And then Isabelle moves onto Essie's street, and Essie suddenly fears different -- more alive if you will. Everyone is curious about a single woman renting in the neighborhood when there are all families who have bought their houses, and even Isabelle's job seems to be a bit of a mystery; however, Essie is charmed. She becomes almost obsessed with spending time with Isabelle despite warnings from her friends and mother, and it's not until later that Isabelle's presence in the neighborhood makes sense.
THE FAMILY NEXT DOOR is a compelling story about women who live in a "'perfect" neighborhood" but have many secrets. Both Essie and Isabelle are definitely not what they seem and definitely represent that appearances can be deceiving. I enjoyed this novel and its characters quite a bit and definitely thought the novel was intriguing. The ending was packed with quite a few surprises and I think many readers will be kept guessing about these women's past actions.
The story was told in alternating chapters through the voices of various characters in the novel, and I thought the author did a good job in bringing each woman's character to life. I felt as if I got to know each of the characters as well as their secrets, and I was definitely vested in each of them.
At its heart, THE FAMILY NEXT DOOR represented that everyone has secrets that threaten to come out no matter how much we try to hide them. Each of the woman in this story were flawed and trying to cope with having imperfect lives which many readers will relate to. However, some of the secrets these woman were hiding were pretty dramatic (much more so that the average woman.) I appreciated the intriguing stories that these woman were hiding, and they definitely made for good reading!
Fans of Liane Moriarty and even the show Desperate Housewives will want to check out THE FAMILY NEXT DOOR.
Thanks to the publisher for providing a review copy of this novel.
Labels: Advance Readers Copy, Book Clubs, Fiction, Mystery, Review
This was my first Hepworth and I liked it a lot. I want to read more of her work now.
Lloyd Russell said...
This is the 4th Hepworth, and I have now read them all. This is a very good book that I enjoyed a lot. I would have to say, though, that I liked the 1st 3 just a smidge more. Admittedly there's not much to choose from among the 4. Just read them all in any order that you want.
Review: The High Tide Club
Review: Look for Her
Kid Konnection: Mama's Belly
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Review: Tangerine


Camel Press is delighted to announce that Johnnie Come Lately, a work of women's contemporary fiction by Kathleen M. Rodgers, is now available in audiobook. The narrator is Grammy award-winning vocalist and former Broadway actress Leslie Ellis.
BriefingWire.com, 6/01/2016 - Seattle, WA.—Camel Press is delighted to announce that Johnnie Come Lately ($14.95, 292 pp., ISBN: 978-1-60381-215-3), a work of women's contemporary fiction by Kathleen M. Rodgers, is now available in audiobook. The narrator is Grammy award-winning vocalist and former Broadway actress Leslie Ellis, www.leslieellis.com.
Bloggers interested in reviewing the audiobook should contact info@camelpress.com.
The audiobook is available on Audible.com, Amazon.com, and iTunes as well as their global retail partners.
The book Johnnie Come Lately has received several awards in the past year, including First Place in Women's Fiction for 2016 Texas Association of Authors Best Book Award Contest, a gold medal in the Military Writers Society of America 2015 Book Awards, and a bronze medal in the Readers' Favorite 2015 Book Awards–Women's Fiction Category. The cover of Johnnie Come Lately was one of eight winners in the Southern Writers Magazine's Cover Contest.
Kathleen lives in a suburb in North Texas and is represented by Jeanie Loiacano of Loiacano Literary Agency. Kathleen has a particular connection with the military; her husband is a retired fighter pilot/commercial airline pilot and her youngest son is a former Army officer who deployed to Afghanistan in 2014. Her first novel, The Final Salute, takes place on an air force base.
Johnnie Come Lately is also available in eBook and 5x8 trade paperback formats online at BN.com, Amazon.com, the European Amazons and Amazon Japan. Bookstores and libraries can order through Ingram, Baker & Taylor, or by contacting info@camelpress.com or Brodart. Other eBook formats are for sale on Smashwords.
ABOUT Camel Press—Based in Seattle Washington, Camel Press is the genre imprint of Coffeetown Enterprises, Inc. We publish genre fiction: romance, mystery/suspense, science fiction, and women's fiction—the books that grab you and hold you in their grip long into the night.


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5 Girl Groups You Should Be Listening to, Based on Artists You Already Love
Last Updated on January 31, 2019 by Brianna - University of Florida
Girl groups have been a music staple since the 1960s. A great blend of talented voices plus some girl power can create a killer combination. Girl groups tend to go all in with their performances, too, with cute outfits and amazing choreography. In recent years, girl groups have made a comeback with more popping up on the charts every year.
Is there a girl group void in your music library? It might be because you don't know where to start listening. If the last girl group you remember listening to is The Spice Girls, here's my list of the best girl groups, with recommendations based on the artists you already love.
If you like Ariana Grande, listen to Fifth Harmony
Fifth Harmony are one of the most popular girl groups on the scene right now, so you've probably heard at least one of their songs. Still, if you listen to more of their music, you might find yourself invested enough to become a fan.
Ariana Grande and Fifth Harmony both produce powerful pop anthems. Ariana's Break Free and Dangerous Woman are radio-heavy bops not unlike Fifth Harmony's Worth It and Work from Home.
Now's a great time to get into Fifth Harmony because the group's sound is evolving on their most recent self-titled album, the first release since Camila Cabello left the group.
If you like Rita Ora, listen to Little Mix
Who doesn't love a British group from The X Factor? Little Mix are known for their coordinating outfits and fun pop tracks. They're about to release a new song, too, so there's no better time to start listening.
Rita Ora and Little Mix both combine fashion and confidence in the way they present themselves. Songs like Rita Ora's Poison and Little Mix's Black Magic are a perfect additions to your summer playlist.
If you really want to get into Little Mix, watch videos of some of their energy-packed live performances. Their fun, lively personalities make them all the more enjoyable.
If you like Bon Iver, listen to The Staves
This pick is different from the previous girl groups in that it isn't focused on a pop sound. However, if you're in need of some acoustic vibes, The Staves have some great songs for you.
Bon Iver's folky tone and solid harmonies on tracks like Skinny Love and Holocene have a lot in common with The Staves, a group made up of sisters. Songs like Mexico and Make It Holy will give you the same vibes as your favorite coffee shop's playlist.
The Staves are a great group to give a try if you're looking for something different from your favorite pop anthems.
If you like BTS, listen to Red Velvet
The idea of listening to a Korean pop group can be a little intimidating if you're not already into the style of music. However, BTS is currently enjoying a larger American following with the success of their song Mic Drop and their performances on award shows like the AMAs. K-pop girl groups deserve their turn in the spotlight, too!
Red Velvet songs like Peek-A-Boo are so catchy and danceable that you'll find you don't need to understand all the words to enjoy them. Being a fan of K-pop is cool because the groups have their own sense of style as well, and usually perform intricate choreography in their music videos and live performances.
If you like Lorde, listen to HAIM
Another sister group, HAIM blends some rock with their pop sound. They combine some of the traditional elements of girl groups (choreography, coordinating outfits) with the driving sound of rock 'n' roll.
Like Lorde, HAIM gives off a total girl power vibe that is largely based on confidence and owning who you are. Songs like Lorde's Supercut and HAIM's Want You Back are perfect for driving around with the windows down.
The sisters all have great personalities, too, which is part of what makes it so fun to be a HAIM fan.
Is there a girl group that you love? Any girl groups you'd recommend to other CF readers? Let me know in the comments!
Tags : Ariana Grande, K-Pop, Lorde, music
Originally published on June 20, 2018
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Handong's Honey says
I would also suggest k-pop girl groups like Dreamcatcher (rebranded themselves from the saccharine sweet MINX to a darker, edgier "rock/metal" feel), and LOONA, a group of 12 members with an amazing, overarching mythology/backstory. They haven't officially debuted but each member has released a solo and there have been three subunits (including one with a feature by Grimes – my personal favourite is the Odd Eye Circle). Also, Kim Lip's song "Eclipse" was used on NASA's official solar eclipse playlist!
Ana Seip says
Personally, I think people who like BTS are more likely to enjoy BlackPink than Red Velvet. Red Velvet is good (Bad Boy is my personal fav) but is a lot more "pop" sounding. BlackPink has that edge that BTS has, and a more rock and hip hop feel to the music. They are my favorite girl group and BTS my fav boys!!!


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Why Daenerys Targaryen Deserves to Win GAME OF THRONES
Who do we most want to see emerge victorious and seize the Iron Throne? Before Game of Thrones' final season, we're making the case for every worthy candidate still standing, this time looking at Daenerys Targaryen.
Daenerys Targaryen grew up homeless and on the run in a foreign land. Her father, the Mad King, and her older brother Rhaegar were killed during Robert's Rebellion, ending her family's dynasty that had united the Seven Kingdoms under one rule for three centuries. Her mother died giving birth to her. And her brother Viserys bartered her away to Khal Drogo in exchange for an army. But from the ashes she emerged with three dragons, and along with guile, strength, and sheer force of will, she has since climbed step-by-painful-step to become the most powerful person, man or woman, anywhere. It has been a remarkable ascension, one that has led her back to the land her family once ruled to try to take back the Iron Throne.
Here's the case for why the Mother of Dragons should be the one to reclaim the seat forged by House Targaryen.
Qualifications and Experiences
She has the name when it comes to ruling Westeros, and for what she lacks in personal experience of living in the Realm, she has the perfect Hand of the Queen to fill in the gaps. That alone would be enough to qualify her, but that was also true of her idiot brother Viserys, who wasn't qualified to do anything. Except for her temper, she's certainly nothing like him. She's smart, capable, kind, and a survivor.
Like her ancestor Aegon, Daenerys is also a conqueror. From wandering lost in the Red Waste to leaving Qarth with riches, she and the Unsullied left Astapor in ruins, took Yunkai, and mastered Meereen. Along her rise through the former Slaver's Bay, her time in the newly named Bay of Dragons proved she knows the value in mercy (letting many great lords and families live), the value in justice (punishing the slavers who crucified innocent children to send her a message), and the value in destroying your enemies by any means necessary (burning the khals). While her time in Meereen was fraught with problems, some of them of her own doing, those obstacles were also a great learning tool. She knows the pitfalls and troubles of ruling, and that leadership means making difficult decisions you don't want to.
No one in Westeros, not even Cersei Lannister, who has ruled over only a small part of the land, knows what it's like to truly conqueror and deal with the fallout of being in charge after. Daenerys' experiences, even in Westeros where her military failures have been devastating, have been difficult, dangerous, and full of heartache, but each obstacle has been another learning experience.
Her good heart and empathy for those who suffer under the weight of the powerful, which she experienced as a child, is why she engenders loyalty and love in her people who will follow her everywhere. She does not make people her subjects; they choose her as their leader because they believe in her, the true mark of greatness.
She also managed to unite every khalasar behind her, giving her the control of one of the most fearsome forces in the world, something no Dothraki was ever able to achieve. Oh, and she also is the Mother of Dragons, the most powerful creatures in the world. That's pretty good. Dragons are definitely a plus.
Speaks High Valyrian and Dothraki
Can't be burned
Can eat a horse heart
Why don't we let Missandei handle this one:
"Daenerys Stormborn of House Targaryen, rightful heir to the Iron Throne, rightful Queen of the Andals and the First Men, Protector of the Seven Kingdoms, the Mother of Dragons, the Khaleesi of the Great Grass Sea, the Unburnt, the Breaker of Chains."
Even without all of her accomplishments and loyal subjects abroad, as the last known living Targaryen she has an unquestioned claim to the Iron Throne. While true that no previous Targaryen woman is officially recognized as having ever ruled as Queen (sorry Rhaenyra), Daenerys would have an overwhelming argument that the seat and title only exists because of her family. Plus, she is the only one alive who could inherit it in the traditional Westerosi way. Since Robert Baratheon left no rightful heirs (sorry Gendry), and Cersei acquired the throne through marriage and death instead of blood, many would side with Daenerys' natural claim.
Plus, she has dragons. Really, that just can't be overstated. Just like dragons made Valyria the most powerful empire in the world, dragons won Aegon Westeros. Without them there would not be an Iron Throne to win.
Are we sure she's not crazy? Did you see her bathe Randyll and Dickon Tarly in dragonflame? That wasn't the first time she did that. Even if she's not nuts now, how can we be certain she won't go all "blood and fire" on anyone and everyone eventually? Her father wasn't always the Mad King; in his younger years he was a likable, charming monarch with a bit of a temper. Sound familiar?
Even if she's not cuckoo, does Westeros even want someone who brought the Dothraki to its shores? Where are they going to go when she rules? Are they going to be given castles that belong to ancient houses, or just roam the countryside murdering everyone? What's the endgame here, Dany?
Oh, and dragons also bring death. Lots of death. Westeros might be better off without them, period.
"First of Her Name…"
Daenerys walked into those flames with nothing more than three eggs and belief in herself. She walked out with three dragons, but that's far from the only reason she rose to where she is now. It took wisdom, patience, commitment, and courage. Her name alone gives her a claim to be Queen of the Seven Kingdoms, but her experiences and kind heart is why she would do a good job with that incredible and overwhelming responsibility.
If all of this has really been a game, no one has "won" more than Daenerys has. That's why the Mother of Dragons deserves to be the ultimate winner of the game of thrones.
daenerys targaryen, Emilia Clarke, Game of Thrones
Everything You Need to Remember About GAME OF THRONES Season 7
A History of Winterfell
New SONG OF ICE AND FIRE Illustration Shows the Legendary Giant Ice Spiders


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I'm a former New York-trained opera singer, a life-long musician, and currently an international jazz and classic blues singer. After years in the opera fast-track I followed my heart and returned to my roots. Boogie Woogie piano great, Albert Ammons, was my grandfather and tenor sax titan, Gene Ammons, was my uncle and I felt them urge me forward.
It was an exciting journey: Listening and watching others, developing a new style, growing artistically, and then discovering my true musical soul. When I travel, I notice how widely jazz is loved - and how it connects people. And that is what inspired me to create this CD, "GENEALOGY": A celebration of jazz music and a family legacy. This project honors the roots of jazz past, the present, and looks forward to the future - wherever it leads me.
To make this CD happen, I launched a Kickstarter campaign in April 2018. 85 wonderful people contributed and became an integral part of this project. I raised more than half of the funds needed to produce "Genealogy" and I am forever grateful. With that money, I am recording nearly all of the tunes I planned with most of the musicians. However, I'm still in need of help to raise the remaining amount. With that, I'll be able to complete recording all 12 tunes with all desired instruments, and I can fund reproduction of my CD.
The folks at Kickstarter sent out a message reminding me that even after the closing of the formal campaign, supporters may still make contributions to me directly. And so far, I've received an additional $500!
If you haven't already contributed, and would like to be a part of this exciting project, please contact me through this website on my CONTACT page. I hope we meet, either at a CD release party or on the road while I'm on tour. For more information, click GENEALOGY to find my Kickstarter page.


On the ISM, you can see that the name of the storage pool become "unlocated", and it will be failed to delete the pool.
First, enter the "support" mode, use the command "vxdisk list -o alldgs" to check if the all the data disks in the problematic storage pool are in the group of "sfsdg", and the status of "(sfsdg)" in the picture below show that the data disks are not in the group. For this situation, to make the data safe, we suggest to restart the device with a maintenance window.
Second, if all the data disks are in the gourp of "sfsdg", we can use the way as below to restore the device online.
2. With "support" mode, use the command "" to reset the storage pool.
Customer delete and add the same data disk to the storage pool repeatly, or they move one data disk between two storage pool frequently, which will make the flag of the storage pool reset.
We suggest to design all the configuration before initializing the storage.


text:
Procedural magic opens NG19
Anastasia Opara, procedural artist at Stockholm-based Embark Studios, will open this year's Nordic Game conference in Malmö, Sweden.
Embark Studios was founded in 2018 by industry veterans Patrick Söderlund, Johan Andersson, Jenny Huldschiner, Robert Runesson, Magnus Nordin and Stefan Strandberg.
On 22 May in the Unreal Theatre at Slagthuset, Anastasia Opara will open NG19 with her keynote "More Like This, Please! Texture Synthesis and Remixing from a Single Example".
In her talk, Anastasia will explore example-based generation though a lens of texture synthesis, and at the same time touch upon her long-term vision of enabling anyone to "program" by making art.
"We're thrilled that Anastasia Opara and Embark Studios will open NG19," says Nordic Game program director Jacob Riis. "Embark Studios is one of the best contemporary examples of the continuing expansion in scope and quality of the Nordic games industry, and Anastasia is a true wizard in her field. I'm sure her talk will leave the NG19 audience in a state of delighted awe."
"The games industry is such an interesting place right now," says Anastasia Opara. "I can't wait to meet new faces, see what other studios are up to and give you all a glimpse into some of the things we're tinkering with at Embark."
The Nordic Game conference is held annually in Malmö, Sweden. The 2019 edition of Nordic Game will take place on 22-24 May at Slagthuset, near Malmö city center and only minutes away from Copenhagen Airport. As the leading games conference in Europe, we have a lot to offer, including a program filled with the best speakers from the global industry and our own Nordic heroes, access to international exhibitors and 2000+ professionals, world-class hospitality and a host of networking events, such as MeetToMatch, Expo, Discovery Day, Nordic Game Awards, the new Dinner Experience and renowned Nordic Party.
About the Nordic Game conference
Impact Sessions expanded for NG19
Join the Games Capital Summit
Winners selected, April challenge
17/04/2019 NG191,374


You are welcome and I hope the horrendous rain stops for long enough to actually get them on the car.
Ebay has given me a full refund for the defective tyres, no strings attached (as should have been the case from square one, shady vendor's fault not eBay's).
I am under no obligation to return the tyres either, as that would be at further cost to me.
So basically the vendor can have the tyres back so long as they send me the money it will cost to have them unmounted from the rims (£40), which isnt likely.
I'll probably sell these superlights and buy those 7-spokes Not_Anumber has lent me, which i have just put on the car and they look AWESOME!
Pictures tomorrow, too tired now.
Arya2.0S wrote: too tired now.
They are off a Sierra so they require wheel spacers to give them the right offset for the Capri or else they'll rub on the struts, but yeah they look pretty sweet so im thinking of buying them with my refund money since the tyres on them have barely been used.
They need a clean and i'll likely do a light refurb on them with some sand paper and some rattle cans before i put them on the car for good.
Once i have tested them and found out for sure what is going on with this whole wobble situation i'll tart them all up and keep them on the car for good, and just keep my old 4-spokes as a back up as they have been a life saver during this whole tyre nightmare, plus its good to keep the originals for posterity.
Not_Anumber wrote: You are welcome and I hope the horrendous rain stops for long enough to actually get them on the car.
What a guy! Hope it helps sort the issue.
Oh btw, you dont have pneumonia now after getting drenched yesterday do you?
My shirt was soaked all the way through, had to put a plastic bag behind me so i didnt get my seat wet! I was tempted to drive home shirtless lol.
Still was pretty fun hanging out in the rain, im a bit crazy but i love the rain.
Believe me, so do I. Then i can finally sleep at night and not have to worry anymore.
No solution still as of now. The wheels and tyres Not_Anumber lent me made the problem even worse, the wobble was coming in at 40mph on those wheels.
It seems my assumption that the problem goes away on my old factory 4 spokes was also wrong, as i had to go on a semi-long journey the other day and got it up to motorway speeds and the wobble was there also on these old rims, but it came on at about 60 this time.
New rims and tyres the wobble came on at about 55/60 (these tyres were still defective but not the cause of the problem).
Borrowed Not_Anumber's 15 inchers and the wobble came on at 40.
Original factory 4-spokes with 10+ year old tyres on them, wobble comes on at 60.
Reason i thought the problem went away on my old 4-spokes is because sometimes the wobble eases depending on the camber of the road, so on the short section i tested it on these old wheels it must have been in its favour and gave my a false result.
I have found the steering rack mounting bushes are perished and are allowing the rack to move slightly side to side so will replace those next and get the alignment checked.
If that still doesn't fix it, well i haven't got a sodding clue! Looks like its a whole new steering rack even though the present one was only refurbished just over a year ago. Theres very minor play in the right hand steering arm as well, but this shouldn't be failing already after such a short time period. But apart from that theres literally nothing else left to check or replace!
If you get a chance, lift it up with wheels on a ramp (car weight on the wheels) and with a hefty screwdriver try to pry the inner end of the radius arms either way along the axis of the bolts. Soft bushes here could allow a small movement to increase at speed?
nigecapri wrote: If you get a chance, lift it up with wheels on a ramp (car weight on the wheels) and with a hefty screwdriver try to pry the inner end of the radius arms either way along the axis of the bolts. Soft bushes here could allow a small movement to increase at speed?
Thanks for the suggestion. Unfortunately I have no where I can do that since I don't know anyone with a ramp. I'll mention it to my mechanic however and see if he knows someone who does.
New poly steering rack mountings fitted.... zero difference.
I think i may have found my issue. The lower steering arm - the one that comes out of the rack itself and has the TCA's attached to it, or are they tie rod ends? Not sure, its the bit with the rubber gators and goes into the rack itself - has a lot of play in it on the right hand side. If you move the steering side to side, you can hear it clunking and if you put your hand on it you can feel it is notchy and not smooth as it moves side to side.
This is a refurbished rack less then 2 years ago, should have lasted much longer than this! Ive been told that you cant just replace or adjust the worn components inside the rack itself as the parts arent available hence why getting a whole refurbished rack is the only solution, but this info could of course be wrong.
Arya2.0S wrote: you can feel it is notchy and not smooth as it moves side to side.
Have you greased it up? I do believe that they are filled with oil originally. But it's common to take the gaiters off, grease it all up as you move the steering from side to side.
It would be worth making sure if the play is in the track rod itself (this is a part of the steering rack which emerges from the gator) or is the Track Rod End which is the balljoint which screws onto the end of the track rod and physically connects this to the front hub.
The Track Rod End. also variously known as the steering balljoint or track rod balljoint is a removable & consumable part. Ideally you want the play to be here as its the cheapest and easiest to fix.
To establish which it is I would say the sure fire way is to remove the balljoint from the hub (I have a ball joint splitter you can borrow) and check if the play is in the balljoint itself. Whilst this is disconnected you can also check for play in that side of the steering rack itself.
If the play is in the steering rack it maybe as cheap to try Niall, Martin etc for a reasonable 2nd hand rack rather than trying to rebuild yours.
I had a similar scenario last year on an MGB im rebuilding where there was a damaged but otherwise recently refurbished rack so I sourced a 2nd hand one which was sound as a pound but was cheap as it had damaged gators and reused the ones from the other rack.
I have not, might try that first.
Not_Anumber wrote: It would be worth making sure if the play is in the track rod itself (this is a part of the steering rack which emerges from the gator) or is the Track Rod End which is the balljoint which screws onto the end of the track rod and physically connects this to the front hub.
Im pretty certain its the rod itself and whatever it joins onto inside the rack. Theres no play in the track rod end.
Pretty sure ive tried the usual parts sources when i needed the rack last year and they didnt have any hence why i had to go down the refurbed route.
Gonna wait to get the alignment checked first before making a final decision anyway, but pretty sure this is the cause at this point.
There is a cheap rack on Ebay at present for £ 25 +£ 10 postage. You'd need to use the gators and track rod ends from your old rack, could be a way out.
Hmm, it seems the people who supplied me with the rack are willing to send out a replacement.
Thats an excellent result. I think this should make a very great difference and it shouldnt take long to swap the racks over.
When transferring the track rod ends from your old rack undo the locknut on one side first. You will need 2 spanners one for the locknut and the 2nd for the track rod end. Now start unscrewing the track rod end BUT be careful to count how many turns it takes to unscrew it entirely, if in doubt write this down.
Next, fully unscrew the locknut (you dont need to count the turns) and shift this over to the same side of the new rack. Screw it on far enough so you know it wont get in the way when you start to fit the track rod end.
Start to screw the track rod onto the new rack, using the same number of turns you counted when it was removed. hold it in place at this position then tighten the locknut against it using 2 spanners so you dont disturb the position of the track rod end.
Repeat for the other side then transfer the rack over and take the car for a drive once the ball joints, steering column clamp bolt and steering rack mounting bolts are all safely tightened.
Not_Anumber wrote: Thats an excellent result. I think this should make a very great difference and it shouldnt take long to swap the racks over.
Thanks for the awesome advice. What about the ball joints that are bolted onto the hubs? Do I need a ball joint splitter to get them off?
I don't have one if I do need one unfortunately.
Other than that it sounds like something I might actually be able to do myself, seems simple enough? How'd you get on with your leaf springs?
I have a ball joint splitter somewhere you are welcome to borrow, I'll let you know as soon as I can find it. If the rack was changed not that long ago there's every chance the track rod end will be quite easy to remove from the hub. Ive lent my torque wrench out but let me know if you need it and i'll get it back.
Still on the leaf springs this morning as I had to give up yesterday due to the rain. Most of the way through now.
Hoping to get to South Essex Fasteners for the sunroof screws in the week and i'll need to look at an exploded diagram of the sunroof to understand what bits i need to run smoothly. Id be very grateful if you could help with the paint on the sunroof sometime where it has scraped near that edge.


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Welcome to the 2018-2019 School Year. The Central Islip Board of Education, Administration, Faculty and Staff work to provide a safe and enriching educational environment so your children - our students, will experience positive and fulfilling learning experiences that will allow them to reach their maximum potential. Cutting edge curricula, music and athletic programs and opportunities in the arts and extracurricular activities, combined with substantive new initiatives, promise to make the coming school year an exciting one for all of us!
To this end, the Central Islip Union Free School District has undergone a 'Restructuring' which will address overcrowding, enrollment projections and enhance the educational process as we move forward. Our School District is now represented by six elementary schools: Alfano, Cordello, Morrow, Mulligan, Mulvey and O'Neill which will comprise grades kindergarten through six; Reed Middle School for grades seven and eight; and Central Islip High School for grades nine through twelve. All students enrolled in pre-kindergarten classes will attend Alfano Elementary School.
Also very exciting is an announcement made recently by Governor Andrew Cuomo, in which the Hamlet of Central Islip is the recipient of a $10 million Downtown Improvement Initiative which will further improve the value and quality of our community.
On September 27 the Community voted on a referendum to construct a wrought-iron colored fence with brick piers around the perimeter of Central Islip High School. The majority of the voting electorate approved this referendum. The fence will enhance our ability to control ingress and egress points onto the High School campus. The Board of Education and Administration will keep the Community updated as the project moves forward. On behalf of the Board of Education and Administration, I thank you for taking time to make your vote count.
Please refer to our School District Calendar and log on to the District Website at www.centralislip.k12.ny.us for a listing of Board of Education Meetings, as well as school related activities, concerts and athletic games.
It is my pleasure to serve as your School Board President. On behalf of the Central Islip Board of Education, Administration, Faculty and Staff, I thank you for giving us the opportunity to educate your children.


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The Movie Essay Buyers Club
Is Windows Film Maker Proper For You?
January 4, 2022 - admin
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Posted in Movie
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Watch Musical Films
November 29, 2021 - admin
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Newest Movie Assessment Of Bollywood, Hollywood And Regional Motion pictures
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November 6, 2021 - admin
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The Homefront In WWII Movies
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Vishal does a good job, and is very good in action episodes. Aishwarya Arjun made a good effort. Though she didn't have many scenes to accomplish, she made probably the most of his display time.Santhanam's comedy is good in his regular position. Action episodes have been designed and properly turned. It was through the second half, the film picks up speed, and makes it a little fascinating. DVD Rental Services – On-line film rental companies compared and contrasted. 10. You've got Obtained Mail. Tom Hanks and Meg Ryan come together once more in this romantic movie that could be a tribute to the web age through which we dwell. Each run bookstores, however Hanks' is a far larger chain of bookstores. Unaware of each other's real identities, they develop into mates via email, using fictitious IDs. Eventually, the 2 meet as their actual selves and fall in love.
Fear Of The Dentist
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Showing results for "Thomas Klobucher"
Transformation is the key to personal growth and fulfillment. Intellectually, physically, and spiritually, transformation is how we advance, achieve, and inspire others. Transformation is how we improve and reach new, higher levels in life. Transformation is healthy and stimulates learning, growth, and development.
Retirement: The Best Is Yet to Come provides the retirement roadmap for the time of your life! What is the secret to a successful retirement? Tom shares 25 bold steps to a happy, positive, fulfilled, and engaged retirement.
Go preach somewhere else. not for me.
Trace the trajectory of this resilient young man's harrowing transition from foreigner to fixture - from day laborer to successful entrepreneur - in his new country. Experience this moving account of the founding of a Slovenian-American family, as John woos and wins the love of his life, sets up his tailor shop in small-town America, and raises five children with his beloved bride in their modest home behind the shop.
Author Tom Klobucher introduces listeners to 37 secrets to a happy life and explains the many benefits of what he calls The Gentle Life.
Tales of Gratitude is a collection of positive short stories with happy endings that will inspire thankfulness in the young and the young at heart. Tom Klobucher's stories are a touching and optimistic take on the American Dream. Each of his heroes confronts towering obstacles and overwhelming odds with little more than the support of their families, their sheer determination, and their ever-grateful spirits.
Marriage - The Time of Your Life!
As you may have noticed, marriage is in crisis! Experts tell us that 50% or more of marriages in the US end in divorce. Living together prior to getting married, increases the likelihood of getting divorced by 40%. 43% of American children are being raised without their fathers. What really matters, Tom says, isn't what you expect to get out of the relationship, but what you expect to bring into it. The best marriage doesn't start with you looking outward at your spouse. Instead, Tom invites you to look inward, at yourself.


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Specializing in the works of Harvey Ellis, Gustav Stickley, Limbert, Roycroft, Greene & Greene, L. &. J.G. Stickley, Dirk Van Erp, D`Arcy Gaw and Rohlfs. Custom reproductions and antiques.
Arts & Crafts Hand Hammered Copper Mailbox with plaque reading O. Christensen
Fine Arts & Crafts Hand Hammered Copper Mailbox with plaque reading "O. Christensen". Beautifully designed and skillfully executed. Maker unknown, but the quality is equal to works from the workshops of experienced coppersmiths, possibly a talented student. Even Dirk Van Erp offered classes to the public and much of the student's work is very well done. The curved mitered corners and the hinged door would be very challenging for most students though. The back is made of galvanized steel sheet metal for it's resistance to rust. I always assumed that such metal was in use after the Arts and Crafts Movement. After researching I learned that Stanislas Sorel, in 1836 patented a process of cleaning steel and then coating it with zinc by dipping it into molten zinc. I don't have a key for the door at this time, but we have had keys made for items from this period by our local locksmith. The plaque could be removed and replaced with another name or, to preserve it's history, a plaque could be attached with two sided tape. Beautiful original patina, the image with the egg is the most accurate image. Measures: 9 3/4" tall x 7 13/16" x 1 3/4" deep.
The back is made of galvanized steel sheet metal for it's resistance to rust. I always assumed that such metal was in use after the Arts and Crafts Movement. After researching I learned that Stanislas Sorel, in 1836 patented a process of cleaning steel and then coating it with zinc by dipping it into molten zinc.
Most accurate color representation.


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Formula: C2H4
Molecular weight: 28.0532
IUPAC Standard InChI: InChI=1S/C2H4/c1-2/h1-2H2
IUPAC Standard InChIKey: VGGSQFUCUMXWEO-UHFFFAOYSA-N
CAS Registry Number: 74-85-1
Isotopologues:
(Z)-Ethylene-1,2-d2
Other names: Ethene; Acetene; Bicarburretted hydrogen; Elayl; Olefiant gas; C2H4; Athylen; Liquid ethyene; UN 1038; UN 1962
Reaction thermochemistry data (reactions 1 to 50)
Gas phase thermochemistry data
Condensed phase thermochemistry data
Reaction thermochemistry data: reactions 51 to 54
Henry's Law data
Ion clustering data
UV/Visible spectrum
Vibrational and/or electronic energy levels
Data at other public NIST sites:
Microwave spectra (on physics lab web site)
Electron-Impact Ionization Cross Sections (on physics web site)
Computational Chemistry Comparison and Benchmark Database
Gas Phase Kinetics Database
NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data)
Reaction thermochemistry data
Data compiled as indicated in comments:
B - John E. Bartmess
MS - José A. Martinho Simões
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
C2H3- + =
By formula: C2H3- + H+ = C2H4
ΔrH° 1704. ± 9. kJ/mol AVG N/A Average of 5 out of 6 values; Individual data points
ΔrG° 1677.8 ± 2.1 kJ/mol IMRE Ervin, Gronert, et al., 1990 gas phase; B
ΔrG° 1670. ± 8.8 kJ/mol H-TS DePuy, Gronert, et al., 1989 gas phase; B
ΔrG° 1668. ± 21. kJ/mol H-TS Peerboom, Rademaker, et al., 1992 gas phase; B
ΔrG° >1661.0 kJ/mol IMRB Froelicher, Freiser, et al., 1986 gas phase; B
C7H4CrO5 (g) = C5CrO5 (g) + (g)
By formula: C7H4CrO5 (g) = C5CrO5 (g) + C2H4 (g)
ΔrH° 105. ± 4. kJ/mol KinG McNamara, Becher, et al., 1994 The reaction enthalpy was identified with the activation energy.; MS
ΔrH° 103. ± 10. kJ/mol KinG Wells, House, et al., 1994 The reaction enthalpy relies on the measured activation energy and on the assumption of a negligible barrier for product recombination Wells, House, et al., 1994.; MS
+ = ( • )
By formula: Ag+ + C2H4 = (Ag+ • C2H4)
ΔrH° 141. kJ/mol HPMS Guo and Castleman, 1991 gas phase; Entropy change calculated or estimated; M
ΔrS° 92.5 J/mol*K N/A Guo and Castleman, 1991 gas phase; Entropy change calculated or estimated; M
Free energy of reaction
ΔrG° (kJ/mol)
71.5 750. HPMS Guo and Castleman, 1991 gas phase; Entropy change calculated or estimated; M
By formula: H4N+ + C2H4 = (H4N+ • C2H4)
ΔrH° 42. kJ/mol PHPMS Deakyne and Meot-Ner (Mautner), 1985 gas phase; Entropy change calculated or estimated; M
ΔrS° 84. J/mol*K N/A Deakyne and Meot-Ner (Mautner), 1985 gas phase; Entropy change calculated or estimated; M
15. 294. PHPMS Deakyne and Meot-Ner (Mautner), 1985 gas phase; Entropy change calculated or estimated; M
By formula: Co+ + C2H4 = (Co+ • C2H4)
ΔrH° 186. ± 9.2 kJ/mol CIDT Sievers, Jarvis, et al., 1998 RCD
Enthalpy of reaction
ΔrH° (kJ/mol)
179. (+7.1,-0.) CID Armentrout and Kickel, 1994 gas phase; guided ion beam CID; M
27. (+13.,-0.) CID Haynes and Armentrout, 1994 gas phase; ΔrH>=, guided ion beam CID; M
= +
By formula: C2H5Cl = C2H4 + HCl
ΔrH° 92.0 kJ/mol Eqk Levanova, Bushneva, et al., 1979 liquid phase; ALS
ΔrH° 71.5 kJ/mol Eqk Levanova, Bushneva, et al., 1979 gas phase; ALS
ΔrH° 72.6 ± 2.1 kJ/mol Eqk Howlett, 1955 gas phase; ALS
ΔrH° 71.5 kJ/mol Eqk Lane, Linnett, et al., 1953 gas phase; ALS
By formula: Cr+ + C2H4 = (Cr+ • C2H4)
ΔrH° 96. ± 11. kJ/mol CIDT Sievers, Jarvis, et al., 1998 RCD
125. (+19.,-0.) CID Armentrout and Kickel, 1994 gas phase; ΔrH>=, guided ion beam CID; M
By formula: Ni+ + C2H4 = (Ni+ • C2H4)
ΔrH° 182. ± 11. kJ/mol CIDT Sievers, Jarvis, et al., 1998 RCD
By formula: Cu+ + C2H4 = (Cu+ • C2H4)
95. (+11.,-0.) CID Armentrout and Kickel, 1994 gas phase; ΔrH>=, guided ion beam CID; M
By formula: Sc+ + C2H4 = (Sc+ • C2H4)
ΔrH° 220. ± 10. kJ/mol PDiss Ranashinge and Freiser, 1992 gas phase; M
131. CID Armentrout and Kickel, 1994 gas phase; ΔrH >=, guided ion beam CID; M
By formula: La+ + C2H4 = (La+ • C2H4)
90.0 CID Armentrout and Kickel, 1994 gas phase; ΔrH>=, guided ion beam CID; M
By formula: Y+ + C2H4 = (Y+ • C2H4)
109. CID Armentrout and Kickel, 1994 gas phase; ΔrH>=, guided ion beam CID; M
By formula: Ti+ + C2H4 = (Ti+ • C2H4)
By formula: V+ + C2H4 = (V+ • C2H4)
By formula: Fe+ + C2H4 = (Fe+ • C2H4)
By formula: C2H4 + Br2 = C2H4Br2
ΔrH° -120.9 ± 1.3 kJ/mol Cm Conn, Kistiakowsky, et al., 1938 gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -121.6 ± 1.3 kJ/mol; At 355 °K; ALS
By formula: C2H4 + I2 = C2H4I2
ΔrH° -48.1 ± 0.8 kJ/mol Eqk Abrams and Davis, 1954 gas phase; ALS
ΔrH° -56. ± 2. kJ/mol Eqk Cutherbertson and Kistiakowsky, 1935 gas phase; Heat of dissociation; ALS
( • ) + = ( • 2 )
By formula: (Ag+ • C2H4) + C2H4 = (Ag+ • 2C2H4)
ΔrH° 136. kJ/mol HPMS Guo and Castleman, 1991 gas phase; M
ΔrS° 126. J/mol*K HPMS Guo and Castleman, 1991 gas phase; M
By formula: H2 + C2H4 = C2H6
ΔrH° -136. ± 2. kJ/mol Chyd Kistiakowsky and Nickle, 1951 gas phase; ALS
ΔrH° -136.3 ± 0.3 kJ/mol Chyd Kistiakowsky, Romeyn, et al., 1935 gas phase; ALS
By formula: C2H5Br = HBr + C2H4
ΔrH° 80.3 ± 2.1 kJ/mol Eqk Lane, Linnett, et al., 1953 gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 79.9 kJ/mol; ALS
C3H9Si+ + = (C3H9Si+ • )
By formula: C3H9Si+ + C2H4 = (C3H9Si+ • C2H4)
ΔrH° 98.7 kJ/mol PHPMS Li and Stone, 1989 gas phase; M
ΔrS° 161. J/mol*K PHPMS Li and Stone, 1989 gas phase; M
C2H4+ + = (C2H4+ • )
By formula: C2H4+ + C2H4 = (C2H4+ • C2H4)
ΔrH° 66.1 kJ/mol PI Ono, Linn, et al., 1984 gas phase; M
ΔrH° 76.1 kJ/mol PI Ceyer, Tiedemann, et al., 1979 gas phase; M
C6H4FeO4 (l) = 4 (g) + (cr) + (g)
By formula: C6H4FeO4 (l) = 4CO (g) + Fe (cr) + C2H4 (g)
ΔrH° 192.5 ± 8.4 kJ/mol HAL-HFC Brown, Connor, et al., 1976 MS
ΔrH° 185.4 kJ/mol TD-HFC Brown, Connor, et al., 1976 MS
By formula: C8H12 = C6H8 + C2H4
ΔrH° 136. kJ/mol Kin Huybrechts, Rigaux, et al., 1980 gas phase; Diels-Alder addition at 560°K, see Van Mele, Boon, et al., 1986; ALS
By formula: F- + C2H4 = (F- • C2H4)
ΔrH° 25. ± 13. kJ/mol IMRB Sullivan and Beauchamp, 1976 gas phase; Structure: Roy and McMahon, 1985; B
Rh+ + = (Rh+ • )
By formula: Rh+ + C2H4 = (Rh+ • C2H4)
161. (+3.,-0.) CID Chen and Armetrout, 1995 gas phase; guided ion beam CID; M
C7H9Cl2NPd (solution) + (l) = (PdCl2(C5H5N)2) (solution) + (solution)
By formula: C7H9Cl2NPd (solution) + C4H4N2 (l) = (PdCl2(C5H5N)2) (solution) + C2H4 (solution)
ΔrH° -57.7 ± 1.7 kJ/mol RSC Partenheimer and Durham, 1974 solvent: Dichloromethane; MS
(solution) + (solution) = C13H19O2Rh (solution) + 2 (solution)
By formula: C9H15O2Rh (solution) + C8H12 (solution) = C13H19O2Rh (solution) + 2C2H4 (solution)
ΔrH° -9.0 ± 0.4 kJ/mol RSC Jesse, Cordfunke, et al., 1979 solvent: n-Heptane; MS
(g) + C2H3BrMg (solution) = (solution) + Br2Mg (solution)
By formula: HBr (g) + C2H3BrMg (solution) = C2H4 (solution) + Br2Mg (solution)
ΔrH° -294.1 ± 2.2 kJ/mol RSC Holm, 1981 solvent: Tetrahydrofuran; MS
C6HCrO6+ + = (C6HCrO6+ • )
By formula: C6HCrO6+ + C2H4 = (C6HCrO6+ • C2H4)
ΔrH° 59.8 ± 5.0 kJ/mol ICRCD Hop and McMahon, 1991 gas phase; Ar collision gas; M
By formula: Al+ + C2H4 = (Al+ • C2H4)
ΔrH° 54.4 ± 8.4 kJ/mol CIDC,EqG Stockigt, Schwarz, et al., 1996 Anchored to theory; RCD
(CAS Reg. No. 25013-41-6 • 4294967295 ) + = CAS Reg. No. 25013-41-6
By formula: (CAS Reg. No. 25013-41-6 • 4294967295C2H4) + C2H4 = CAS Reg. No. 25013-41-6
ΔrH° 54.0 ± 8.8 kJ/mol N/A DePuy, Gronert, et al., 1989 gas phase; B
+ = +
By formula: H2 + C2H3Cl = C2H4 + HCl
ΔrH° -76.94 kJ/mol Chyd Lacher, Kianpour, et al., 1956 gas phase; At 298 K; ALS
By formula: C2H4 + Cl2 = C2H4Cl2
ΔrH° -182.6 ± 0.63 kJ/mol Cm Conn, Kistiakowsky, et al., 1938 gas phase; At 355 °K; ALS
= + +
By formula: C2H4ClI = I + Cl + C2H4
ΔrH° 320. ± 4.2 kJ/mol Kin Minton, Felder, et al., 1984 gas phase; ALS
(C2H4+ • ) + = (C2H4+ • 2 )
By formula: (C2H4+ • C2H4) + C2H4 = (C2H4+ • 2C2H4)
ΔrH° 18. kJ/mol PI Ceyer, Tiedemann, et al., 1979 gas phase; M
C12H14Mo (cr) + (cr) = C10H10I2Mo (cr) + (g)
By formula: C12H14Mo (cr) + I2 (cr) = C10H10I2Mo (cr) + C2H4 (g)
ΔrH° -163.0 ± 2.1 kJ/mol RSC Calhorda, Carrondo, et al., 1991 MS
(cr) + 2 (g) = (cr) + 2 (g)
By formula: C9H15O2Rh (cr) + 2CO (g) = C7H7O4Rh (cr) + 2C2H4 (g)
ΔrH° -53.6 ± 1.7 kJ/mol DSC Jesse, Baks, et al., 1978 MS
C9H15IrO2 (cr) + 2 (g) = C7H7IrO4 (cr) + 2 (g)
By formula: C9H15IrO2 (cr) + 2CO (g) = C7H7IrO4 (cr) + 2C2H4 (g)
By formula: (Fe+ • C2H4) + C2H4 = (Fe+ • 2C2H4)
By formula: (Cr+ • C2H4) + C2H4 = (Cr+ • 2C2H4)
By formula: (Mn+ • C2H4) + C2H4 = (Mn+ • 2C2H4)
By formula: (V+ • C2H4) + C2H4 = (V+ • 2C2H4)
By formula: (Ni+ • C2H4) + C2H4 = (Ni+ • 2C2H4)
By formula: (Co+ • C2H4) + C2H4 = (Co+ • 2C2H4)
By formula: (Cu+ • C2H4) + C2H4 = (Cu+ • 2C2H4)
ΔrH° 97.2 ± 2.5 kJ/mol Eqk Walsh and Wells, 1976 gas phase; ALS
By formula: 2C2H4 = C4H8
ΔrH° -86.6 ± 4.2 kJ/mol Eqk Quick, Knecht, et al., 1972 gas phase; At 750 K; ALS
By formula: C2H4I2 = C2H4 + I2
ΔrH° 48.1 ± 0.8 kJ/mol Eqk Benson and Amano, 1962 gas phase; ALS
By formula: C4H8 + C2H4 = C6H12
ΔrH° -69.9 kJ/mol Eqk Scacchi and Back, 1977 liquid phase; ALS
Go To: Top, Reaction thermochemistry data, Notes
Ervin, Gronert, et al., 1990
Ervin, K.M.; Gronert, S.; Barlow, S.E.; Gilles, M.K.; Harrison, A.G.; Bierbaum, V.M.; DePuy, C.H.; Lin, W.C., Bonds Strengths of Ethylene and Acetylene, J. Am. Chem. Soc., 1990, 112, 15, 5750, https://doi.org/10.1021/ja00171a013 . [all data]
DePuy, Gronert, et al., 1989
DePuy, C.H.; Gronert, S.; Barlow, S.E.; Bierbaum, V.M.; Damrauer, R., The Gas Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1989, 111, 6, 1968, https://doi.org/10.1021/ja00188a003 . [all data]
Peerboom, Rademaker, et al., 1992
Peerboom, R.A.L.; Rademaker, G.J.; Dekoning, L.J.; Nibbering, N.M.M., Stabilization of Cycloalkyl Carbanions in the Gas Phase, Rapid Commun. Mass Spectrom., 1992, 6, 6, 394, https://doi.org/10.1002/rcm.1290060608 . [all data]
Froelicher, Freiser, et al., 1986
Froelicher, S.W.; Freiser, B.S.; Squires, R.R., The C3H5- isomers. Experimental and theoretical studies of the tautomeric propenyl ions and the cyclopropyl anion in the gas phase, J. Am. Chem. Soc., 1986, 108, 2853. [all data]
McNamara, Becher, et al., 1994
McNamara, B.; Becher, D.M.; Towns, M.H.; Grant, E.R., J. Phys. Chem., 1994, 98, 4622. [all data]
Wells, House, et al., 1994
Wells, J.R.; House, P.G.; Weitz, E., J. Phys. Chem., 1994, 98, 8343. [all data]
Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W., The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes, Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T . [all data]
Deakyne and Meot-Ner (Mautner), 1985
Deakyne, C.A.; Meot-Ner (Mautner), M., Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives, J. Am. Chem. Soc., 1985, 107, 2, 474, https://doi.org/10.1021/ja00288a034 . [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]
Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]
Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]
Levanova, Bushneva, et al., 1979
Levanova, s.V.; Bushneva, I.I.; Rodova, R.M.; Rozhnov, A.M.; Treger, Yu.A.; Aprelkin, A.S., Thermodynamic stability of chloroethanes in dehydrochlorination reactions, J. Appl. Chem. USSR, 1979, 52, 1439-1442. [all data]
Howlett, 1955
Howlett, K.E., The use of equilibrium constants to calculate thermodynamic quantities. Part II, J. Chem. Soc., 1955, 1784-17. [all data]
Lane, Linnett, et al., 1953
Lane, M.R.; Linnett, J.W.; Oswin, H.G., A study of the C2H4+HCl=C2H5Cl and C2H4+Hbr=C2H5Br equilibria, Proc. Roy. Soc. London A, 1953, 216, 361-374. [all data]
Ranashinge and Freiser, 1992
Ranashinge, Y.A.; Freiser, B.S., Gas-Phase Photodissociation of MC2H2+ (M = Sc, Y, La). Determination of D0(M+ - C2H2), Chem. Phys. Let., 1992, 200, 1-2, 135, https://doi.org/10.1016/0009-2614(92)87058-W . [all data]
Conn, Kistiakowsky, et al., 1938
Conn, J.B.; Kistiakowsky, G.B.; Smith, E.A., Heats of organic reactions. VII. Addition of halogens to olefins, J. Am. Chem. Soc., 1938, 60, 2764-2771. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Abrams and Davis, 1954
Abrams, A.; Davis, T.W., Use of radioactive iodine to determine equilibrium constants in ethylene-iodine-1,2-diiodoethane systems, J. Am. Chem. Soc., 1954, 76, 5993-59. [all data]
Cutherbertson and Kistiakowsky, 1935
Cutherbertson, G.R.; Kistiakowsky, G.B., The thermal equilibrium between ethylene iodide, ethylene and iodine, J. Chem. Phys., 1935, 3, 631-634. [all data]
Kistiakowsky and Nickle, 1951
Kistiakowsky, G.B.; Nickle, A.G., Ethane-ethylene and propane-propylene equilibria, Faraday Discuss. Chem. Soc., 1951, 10, 175-187. [all data]
Kistiakowsky, Romeyn, et al., 1935
Kistiakowsky, G.B.; Romeyn, H., Jr.; Ruhoff, J.R.; Smith, H.A.; Vaughan, W.E., Heats of organic reactions. I. The apparatus and the heat of hydrogenation of ethylene, J. Am. Chem. Soc., 1935, 57, 65-75. [all data]
Li and Stone, 1989
Li, X.; Stone, J.A., Determination of the beta silicon effect from a mass spectrometric study of the association of trimethylsilylium ion with alkenes, J. Am. Chem. Soc., 1989, 111, 15, 5586, https://doi.org/10.1021/ja00197a013 . [all data]
Ono, Linn, et al., 1984
Ono, Y.; Linn, S.H.; Tzeng, W.-B.; Ng, C.Y., A Study of the Unimolecular Decomposition of the (C2H4)2+ Complex, J. Chem. Phys., 1984, 80, 4, 1482, https://doi.org/10.1063/1.446897 . [all data]
Ceyer, Tiedemann, et al., 1979
Ceyer, S.T.; Tiedemann, P.W.; Ng, C.Y.; Mahan, B.H.; Lee, Y.T., Photoionization of Ethylene Clusters, J. Chem. Phys., 1979, 70, 5, 2138, https://doi.org/10.1063/1.437758 . [all data]
Brown, Connor, et al., 1976
Brown, D.L.S.; Connor, J.A.; Leung, M.L.; Paz-Andrade, M.I.; Skinner, H.A., J. Organometal. Chem., 1976, 110, 79. [all data]
Huybrechts, Rigaux, et al., 1980
Huybrechts, G.; Rigaux, D.; Vankeerberghen, J.; Van Mele, B., Kinetics of the Diels-Alder addition of ethene to cyclohexa-1,3-diene and its reverse reaction in the gas phase, Int. J. Chem. Kinet., 1980, 12, 253-259. [all data]
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Go To: Top, Reaction thermochemistry data, References
T Temperature
ΔrG° Free energy of reaction at standard conditions
ΔrH° Enthalpy of reaction at standard conditions
ΔrS° Entropy of reaction at standard conditions


If you are accepted into the summer school, you will be expected to buy and read Introduction to Sport Marketing prior to the start of the summer school.
Either a hotel in the centre of Aarhus or a hotel outside of town. Further information will be available soon.
There is no tuition fee for the course if you come from one of our partner universities. Students that come from non-partner universities must pay 5000 DKK.
You must pay all other expenses in connection with the summer school in Aarhus.
If you are offered a place on this summer school, a non-refundable payment (750 DKK) must be paid in approximately mid-March in order to ensure your registration. This amount pays for some of the combined social activities etc. and will be for your benefit. We may require you to pay a little bit more later on in the process.


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Pearl Jam is providing an even flow for all its former drummers — even the ones not included in its Rock and Roll Hall of Fame induction.
The rock group invited each of the five percussionists who spent time as members of Pearl Jam to next month's inauguration ceremony, even though only two of them will be officially inaugurated into the hall.
"While awards and accolades are understandably subjective and a countless number of our peers have yet to be honored, we do feel fortunate to be recognized and provided the opportunity to reunite with everyone who has been part of the group," the band wrote in a hand-written statement shared to social media.
"Specifically the drummers who all left their distinctive mark on our band in the pre-Matt Cameron years," the "Even Flow" rockers continued.
Cameron, the current and longest-tenured drummer in the group, and Dave Krusen are the only drummers selected by the Hall of Fame voters to be included in Pearl Jam's induction.
Founding drummer Jack Irons, Matt Chamberlain and Dave Abbruzzese were not selected.
Abbruzzese, who was part of group from 1991 to 1994, voiced his outrage over being snubbed in October, shortly after Pearl Jam was nominated for a spot in the hall.
"The members of Pearl Jam have got to know what's the right thing to do," he wrote on his private Facebook page at the time. "They can't justify ignoring my contributions. Like me or not."
Pearl Jam is one of six acts being inducted into the hall this year, joining Tupac Shakur, Electric Light Orchestra, Yes, Joan Baez and Journey.
The induction ceremony takes place on April 7 at the Barclays Center in Brooklyn.