text:
C2h6o Lewis Structure
Open the Lewis Structure Drawing Tool, lewisdraw_authoring_2013. C:2x8=16 H:4x2=8 O:1x8=8 Total=32 Step3: Gives you bonding e-. Low prices at Amazon on digital cameras, MP3, sports, books, music, DVDs, video games, home & garden and much more. Download free Steel Structure Pdf Books and training materials. Draw Lewis structures for NCI3 and a hypothetical NCl5, and explain why NCl5 is an unlikely. The carbon-oxygen double bond of aldehydes are composed of one sigma() and one pi (π) bond like the double bond of alkenes. Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file The 3d structure may be viewed using Java or Javascript. In the Lewis structure, the carbon and oxygen atoms are surrounded by eight electrons (an octet of electrons, or four pairs), leading to the stability of these atoms in comparison to atomic C and O which have 4 and 6 outer shell electrons respectively. 0690 g/mol Convert between C2H6 weight and moles. Though many organic chemicals also contain other elements, it is the carbon-hydrogen bond that defines them as organic. Me3SiCl Me3SiC2H5. The production of ethanoll from starch or sugar-based feedstocks is among man's earliest ventures into value-added processing. First, draw the lewis dot structures of each. Historical data and info. In this lab you will practice writing Lewis structures for. Get the latest public health information from CDC: https. Hydrogen is a chemical element with atomic number 1 which means there are 1 protons and 1 electrons in the atomic structure. You do this by remembering "VSEPR". , in CO2, there are 4 + 6 + 6 = 16 VE 2. Download books free. PDF Drive is your search engine for PDF files. Write a Lewis structure for each of the following molecules. Draw the Lewis dot structure of NO2. What this place carrying, club-swinging, quick-stepping, nineteen-year-old-pot-shot patriots, have worn out their welcome in Italy. Additional information for writing Lewis Structures Lewis Structures that Show Bonding between Nonmetals 1. And the π bond is formed by the overlap of two unhybridized p. C6H6 in presence of anhydrous AlCl3. : Build and draw both the Lewis structure and a ball and spring picture for the following. Three are two ways to draw the Lewis structure for C2H6O. On the periodic table, Carbon is in group 4 or 14, so it has 4 valence electrons, but we have 2 of them. Structural and molecular modelling studies reveal a new mechanism of action of chloroquine and hydroxychloroquine against SARS-CoV-2 infection. nonbonding valence electrons. Marrow said: "Chawming climate out heah in the tropics, old chap. Lewis dot structure of CH4O consists of the Carbon atom being bonded to three of the Hydrogen atoms, and the Oxygen atom. C:4x2=8 H=1x6=6. Free delivery on millions of items with Prime. Although typically, this is actually not possible, as a dot-cross structure can only handle 2 elements in a compound with dots and crosses to indicate. ; Remember that Hydrogen (H) atoms always go on the outside of a Lewis Structure. Both use all 20 valence electrons and achieve full outer shells. 024 mol C2H6O There are about 11 moles in 508 grams of ethanol. The arrows point from the atoms with less electronegativity to the atoms with the higher electronegativity. symbol for the element. com site to login to your FedEx account, get your tracking status, find a FedEx near you, learn more about how to become a better shipper, get online print offers, or get inspiration for your small business needs. You will find here all are free download and in various formats: (PDF, DOC, PPT, ZIP, RAR). C2f2 Lewis Structure Molecular Geometry. In this ScienceStruck post, we provide you with the polarity and steps to create the Lewis dot diagram of this aromatic compound. (b) What volume of methanol, density 0. On the dorsolateral sides there is a pair of compound eyes […]. Objective: Predicting the bonding and geometric structure for simple molecules is. A sample of ethanol (C2H6O) has a mass of 0. When the AgNO 3 is added, Cl - is removed from solution. Lewis structure is nothing but the electron structure made by the dots. Lewis structures of alkanes look like this: These are also called structural formulas. 4: 9409: 79: c2h601: 1. The Lewis structure shows that the central P atom is surrounded by five bonding electron pairs. A simple procedure for writing Lewis Structures was given in a previous article entitled "Lewis Structures and the Octet Rule". Source of this material. Since these take up a lot of space, condensed structural formulas are used. Historical data and info. Like the empirical formula, the molecular formula fails to provide information about the bonding and structure of a molecule. 원자는 안정된 전자 구조를 이루기 위해 금속은 양이온(양으로 하전된 이온)을 비금속은 음이온(음으로 하전된 이온)을 형성한다. C:2x4=8 H:4x1=4. bodies that this change in population structure will bring widespread challenges at every level of human organization, starting with the structure of the family, which will be transformed as people live longer. COVID-19 is an emerging, rapidly evolving situation. Ethanol is considered a universal solvent, as its molecular structure allows for the dissolving of both polar, hydrophilic and nonpolar, hydrophobic compounds. 89E+003 (Mean VP of Antoine. C2h2o bond angles. (f) Geometry name polar polar non-polar polar polar bent trigonal planar square planar tetrahedral trigonal pyramidal (b) Lewis structure _____ 3. Chemical Bonding and Molecular Structure - Lewis Structure - 1. Functional groups: the portion of the structure that controls the reactivity of the entire molecule and much of its physical properties. the faculty of hearing). (Hint: The connection of atoms isdifferent in the two structures. 1 Difficulty Level: Easy 2. chemistry 120 lewis structures shapes key report sheet key lewis structures shapes part follow the instructions in the procedure to complete this table. All Discussions Screenshots Artwork Broadcasts Videos News Guides Reviews Forum: Start a New Discussion < > Showing 1-4 of 4 active topics 0 Apr 14, 2019 @ 3. Atoms with greater stability have less energy, so a reaction that increases the stability of the atoms will release energy in the form of heat or light. Draw the Lewis structure for ketene, C2H2O. Since the number of valence electrons is. Draw Lewis structures for NCI3 and a hypothetical NCl5, and explain why NCl5 is an unlikely. However, the Lewis structure does not necessarily provide an accurate depiction of the three-dimensional shape and bond angles in the molecule or ion. 24)- moderately polar covalent bond Hydrogen to Carbon (difference of 0. Most resonance structures and coordination compounds are also supported. The calorimeter has a mass of 2. Bond-line, Lewis and Condensed Structures with Practice Problems Bond-line Structures One of the fundamental differences of Organic Chemistry from General Chemistry is the need for having a much better visualization and understanding of the molecular structures. 6 Writing Lewis Structures Give the Lewis structure for each of the following. 2 and 3 🤓 Based on our data, we think this question is relevant for Professor Shteynbuk's class at UWM. Draw a Lewis structure for ketene, C2H2O which has a carbon-carbon double bond. The first step in drawing the Lewis dot structure for ethane ( C2H 6) is to determine how many valence electrons are available for the molecule. (1), (2), and (3) - all three structures are possi. Lewis Structure. Structure of SARS coronavirus spike receptor-binding domain complexed with receptor. Problem: Which of the following are possible Lewis structures for C2H6O?a. Specify drawing parameters in the Lewis Structure Drawing Tool. of all of the atoms in a compound, but not which. 2 Lewis Structures. Lewis structure is nothing but the electron structure made by the dots. Methoxyethane Condensed Formula. May 19, 2015 - Draw Lewis structures depicting the bonding in simple molecules of ethylene (C2H4), ethane (C2H6), propyne (H3CCCH), and diacetylene. Problem Draw orbital diagrams and Lewis structures to show how the following pairs of elements can combine. C2h2 Molecular Shape. Using the Periodic Table to Draw Lewis Dot Structures. Problem: There are 3 Lewis structures for C2H2Cl2 draw all three and indicate whether each is non-polar or polar. Drawing the Lewis Structure for HCO 2-. (refer to the second picture). That's exactly the same as the other two structures. Lewis dot structures predate the advent of modern quantum theory and quantum chemistry. Algorithms & Data Structures. That's called ethanol. Functional groups: the portion of the structure that controls the reactivity of the entire molecule and much of its physical properties. It is the outer shell or valence shell electrons which are responsible for forming bonds and it is the arrangement of these electrons which determine molecular shape. Simon le Maistre & Carina Lewis (+ Audio). Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1. Answers: 2. It has a hydrogen attached to it as well as the methyl group. Its formula can be also written as CH 3 − CH 2 − OH or C 2 H 5 OH (an ethyl group linked to a hydroxyl group), and is often abbreviated as EtOH. (b) NCI3 is a known compound, but all attempts to synthesize NCI5 have failed. C2h3br Lewis structure. In drawing Lewis structures (Section 8. 47 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1. Shop new season trends in homeware, furniture and fashion at John Lewis & Partners. (1) and (2)b. Draw the Lewis structure 2. jpg","width":720,"height":1280}}},{"title":"","image". It's best if I illustrate the idea of constitutional isomers with an example. So they're both valid Lewis structures. Moreover, by sharing a bonding pair with oxygen, each hydrogen atom now has a full valence shell of two electrons. Stability []. Me3SiCl Me3SiC2H5. By Shota Yoshioka, Sota Nimura, Masayuki Naruto, Susumu Saito. Oxygen and Sulfur have similar bonding patterns because they are both Chalcogens, having six valence electrons and being able to form two possible bonds (i. Arrange electrons until both carbons get 8 electrons. Breaking news, sport, TV, radio and a whole lot more. o Observing Dislocations o Significance of Dislocations o Schmid's Law o Influence of Crystal Structure o Plane (area) Defects, (two-dimensional) o Volume Defects (three-dimensional). Jan 11, 2015. , C makes 4 bonds and O makes 2 bonds 3. 81 (Mean or Weighted MP) VP(mm Hg,25 deg C): 4. The Lewis structure of ammonia reveals three bonding pairs and one nonbonding pair around the nitrogen atom. E`��J��ԼT\�_ X�tn�����s�WM��fs�e��1��:=]l�w�������+�(>V I�����H��V� |� �Q���MH. None of the atoms bears a formal charge, and all atoms have octets (except for hydrogen atoms, which have duets). That's called ethanol. AP® Chemistry 2013 Scoring Guidelines. 3 More Lewis Structures. In the table below, pK a1 and pK a2 for water solutions at 25°C are given together with boiling and melting point, density and molecular weight, as well as number of carbon, hydrogen and oxygen atoms in each molecule. The origin and evolution of cosmic structure - Coles P. Lewis developed a theory that focused on the significance of valence electrons (electrons in the outer shell) in chemical reactions and in bonding. ) c2h6o ===== What is the number of moles in 508 g of ethanol? C2H6O = 46. Since C has 4 valence electrons, and each H atoms contributes 1 valence electron, the total number of electrons will be. Chemistry may not be much of a race, but what if you need to draw a Lewis structure as quickly as you can? Here's a step-by step process to make it happen, along with an example showing how you would apply these steps to draw the structure of water: Write a skeletal structure showing a […]. There are two possible options. In the formation of CO 2, there are two particles; Carbon, and Oxygen. The other two carbons bond with 3. Problem Draw orbital diagrams and Lewis structures to show how the following pairs of elements can combine. How many double bonds are there in the extended octet Lewis structure where the formal charge on S = zero for the sulfite ion, SO32-?. Structures like those shown in Figure 13. In this ScienceStruck post, we provide you with the polarity and steps to create the Lewis dot diagram of this aromatic compound. Add them together. Tekla Structures 21 SR1 (64-Bit) Crack - [FirstUploads]. In nonpolar covalent bonds, the electrons ar shared unequally between two atoms. Compare Products: Select up to 4 products. ) c2h6o ===== What is the number of moles in 508 g of ethanol? C2H6O = 46. There are two possible options. Lewis dot structure of CH4O consists of the Carbon atom being bonded to three of the Hydrogen atoms, and the Oxygen atom. Atoms will react to get in the most stable state possible. Ch3oh Lewis Structure. Lewis structure of [(CH3)3O]+. On the dorsolateral sides there is a pair of compound eyes […]. The first step in drawing the Lewis dot structure for ethane ( C2H 6) is to determine how many valence electrons are available for the molecule. 67 estimate) = 0. and around the world at WSJ. C atomuna 3 H, 2. e- = A group # ⚫except helium, which has 2 val e-. 120 (C2H6O) is a common. In the box below, draw a Lewis electron-dot diagram for a molecule of phosphorus trichloride, PC13 (c) ammonia 60) 61) 62) 65) In the box provided, draw a Lewis electron-dot diagram for a molecule of chlorine, Ch. It is a 2-carbon alcohol. Simply follow the steps below: If you do not already know the name or chemical formula of the molecule you wish to generate a dot structure for, you can browse the list of molecules at molcalc. C atomunun Lewis yapısını gösterelim. 4 How to Write Lewis Structures • Step 4: Subtract the number of electrons in bonds from the total number of valence electrons. 2) it could be either ketone or aldehyde as they are functional group isomers. Lewis dot structures predate the advent of modern quantum theory and quantum chemistry. Comment on the difference. If the oxygen atom is bonded on the terminal C atoms then it is aldehyde and if it is bonded with the 2nd carbon atom then it is ketone. 2 C2H6O Soluble 78 Compounds 1 and 2 in the data table above have the same empirical formula, but they have different physical properties. im/avZJc-CH4 is methane -CuI3 is copper (III) iodide -Al2Cl3 is aluminum chloride -P2O5 is phosphorus pentoxide (or sometimes called phosphoric anhydride, if you are old like me!) -C2H6O is ethanol If you could not figure these out, perhaps chemistry is not for you!. En ella dichos enlaces y los electrones se representan con puntos o guiones largos, aunque la mayoría de las veces los puntos corresponden a los electrones no compartidos y los guiones a los enlaces covalentes. Problem: Which of the following are possible Lewis structures for C2H6O?a. Build and draw the two. Ethanol | CH3CH2OH or C2H6O | CID 702 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities. Covalent BondingDraw the Lewis structure for formaldehyde: H2CO1. CO2 Lewis structure. In the Lewis-dot structure the valance electrons are shown by 'dot'. The number of carbon atoms and the number of C-H bonds in. That's exactly the same as the other two structures. e- of A group elements are represented as dots surrounding the symbol of the element. The Lewis structures of the two compounds are: a) Match the Compound from the table with the correct Lewis structure. 4: 6128: 57: c2h6o2: 0. Play online with friends, challenge the computer, join a club, solve puzzles, analyze your games, and learn from hundreds of video lessons. Each C also contains one In diatomic carbon, each carbon atom is connected to the other with a double bond. Complete the Lewis structure by drawing atomic connectivity. Cellular Automata. (refer to the first picture) b) find the element(s) that has more dots than the rest. CPE (Certificate of Proficiency in English) Уровень Proficiency (C2). Lewis structures are meant to provide a visualization of the atomic structure and the distribution of electrons in a given chemical compound. (1), (2), and (3) - all three structures are possi. Hydrogen sulfide is a triatomic (3-atom) molecule that consists of a central sulfur atom and 2 terminal hydrogen atoms. Onun için çift olarak yazılır. C:2x4=8 H:4x1=4. B) Calculate the formal charge…. C6H6 in presence of anhydrous AlCl3. Draw a skeleton structure. Draw the lewis structure for CH3CH2OCH2CH3: i need help with lewis dot structure of zolpidem: How to draw and name cis-trans isomers: How to draw the lewis dot structure of the given compounds? 4-chloro-1-ethyl-2-methylcyclohexane? How to draw the lewis dot structures of covalent compound: Draw condensed structural formulas for ketones and. 8: 2322: 65: c2h6o molar mass: 0. There are no slots. im/avZJc-CH4 is methane -CuI3 is copper (III) iodide -Al2Cl3 is aluminum chloride -P2O5 is phosphorus pentoxide (or sometimes called phosphoric anhydride, if you are old like me!) -C2H6O is ethanol If you could not figure these out, perhaps chemistry is not for you!. What is the Lewis structure for C5H6O. 2: 2215: 38: c2h6o2 molar mass: 1. 455 (Program type: Ramp; Column cl (show more) ass: Standard non-polar; Column type: Capillary; CAS no: 64175; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Du, X. Find more Chemistry widgets in Wolfram|Alpha. C6H6 (Benzene): Lewis Dot Structure and Polarity. Add them together. im/avZJc-CH4 is methane -CuI3 is copper (III) iodide -Al2Cl3 is aluminum chloride -P2O5 is phosphorus pentoxide (or sometimes called phosphoric anhydride, if you are old like me!) -C2H6O is ethanol If you could not figure these out, perhaps chemistry is not for you!. They're all wrong) Thank You. C8h16 Isomers C8h16 Isomers. In a Lewis structure, the nucleus and the inner core electrons are represented by the. Lewis structures of acetaldehyde,ethylene oxide and vinyl alcohol. Thegeoexchange. AsF4^- Does Not Obey The Octet Dr. 1H Lewis Simgesi Değerlik Elektron Sayısı Elektron Dizilişi Elektron Nokta Yapısı. Simply follow the steps below: If you do not already know the name or chemical formula of the molecule you wish to generate a dot structure for, you can browse the list of molecules at molcalc. The number of dots equals the number of valence electrons in the atom. meritnation. Welcome to the leading CS:GO site in the world, featuring news, demos, pictures, statistics, on-site coverage and much much more!. AP® Chemistry 2013 Scoring Guidelines. Chemical Formula. CF4 O3 C2H4 C6H6 NH3 HNO3. Since these take up a lot of space, condensed structural formulas are used. An ionic bond is a. Organic molecules contain both carbon and hydrogen. Lewis Dot structure of C2H6O2. The bonding pattern should be different in each structure. If you draw a dot and cross diagram, you'll find that: 1. Watch and chat now with millions of other fans from around the world. For IEEE to continue sending you helpful information on our products and services, please consent to our updated Privacy Policy. C2H6O, also known as Ethanol, is a polar molecule. Lewis structures are meant to provide a visualization of the atomic structure and the distribution of electrons in a given chemical compound. (b) What volume of methanol, density 0. It is possible to draw Lewis structures for ionic compounds, but where it finds the most use is in molecular compounds that are comprised of non-metals so that's So, the cloud is not equal around both nuclei like it was with the H2 molecule. ho lewis structure draw dot structure ho youtube. You do this by remembering "VSEPR". COVID-19 is an emerging, rapidly evolving situation. The skeletal formula, also called line-angle formula or shorthand formula, of an organic compound is a type of molecular structural formula that serves as a shorthand representation of a molecule's bonding and some details of its molecular geometry. 08 g 508 g * (1 mol C2H6O/46. As of today we have 85,954,123 eBooks for you to download for free. ) Draw the molecule by placing atoms on the grid and connectingthem with bonds. As in Lewis structures, covalent bonds are indicated by line segments, with a doubled or tripled line segment indicating double or triple bonding, respectively. 6: 6166: 27: c2h6 moles: 0. Politics, Economics, Markets, Life & Arts, and in-depth reporting. CH3(MeO)CCH2 H. Draw Lewis structures for these two compounds. Stability []. This structure does not give the guarantee to tell the exact shape of molecules, but helps a lot to assume what it could be! It helps in the identification of the bond pairs and the lone ones. You might want to track the following attributes about each book −. Animated Algorithm and Data Structure Visualization (Resource). Arrange electrons until both carbons get 8 electrons. Explain the structure of Diborane. The Lewis structure of C2, the chemical formula for diatomic carbon, is written with two Cs connected by two straight lines. , Quantitative structure-property relationship. Open the Lewis Structure Drawing Tool, lewisdraw_authoring_2013. Cellulose (C6H10O5)n - Cellulose is the chemical name of (C6H10O5)n. Science Advances 23 Oct 2020 : eabc0274 Open Access. Advertiser Disclosure. Resonance structures differ only in the arrangement of electrons. Finding books | B-OK. , and thanks for watching. The answer to "Draw Lewis structures for(a) two compounds of formula C4H10(b) two compounds of formulaC2H6O(c) two compounds of formula C2H7N(d) three compounds of formula C2H7NO(e) three compounds of formula C3H8O2(f) three compounds of formula C2H4O" is broken down into a number of easy to follow steps, and 33 words. C6H6 in presence of anhydrous AlCl3. LESSON 6: SYLLABLE STRUCTURE. Question 2C: Online dictionary. Let's do the Lewis structure for C2H6, ethane. 47 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1. Lecture Outline Real Structure. Otherwise known as Lewis structures, dot-cross representations show the electrons in the outer shell (valence electrons) of all of the atoms involved in a molecule. Be sure to show all atoms, bonds, lone pairs, and formal charges. "You'll probly be sick as a dog tomorra, Tills. Structural Isomers – Just how many structures can you make from a simple formula? 1. When drawing the Lewis structure of HClO3, how do you know that the H atom is bonded to the O instead of to the central Cl atom? It is the Lewis structure with the lowest energy, and is thus the more stable and more favorable structure!. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1. Predicted data is generated using the US Environmental Protection Agency's EPISuite™. 2 H2(g) + 02(g) à 2 H20(g) Since you must break two moles of H-H bonds and one mole of 0=0 bonds on the left-hand side of the equation and form four moles of 0-H bonds on the right-hand side, the. 2: 2215: 38: c2h6o2 molar mass: 1. «I think it's also the changing structure of the labour market. What is the structure for c2h6o? C2H6O could be 1) Ethanol, CH3CH2OH 2. H:C:::C:H or H-C---C-H (that's intended to be a triple bond But Hydrogen always goes on the outside. Lewis structures are structural formulas for molecules and polyatomic ions that represent all valence electrons. En général les erreurs se corrigent par la prise en compte de plusieurs structures de Lewis (comme dans CO 2-), on parle de mésomérie. By Jazmin Goodwin, CNN Business. All compounds are molecules. ) c2h6o ===== What is the number of moles in 508 g of ethanol? C2H6O = 46. Compounds with the molecular formula C 2 H 6 O include:. Login to LinkedIn to keep in touch with people you know, share ideas, and build your career. 24)- moderately polar covalent bond Hydrogen to Carbon (difference of 0. NOT:2He Lewis Simgesinde elektronlar tek tek yerleştirilmez. Description of the type of. The bonding pattern should be different in each structure. místo s odkazy na články o různých chemických látkách, které by jinak měly stejný sumární vzorec nebo název. Viewing Notes: With C 2 H 6 there are only single bonds. Cinema lover exploring consciousness, the earth and martial arts. The Lewis Structure, or Lewis Dot Diagram, shows the bonding between atoms of a molecule and any electrons that may exist. How many moles of ethanol are present in the sample?. Chimie Modèle de Lewis METHODE A SUIVRE POUR CONSTRUIRE LE MODELE DE LEWIS D'UNE MOLECULE Pour construire ce modèle, nous allons apprendre à remplir un tableau. (i) Complete the Lewis electron-dot diagram of the molecule in Box X. Data Structure. All compounds are molecules. Serious Science with an Approach Built for Today's StudentsSmith'sOrganic Chemistrycontinues to breathe new life into the organic chemistry world. However, the Lewis structure does not necessarily provide an accurate depiction of the three-dimensional shape and bond angles in the molecule or ion. , C makes 4 bonds and O makes 2 bonds 3. On the unbonded sides, there are five single bonded H atoms and one single bonded O atom. Step 1: Find valence e- for all atoms. The origin and evolution of cosmic structure - Coles P. Lewis structure of C 2 H 4 O. By arrangement with the publisher (Oxford University Press), this introduction to VSEPR is a hypertext version of Chapter 4 in my book on Chemical Bonding, one of the Oxford Chemistry Primers. Carbon is the least electronegative that means it stays at the center. In the formation of CO 2, there are two particles; Carbon, and Oxygen. Drawelectron-dot structures for both. Hydrogen sulfide is a triatomic (3-atom) molecule that consists of a central sulfur atom and 2 terminal hydrogen atoms. Lewis developed a theory that focused on the significance of valence electrons (electrons in the outer shell) in chemical reactions and in bonding. Include all hydrogen atoms and nonbondingelectrons. Constitutional isomers are molecules that have the same molecular formula but they have a different connectivity of atoms in the molecules. C2h6o Lewis Structure. The shape of a molecule depends upon its electronic structure. On the right, the Oxygen atom's on the outside with the Hydrogen attached to it. Ethanol lewis structure. 08 g C2H6O) = 11. Polar compounds have a net dipole due to polar bonds that are arranged asymmetrically. Ethylene, C2H4 has the Lewis Structure: The molecular shape is predicted to be trigonal planar around each carbon atom. Geometry of the molecule is predicted with VSEPR 3. Add the valence electrons of each element to get the total needed. These different structures are called isomers. When drawing the Lewis structure of HClO3, how do you know that the H atom is bonded to the O instead of to the central Cl atom? It is the Lewis structure with the lowest energy, and is thus the more stable and more favorable structure!. The bond angles between the carbons are 60 degrees while the bond angles between the hydrogen are 115 degrees. Ethane is a saturated molecule. Dolgov Origins - The Quest for our Cosmic Roots - T Yulsman Particle Astrophysics. C2H6 + 2Na Br Fridel craft's alkylation: Alkyle group is. In the table below, pK a1 and pK a2 for water solutions at 25°C are given together with boiling and melting point, density and molecular weight, as well as number of carbon, hydrogen and oxygen atoms in each molecule. Solution for A) Write six unique and valid Lewis structures for C2H6O. Also which are the hybridizations?. Finally, if one of the two contributing structures makes a dominant (major) contribution to the. Some of their properties are given in the table below. n �zh~ �m��cݰ���]eY� SQ�����. Cоединение. C2h6o lewis structure Designing iOS apps can be difficult sometimes, but finding correct and up-to-date information about all of Apples' devices shouldn't be. Predicting Molecular Geometry • The following rules and figures will help discern electron pair arrangements. Find more Chemistry widgets in Wolfram|Alpha. Note the number of electron regions around the central atom, and of these which are bonding or lone pairs (non-bonding pairs) Step 2: Use this info to determine the 3D geometry of the molecule. Intermolecular Forces of Attraction (IMFA) Intermolecular Forces of Attraction are forces of attraction between unlike charges, partially positive and negative dipoles, that occur between two molecules. Step 1: Find valence e- for all atoms. In fact this structure is misleading because it suggests that the two oxygen atoms on the right-hand side of the diagram are joined to the nitrogen in different ways. This is Dr. How to draw Lewis Diagrams. (f) Geometry name polar polar non-polar polar polar bent trigonal planar square planar tetrahedral trigonal pyramidal (b) Lewis structure _____ 3. C:4x2=8 H=1x6=6. Animated Algorithm and Data Structure Visualization (Resource). CF 2 H 2 e. The bonding pattern should be different in each structure. In the formation of CO 2, there are two particles; Carbon, and Oxygen. The Lewis structure of H2 N−OH is given by. Lewis Dot Structure for CH3CH(OH)CH3Lewis Structures - ChemWiki Lewis structure - Wikipedia, the free encyclopedia Lewis Dot Structures Worksheet 1 of 5 - Docstoc – Documents. Internet Archive is a non-profit digital library offering free universal access to books, movies & music, as well as 477 billion archived web pages. 6), we saw two types of valence-shell electron pairs: bonding pairs, which are shared by atoms in bonds, and nonbonding pairs (or lone pairs). Moreover, by sharing a bonding pair with oxygen, each hydrogen atom now has a full valence shell of two electrons. Conjugate acids and bases. C - Structures - Arrays allow to define type of variables that can hold several data items of the same kind. C2h3br Lewis structure. drawing the Lewis dot structure for C 2 H 4 (ethene) and answer the questions below. Coronavirus counter with new cases, deaths, and number of tests per 1 Million population. ) Draw the molecule by placing atoms on the grid and connectingthem with bonds. After that, the application of VSEPR theory takes place with the Lewis structure. Bredt's Rule. Norbury Modern cosmology - S. C6H6 (Benzene): Lewis Dot Structure and Polarity. En ella dichos enlaces y los electrones se representan con puntos o guiones largos, aunque la mayoría de las veces los puntos corresponden a los electrones no compartidos y los guiones a los enlaces covalentes. From this Lewis dot structure we looked at other ways to represent the same molecule. AP® Chemistry 2013 Scoring Guidelines. Structure Search. Both use all 20 valence electrons and achieve full outer shells. Since the number of valence electrons is. atoms, as well as the location of all bonding and. Predict (a) the approximate bond. Animated Algorithm and Data Structure Visualization (Resource). The best of the BBC, with the latest news and sport headlines, weather, TV & radio highlights and much more from across the whole of BBC Online. H&M is your shopping destination for fashion, home, kids' clothes plus beauty products. If you are using mobile phone, you could also use menu drawer from browser. The Lewis symbols for the atoms are used to account for the bonding in a compound; the resulting representation is called the Lewis formula (or Lewis structure) for the compound. Since each electron pair is shared with a chlorine atom, an octahedral. : tổ hợp âm, chuổi âm. Methoxyethane Condensed Formula. This is composed of a σ framework and a π-bond. 70 More Lewis Dot Structures. Lewis Structures. in terms of electrons, why the bonding in NaCl is Ionic. Set the grading options for the problem on the lower left: Click a grading setting option to toggle whether or not it will be active. Found in car exhaust and tobacco smoke. Chimie Modèle de Lewis METHODE A SUIVRE POUR CONSTRUIRE LE MODELE DE LEWIS D'UNE MOLECULE Pour construire ce modèle, nous allons apprendre à remplir un tableau. Alternatively a dot method can be used to draw the lewis structure. 08 g C2H6O) = 11. None of the atoms bears a formal charge, and all atoms have octets (except for hydrogen atoms, which have duets). The predicted protein structures of the RBD of the spike protein were estimated based on target-template alignment using ProMod3 on SWISS-MODEL server (https Li, F. Each C also contains one In diatomic carbon, each carbon atom is connected to the other with a double bond. On the left, we have the. Developing the ability to visualize a three-dimensional structure from two-dimensional formulas requires practice, and in most cases the aid of molecular models. Frustrated Lewis pairs (253). Step 1: Find valence e- in all atoms. Ethanol, CH3CH2-O-H, and methoxymethane, CH3-O-CH3, both have the same molecular formula, C2H6O. On the dorsolateral sides there is a pair of compound eyes […]. Draw Lewis structures for these two compounds. In-depth DC, Virginia, Maryland news coverage including traffic, weather, crime, education, restaurant reviews and more. Here is the Lewis dot structure for the other isomer of C 2 H 6 O, dimethyl ether. How many double bonds are there in the extended octet Lewis structure where the formal charge on S = zero for the sulfite ion, SO32-?. Azomethane | C2H6N2 | CID 10421 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Also which are the hybridizations? What is the min # of atoms out of the plane of paper. The electrons are all negatively charged and so will repel each other. Annotated Algorithms in Python: Applications in Physics Analytic Geometry (1922) - Lewis Parker Siceloff, George Wentworth, David Eugene Smith (PDF). C atomu 4 bağ yapabildiğinden merkezde olmalıdır. How many moles of ethanol are present in the sample?. Predict (a) the approximate bond. A sample of ethanol (C2H6O) has a mass of 0. Problem Draw orbital diagrams and Lewis structures to show how the following pairs of elements can combine. Bond-line, Lewis and Condensed Structures with Practice Problems Bond-line Structures One of the fundamental differences of Organic Chemistry from General Chemistry is the need for having a much better visualization and understanding of the molecular structures. 3) : very covalent. In-depth DC, Virginia, Maryland news coverage including traffic, weather, crime, education, restaurant reviews and more. The Lewis structure of ammonia reveals three bonding pairs and one nonbonding pair around the nitrogen atom. Retail is still a big employer, E. These data elements, known as members, can have Data structures can be declared in C++ using the following syntax: struct type_name { member_type1 member_name1; member_type2 member_name2; member_type3. Search our 100 + Lewis Structures (Opens New Window) See the Big List of Lewis Structures : Frequently Tested Lewis Structures Basic CH 4, NH 3, C 2 H 4, O 2, N 2 Intermediate. https://www. In simple molecules, the atom with the most available sites for bondng is. The College Board. Low prices across earth's biggest selection of books, music, DVDs, electronics, computers, software, apparel & accessories, shoes, jewelry, tools & hardware, housewares, furniture, sporting goods, beauty & personal care, groceries & just about. Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, spirits, or simply alcohol) is an organic chemical compound. 08 g C2H6O) = 11. The result is called a Lewis structure, or dot structure. ho lewis structure draw dot structure ho youtube. The chemical structure, C 3 H 8 O exists as several isomers of propanol, as well as the isomer methoxyethane. Share photos and videos, send messages and get updates. Pure ethanol is used as solvent for esters, medicines, solvent based paints and perfumes. H and F are always terminal atoms. The result is called a Lewis structure, or dot structure. This structure does not give the guarantee to tell the exact shape of molecules, but helps a lot to assume what it could be! It helps in the identification of the bond pairs and the lone ones. com - the #1 chess community with +30 million members around the world. that gives us a total 14 valence electrons for the P2H4 Lewis structure. This VSEPR package use the Jmol molecule viewer. Since these take up a lot of space, condensed structural formulas are used. Pedro Martínez Fernández www. This set index page lists chemical structure articles associated with the same molecular formula. ››More information on molar mass and molecular weight. Solution for A) Write six unique and valid Lewis structures for C2H6O. • Emphasizes rare gas configurations, s2p6, as a stable state. Example Domain. Therefore this molecule is polar. ethane: C2H6 Once the two carbons are connected, there are only six additional bonding sites and these are filled by the six hydrogen atoms. Download books for free. Use the Fedex. In simple molecules, the atom with the most available sites for bondng is. There are two possible options. : tổ hợp âm, chuổi âm. C2H6O (Ethanol-d6) SOCl2 H3O+ (Hydronium) CHF3 (Fluoroform) HClO (HYPOCHLOROUS ACID) NI3 (Nitrogen triiodide) NaCl (sodium chloride) AsH3 (Arsine) NH2Cl OCS (Carbonyl sulfide) SiCl2F2 glucose CH3 N2O PoCl3 (PHOSPHORUS OXYCHLORIDE) MgCl2 vinegar IOF5 phosphate CHBr3 (Bromoform) ICl (IODINE MONOCHLORIDE) carbon monoxide sulfur dioxide PBr3. With a standard atomic weight of circa 1. If the theoretical yield should have been 2. You can also watch top players and compete for prizes. , умножаем C2H6. C - Structures - Arrays allow to define type of variables that can hold several data items of the same kind. This reaction is endothermic as written, so adding heat causes the equilibrium constant to shift to the right. An ionic bond is a. Hello there, I hope my answer will help you :). The Lewis dot structure for C2H6O begins with two C atoms singly bonded to each other. Search our 100 + Lewis Structures (Opens New Window) See the Big List of Lewis Structures : Frequently Tested Lewis Structures Basic CH 4, NH 3, C 2 H 4, O 2, N 2 Intermediate. For those molecules that exhibit resonance, draw all possible resonance structures. jpg","width":720,"height":1280}}},{"title":"","image". The chemical formula for ethanol is CH 3 CH 2 OH or C 2 H 5 OH (condensed structural formulas). C2H6O, also known as Ethanol, is a polar molecule. Lewis Dot Structure for CH3CH(OH)CH3Lewis Structures - ChemWiki Lewis structure - Wikipedia, the free encyclopedia Lewis Dot Structures Worksheet 1 of 5 - Docstoc – Documents. The first step in drawing the Lewis dot structure for ethane ( C2H 6) is to determine how many valence electrons are available for the molecule. Some of the worksheets for this concept are Lewis structure work, Practice problems h s so ch br hcn, Lewis structure work 1, Work 13, Lewis dot structures and molecule geometries work, Covalent bonds and lewis structures. Cellular Automata. e- of A group elements are represented as dots surrounding the symbol of the element. How many moles of ethanol are present in the sample?. The difference between polar and nonpolar bonds stems from the difference in electronegativity of the atoms involved in the bond. The picture to the right shows a Lewis structure of cyclopropane. Calculate the formal charges on the atoms in each and use the results to choose the resonance structure that is lowest in energy: Choose the number of lone pairs located on the central atom for. Lewis structure Step 3: Place lone pairs in separate locations adjacent to each outer atom, but never between atoms, until each outer atom has an octet of To draw the Lewis structure of H2O, we begin by performing the first two steps above: Step 1: Each H has 1 valence electron. The center carbon bonds with itself on each side and two hydrogens. A: Central atom of a compound having less electrons than Octet. As you look at the 2nd diagram, you see the electronegativity of it's atoms. Additional information for writing Lewis Structures Lewis Structures that Show Bonding between Nonmetals 1. When the molecular formula is written as CH 3-CH 2-OH, it is easy to see how the molecule is constructed. : cái cốt (lỏi). JSTOR is a digital library of academic journals, books, and primary sources. o Observing Dislocations o Significance of Dislocations o Schmid's Law o Influence of Crystal Structure o Plane (area) Defects, (two-dimensional) o Volume Defects (three-dimensional). Some of the worksheets for this concept are Lewis structure work, Practice problems h s so ch br hcn, Lewis structure work 1, Work 13, Lewis dot structures and molecule geometries work, Covalent bonds and lewis structures. 원자는 안정된 전자 구조를 이루기 위해 금속은 양이온(양으로 하전된 이온)을 비금속은 음이온(음으로 하전된 이온)을 형성한다. methane: CH4 C H H H H CH4 C H H condensed formula 2D formula 3D formula methane 2. General Relativity and Cosmology for Undergraduates - J. Shop new season trends in homeware, furniture and fashion at John Lewis & Partners. In fact, skeletal formulae can be. Une structure de Lewis n'est qu'une représentation simplifiée de la structure électronique. Molecular Polarity Chemical Properties Dipole Moment: 1. ↑ Bleecker A. Search results for FeCl2 4H2O at Sigma-Aldrich. jpg","width":720,"height":1280}}},{"title":"","image". Step 1: Find valence e- for all atoms. 08 g C2H6O) = 11. Since C has 4 valence electrons, and each H atoms contributes 1 valence electron, the total number of electrons will be 2*4 + 6*1 = 14 "e"^(-) This means that the Lewis dot structure for C_2H_6 must account for 14 valence electrons, either through. Once your lewis structure is complete, predict the electron domain geometry, molecular geometry, and bon. C2h2o bond angles. Lewis, 1916. Draw a Lewis structure for each of the following molecules. of all of the atoms in a compound, but not which. Based on the electron configuration shown in the Lewis structure, predict the O——-C——-O bond angle, in degrees. Welcome to The Skindex - the largest collection of community generated Minecraft skins. So they're both valid Lewis structures. Structure of the aldehyde. Comment on the difference. The iPhone 12's ceramic shield screen is tough — but you can still break it. Элементный состав C2H6. By arrangement with the publisher (Oxford University Press), this introduction to VSEPR is a hypertext version of Chapter 4 in my book on Chemical Bonding, one of the Oxford Chemistry Primers. 120 (C2H6O) is a common. - Carbon and Hydrogen (2. Chlorogenic acid (156). 08 g 508 g * (1 mol C2H6O/46. «I think it's also the changing structure of the labour market. A Lewis structure shows the connectivity between. For those molecules that exhibit resonance, draw the various possible resonance forms. This, correspondingly, makes the solution blue. On the right, the Oxygen atom's on the outside with the Hydrogen attached to it. PubChem mostly contains small molecules, but also larger molecules such as nucleotides, carbohydrates, lipids, peptides, and chemically-modified macromolecules. Daily charts. C:2x4=8 H:4x1=4. atoms are bonded to each other. C6H6 (Benzene): Lewis Dot Structure and Polarity. You do this by remembering "VSEPR". , Chahinian H. : nhịp đánh. Build and Draw ethyl alcohol and dimethyl ether both of these have the formula C2H6O. Molecular structures of PCl4F, PCl3F2, PCl2F3, and PF5 are derived from vapor‐state infrared spectra (2000–250 cm—1) and low‐temperature liquid‐state Raman displacements (Δν=50–1200 cm—1) together. Cоединение. Problem: There are 3 Lewis structures for C2H2Cl2 draw all three and indicate whether each is non-polar or polar. Thus, the difference between organic and inorganic chemistry stems from the difference between organic and inorganic compounds, which in turn, depends on the presence or absence of carbon atoms in their structure. By arrangement with the publisher (Oxford University Press), this introduction to VSEPR is a hypertext version of Chapter 4 in my book on Chemical Bonding, one of the Oxford Chemistry Primers. The Lewis structure helps us identify the type of bonding that may be present in a molecule based on the number of valence electrons available and the octet rule. A data structure is a group of data elements grouped together under one name. Hydrogen sulfide is a triatomic (3-atom) molecule that consists of a central sulfur atom and 2 terminal hydrogen atoms. Find more Chemistry widgets in Wolfram|Alpha. Add them together. A series of videos about a simple method for drawing Lewis electron dot structures. The Lewis symbols for the atoms are used to account for the bonding in a compound; the resulting representation is called the Lewis formula (or Lewis structure) for the compound. 000 kg and a specific heat of 2. Hcl Lewis Structure. The bonding pattern should be different in each structure. The College Board is a mission-driven not-for-profit organization that connects students to college success and opportunity. Structural Formula. CCl 2 F 2 d. Since each electron pair is shared with a chlorine atom, an octahedral. C atomuna 3 H, 2. Include all hydrogen atoms and nonbondingelectrons. 12 Lewis Acid-Base Chemistries: Si2H6 Si3H8 a t% 20 25 30 Si6H12 Si6:H t ration, 10 concen 15 100 200 300 400 0 X-Ray Structure of Si 6Br. Refer to models if you find them helpful. Be sure to show all atoms, bonds, lone pairs, and formal charges. In the case of 2-bromo-2,3-dimethylbutane, described above, tert-butoxide gave a 4:1 ratio of 2,3-dimethyl-1-butene to 2,3-dimethyl-2-butene ( essentially the opposite result to that obtained with hydroxide or methoxide). , Rodríguez F. Grammar, which is inseparably bound up with Lexicology, is the study of the grammatical structure of language. σ framework π-bond Overall structure Question: Identify the σ framework and the π-bonds in acetylene, C2H2, H-C≡C-H. 3 C 2 H 6 O + 2 C 2 H 4 O 2 → 2 C 2 H 5 COOC 2 H 5 + 3 H 2 O. 89E+003 (Mean VP of Antoine. Oxygen almost always has an oxidation number of -2, except in peroxides (H2O2) where it is -1 and in compounds with fluorine (OF2) where it is +2. How many sigma bonds are present in a molecule of methyl ether, C2H6O? What is resonance? Draw all resonance forms of CO3-2. Lewis structures are structural formulas for molecules and polyatomic ions that represent all valence electrons. O is in Group 16, so. The dots represent the remaining valence electrons with a total of four. It's best if I illustrate the idea of constitutional isomers with an example. The correct Lewis structure for a molecule of the compound C2H2 contains an alkyne bond. NO+ P357 p357 8-11 The Lewis structure for PCl6- (5 + 6(7) + 1 = 48 valence electrons) is shown. important in chemistry, because the properties of a molecule may be profoundly affected by these factors. Its chemical structure is illustrated in the following picture. A Lewis Dot Structure is drawn by a series of dots, lines, and atomic symbols and provides a structure for the way that the atom or molecule is arranged. There is no Schroedinger equation associated with them -- in fact placing a dot on an atom (seems to me that it) violates the concept that electrons must be indistinguishable. Tato stránka je rozcestník, tj. Download books for free. (1), (2), and (3) - all three structures are possi. After that, the application of VSEPR theory takes place with the Lewis structure. As in Lewis structures, covalent bonds are indicated by line segments, with a doubled or tripled line segment indicating double or triple bonding, respectively. Historical data and info. C6H12 Lewis Structure: How to Draw the Lewis Structure for Cyclohexane. The Lewis structure is complete when we connect the dots to show the sharing of electron pairs between different atoms. On the right, the Oxygen atom's on the outside with the Hydrogen attached to it. For those molecules that exhibit resonance, draw the various possible resonance forms. Hint: look at the questions before watching the video. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1. 💀 MORTAL KOMBAT 🐉 Wu Assassins @Netflix ⚔ Into The Badlands @amc_tv 👽 Deadpool 2 www. In simple molecules, the atom with the most available sites for bondng is. By Shota Yoshioka, Sota Nimura, Masayuki Naruto, Susumu Saito. ADVERTISEMENTS: The following points highlight the three regions present in the structure of honey bee. Watch and chat now with millions of other fans from around the world. The ethylene-receptor family from Arabidopsis: structure and function. Developing the ability to visualize a three-dimensional structure from two-dimensional formulas requires practice, and in most cases the aid of molecular models. A step-by-step explanation of how to draw the C2H6O Lewis Dot Structure. C:4x2=8 H=1x6=6. This is Dr. Search results for FeCl2 4H2O at Sigma-Aldrich. H and F are always terminal atoms. This is called dimethyl ether. Marrow said: "Chawming climate out heah in the tropics, old chap. Functional groups: the portion of the structure that controls the reactivity of the entire molecule and much of its physical properties. Play chess on Chess. That's called ethanol. The skeletal formula, also called line-angle formula or shorthand formula, of an organic compound is a type of molecular structural formula that serves as a shorthand representation of a molecule's bonding and some details of its molecular geometry. With two bonding pairs and two lone pairs, the oxygen atom has now completed its octet. The production of ethanoll from starch or sugar-based feedstocks is among man's earliest ventures into value-added processing. Breaking news and analysis on politics, business, world national news, entertainment more. La estructura de Lewis es toda aquella representación de los enlaces covalentes dentro de una molécula o un ion. im/avZJc-CH4 is methane -CuI3 is copper (III) iodide -Al2Cl3 is aluminum chloride -P2O5 is phosphorus pentoxide (or sometimes called phosphoric anhydride, if you are old like me!) -C2H6O is ethanol If you could not figure these out, perhaps chemistry is not for you!.


31 km north of Kuusamo, Vuosseli (Eastern Ruka) 4.0 km, lake Vuosselinjärvi 50 m, pier (in shared use) and own rowing boat. Log cottage, built in 2000 (renovated 2018), bedrooms 1-2 (downstairs): 2 beds, loft: 2 beds, combined kitchen/living room, electric sauna. Log cottage area in Koukkuniementie -road, east side of Ruka. Nearest ski lift RukaExpress, nearest restaurants RoySki Pub, Ski Bistro. Internet connection (4 G). Open fire place/lean-to on the lakeshore (in shared use). Bed linen and end cleaning are included in the price. Pets allowed at extra price 100e. 2 fatbikes.
Oulanka National Park / Pieni Karhunkierros trail 30 km. Reservations start at 16.00 and end at 12.00 (also in weekend bookings).


Stison was founded to provide "best in breed", affordable, browser-based solutions for the book publishing sector. The key aim of the company is to provide enterprise level software solutions to publishers of all sizes, effectively bringing solutions previously only available to larger organisations to all publishers! Since inception, Stison has focussed on providing intuitive and easy to use software. The aim is to enable publishers to implement a working system as quickly as possible.
We are a growing company with a single aim...to give small and medium sized book publishers the chance to run their systems with the same efficiency previously only available to the much larger companies.
Stison employs personnel from across the media and publishing world to provide the necessary skills and expertise. Stison continues to develop its software solutions, basing development on a combination of continuous review with feedback derived directly from the industry.
We were formed from the combination of two existing companies, one specialising in design and the other a leader in IT solutions.
Our system is quickly becoming a standard within the industry, and through continual feedback we are creating a highly bespoke solution that understands the needs of the book publisher.
If you would like more information or would like to talk to someone please fill in the form below or call on UK/EUR +44 207 183 1476 or US/CA +1 647 557 8371.


text:
Home > News and events > Announcements > Thanks a million for legacy donation
Posted on 13th January 2020 in Announcements, Fundraising, Grimsby Hospital
A huge donation of more than £1million has helped transform heart services at Grimsby hospital
Members of the Trust board, representatives from the Health Tree Foundation and staff members from the Trust outside the C1 Glover corridor.
The official charity for the Northern Lincolnshire and Goole NHS Foundation Trust, The Health Tree Foundation (HTF), received a donation of £1.2 million left in the will of a local man in 2018.
The £1million left to the charity by Mr Basil Glover, of Humberston, has allowed for a brand new cardiac unit to be opened at Diana, Princess of Wales Hospital.
The renovation of two wards has been described as 'cardiology without walls' meaning all patients who require cardiology treatment can be treated in one place, regardless of their condition.
Formerly known as C1 Kendall and the Coronary Care Unit (CCU), the wards have been transformed and now form the integrated cardiology unit.
As a tribute to Mr Glover, who passed away in November 2016 at 97-years-old, and his late wife Margaret, the new unit has been renamed as C1 Glover.
Previously, patients who required cardiology care were transported between wards as and when treatment was required. This could be any time of the day or night. On the new unit, patients now experience less moving between wards. Treatment is administered quicker meaning patients stay in hospital for a shorter period of time.
Michelle Hailey, matron in medicine, said: "This amazing donation has allowed us to create a state-of-the-art integrated unit where we aim to treat all cardiology patients within one area."
Charity manager Clare Woodard said: "Mr and Mrs Glover should be remembered always for their extraordinary kindness and generosity to our hospital. This just shows what a gift in a will can achieve for our patients in this community."
Anyone wishing to leave a gift in their will can contact the Health Tree Foundation on 03033 304514. Gifts in wills can be left to any department at the hospital – very often people have a connection with a certain area. Gifts can be a fixed amount or a percentage of what you own.
If you are a journalist and require further information contact the communications and marketing team on 03033 302528 or via nlg-tr.comms@nhs.net
Goole Hospital
Grimsby Hospital
Improving Together
Scunthorpe Hospital
Service developments

redpajama_set_name: RedPajamaCommonCrawl


Blowout Sale! Up to 55% off on Uniforms, Work & Safety at Clothing Nine Store. Top brands include Opromo, JSM Auto, Eolgo, Uniform Accessories Unlimited Inc, HMC, TheSupplyRoom, Military Uniform Supply, CUSTOM, adidas, Carhartt, Cherokee, & Skechers. Hurry! Limited time offers. Offers valid only while supplies last.


text:
Admirers Have Little to Admire on Debut
In: _CD Reviews 2013, Album Reviews
Admirers – Involuntary Memory
Ardent Music
-out now
Electro-pop Memphisians Admirers debut their dreamy near-dozen. Now, you know we love ourselves some SVIIB and dance music, but dance music that doesn't make you… well… dance? That we cannot tolerate. And yet Involuntary Memory is chock-a-block with tepid tempos, deflated beats, and just general averageness. These songs here all seem to borrow the same two-and-four beat, never changing, as reliable as the trains – moreso, jab at the MBTA. Which makes for exciting dancing, of course.
The tragedy of it all is that "Return," the opener-slash-single off the album, is really a great four-star bright pop with a super-emotive chorus. We admit, it's what drew us in initially. The next best track on here is "Rhythm Mirages," which is a whole step down: fairly satisfying, and at least it proudly declares us to "dance to the music." And after that, the rest of these tracks fall off the cliff as far as writing goes: they all blend into each other, lose their individuality, and end up as one gray mass of overcooked pasta. It's not as if they stopped trying, but Admirers stopped working hard. It takes a serious amount of effort to come off effortless; a great deal of thought to be spontaneous, and this dance album lacks both. It's a shame to get sucked in by one good song, but it's part of the music business, unfortunately.
Our excitement lasted the 4:42 of the first song and no further. This album is yet another drop in the ocean of mediocrity out there. Take a pass.
Check Admirers out on bandcamp.
Previous Post: Sallie Does New England
Next Post: Self-Release Medwed Is Own Man on Free Man


PREMIER NEW AND USED MERCEDES-BENZ DEALERSHIP. MERCEDES-BENZ OF ELMBROOK PROUDLY SERVES MILWAUKEE, WAUKESHA, GREENFIELD, WAUWATOSA, BROOKFIELD.
When you come to Mercedes-Benz of Elmbrook in Waukesha, WI you can expect to find an ever-changing selection of Mercedes-Benz models. Drivers can also look for superior and knowledgeable customer service. In addition to a wide selection of top-of-the-line luxury models, the location boasts beautiful customer lounges with flat screen televisions, Wi-Fi and complimentary snacks and beverages.


Back on the path again after the Nuro-Virus, finally was able to have lunch.
During the break, we sat down with and heard from Matt Laforis who lost his stomach to an illness, and through misfortune ended up on the east coast, so he made the decision to live out a dream and hike the AT.
Hip is better but gonna take short distances for a few days. Smokies can be intense though with 6.7k and snow. Bears baby!
account to leave a message in Ernie's guestbook.


text:
It's your money: Tell 'em how to spend…
OpinionEditorials
It's your money: Tell 'em how to spend millions
By The Times-Standard |
PUBLISHED: March 9, 2019 at 10:50 pm | UPDATED: March 10, 2019 at 11:22 am
There's roughly $3.5 million in Measure Z tax revenue for Humboldt County to hand out for the coming fiscal year, and dozens of outstretched hands requesting over $14 million. There will be winners and losers.
(You can find all of them below; we've summarized each of the requests.)
While the Citizens' Advisory Committee on Measure Z Expenditures is reviewing these requests, it can only make suggestions. Ultimately, it'll be up to the Humboldt County Board of Supervisors to dole out the revenue from the county's half-percent general sales tax. What approach might the supervisors take? We've concocted a few scenarios:
The least they could do
Supervisors could acknowledge that all the revenue ever collected by Humboldt County rests on a foundation of genocide and plunder, and prioritize funding requests from local tribal entities. If the supervisors acted accordingly, they'd still have over $2.6 million in revenue to spare.
All roads lead to safety
Measure Z was sold to voters as a public safety tax. One of three proposals submitted by the Humboldt County Department of Public Works asks for $3 million for road repair. This is a drop in the bucket compared to the tens of millions needed to fix the county's crumbling roads. And that's not counting recent storms, which, as we reported Saturday, inflicted additional damages to county roads estimated at $18 million and rising. We can't have any semblance of public safety — or civilization — without roads.
Fund the police
Granting all the requests filed by various police agencies would leave the supervisors about $900,000 to play with.
Fire, fire, fire
Firefighting and fire prevention related requests this cycle top $4 million, so some firefighters are going to stay thirsty for funds.
Preparedness is all
Assorted requests for generic, nonfire disaster prevention only total around $270,000, by our estimates.
Many's the finger that pointed at Humboldt County's substance abuse problem as the cause of our public safety woes. Proposals that would either give people something else to do or treat them after they've picked up a habit total $953,546.
Roofs, beds and walls
Various proposals to help the homeless — and to keep them away from the library grounds at night — total just short of $650,000.
We're just spitballing here, of course; it's all up to the supervisors. Feel free to take a look at the list below, pick your favorite proposals, and let us know how you think they should spend $3.5 million.
After all, it's your money.
Measure Z funding requests for fiscal year 2019-2020
Editor's note: Humboldt County has received proposals totaling over $14 million competing for over $3.5 million in projected revenue collected by Measure Z, the county's half-percent general sales tax. Below are Times-Standard summaries of the dozens of funding requests competing for the Board of Supervisors' ultimate approval; a list of the complete requests can be found online here. Or you can click on any of the links below to read them one by one.
2-1-1 Humboldt Information and Resource Center (nonprofit; Eureka)
$55,000: Funding to replace a second call care specialist, bilingual, to assist with 15,000 to 17,000 calls yearly; and to cover associated costs.
AJ's Transitional Living (nonprofit; McKinleyville)
$113,296: Funding to continue the position of house manager ($35,536) and other essential operating costs ($77,760 for rent, utilities, phones, transportation, etc.) of a clean and sober housing program.
Blue Lake Rancheria Volunteer Fire Department
$62,484: Funding for personal protection equipment for firefighters ($43,284), for which the tribe will provide the other required $10,821; and funding for a concrete and black top fire training tower pad ($19,200), for which the tribe will provide the other required $4,500.
Boys & Girls Club of the Redwoods (nonprofit; Eureka)
$100,000: Funding for personnel ($73,470), operating expenses ($19,183), and indirect costs ($7,347).
Bridgeville Community Center (nonprofit; Bridgeville)
$25,000: Funding for four secured 5,000 gallon water tanks reserved for wildfire protection.
City of Arcata
$30,000: Funding for a backup generator for the D Street Neighborhood Center, one of the city's designated emergency disaster shelters.
$98,000: Funding for road grinding equipment to perform road repairs.
$32,000: Funding for five sets (10 individual) radar feedback signs.
$60,000: Funding for a backup generator for the Arcata Community Center, one of the city's designated emergency disaster shelters.
$353,367.25: Funding for the wages and benefits for one school resource officer ($132,180.93) and two juvenile diversion counselors ($110,593.16 each).
City of Blue Lake
$17,540: Funding for design and development of a Hatchery Road/Mad River Access Masterplan to combat transient issues and other illegal activities in the area
$75,317: Funding for half-time sheriff's deputy.
City of Eureka
$82,000: Funding for two part-time community service Crime Prevention Through Environmental Design event team members ($32,000) and the one-time purchase of a maintenance van ($50,000).
City of Eureka Community Services Department
$92,500: Funding for one-time project to address inappropriate behavior in Clara May Berry park, next to the Humboldt County Library, by removing unwanted equipment and installing gated fencing, to be opened daily by city staff and locked nightly by library staff.
City of Eureka Police Department
$415,000: Funding for salary and benefits of a police officer ($110,000); salary and benefits of waterfront parks ranger ($110,000); salary and benefits of half-time police officer ($55,000); temporary part-time salary of a Homeless Services Programs supervisor ($40,000); temporary part-time salary of a homeless outreach worker ($20,000); part-time salary of a homeless liaison ($10,000); funds for detox, emergency shelter, housing and transportation ($50,000); miscellaneous equipment needs ($10,000); out-of-county Police and Uplift staff training ($5,000 for travel, fuel, lodging and meals).
City of Eureka Police Department/Humboldt Bay Fire
$1.01 million: Funding for a complete radio upgrade for a failing radio communication system (six dispatch consoles and all related equipment, $170,000; microwave system replacement at each of seven current radio sites, $840,000).
City of Eureka Public Works
$750,500: Funding for the resurfacing of Fairway Drive.
City of Eureka Public Works/Humboldt County Public Works
$350,000: Funding for a one-time capital expenditure (resurfacing and construction of ADA improvements along Harrison Avenue between Erie and Munson streets).
City of Ferndale Police Department
$82,958: Funding for one-time replacement of the department's Record Management Systems.
City of Fortuna Police Department
$34,794: Funding for a 2019 Ford F-150 pickup truck to be used by the city's Problem Oriented Police officer in his duties to easily reach areas on the river bar and other areas not easily accessible by traditional patrol units.
$186,577: Funding for a full-time school resource officer salary ($72,156), overtime ($15,000), benefits ($76,921), occupancy and overhead costs ($12,500), mandated POST (Peace Officer Standards and Training) training ($2,500), general office supplies ($5,000), and travel costs related to training ($2,500).
$181,577: Funding for Drug Task Force agent ($72,156), overtime ($15,000), benefits ($76,921), occupancy and overhead costs ($12,500), mandated POST (Peace Officer Standards and Training) training ($2,500), travel costs related to training ($2,500).
City of Rio Dell Police Department
$33,488: Funding for a part-time police records technician.
Eel River Clean-up Project (nonprofit; Garberville)
$3,000: Funding to make up for shortfall in funding due to changing economy.
Garberville Sanitary District
$200,000: Funding for one-time replacement of 10 failed water hydrants.
Hoopa Fire Department and Office of Emergency Services, Hoopa Valley Tribe
$196,027.23: Funding for 10 handheld radios for personnel and five mobile radios for vehicles ($40,546.25), 10 gear packs of personal protection equipment ($3,535.75), 10 hard hats ($589.50), a 1-ton flatbed truck ($66,735), a 12-inch woodchipper ($63,333.73), and a masticator head ($21,287) for a Track Skid Steer unit to help with Wildland Urban Interface projects.
Hoopa Valley Tribal Police Department
$253,152.61: Funding for two full-time sworn Hoopa Resource Police Officer positions ($50,000 salary for each, with benefits of $25,589.04 and $22,942.20, respectively); basic issue firearm ($994.34) and basic issue uniform, including body armor ($3,142.87); and two patrol vehicles (new 2019 Ford F-150 crew cab XLT Sport 4WD) equipped with radio, lights, sirens, etc., for those officers ($100,484.15).
Humboldt CERT (Community Emergency Response Teams) Coalition (volunteer organization; Cutten)
$29,320.34: Funding for 60 Family Radio Service radios ($4,557); 7 2,000-3,500-watt Honda generators ($11,392.50); 8 5-gallon fuel cans ($329.84); 7 EZ-Up canopies ($2,498.76); 14 sets of color-coded triage tarps, 4 per set ($1,279.44); 30 triage marking tape sets ($382.42); 14 backboards ($2,536.73); 14 backboard strapping sets ($904.50); 36 4-in-1 utility tools for gas/water shutoff ($535.52); 8 heavy duty 4 packs of 82-quart storage tubs ($1,670.90); 16 pry bars ($429.66); 54 traffic cones ($924.38); 12 folded wagon carts ($1,041.60); 35 20-pack boxes of N95 masks ($388.99); 14 cases of 50 Mylar blankets ($448.11).
Humboldt County Department of Aviation
$81,725: Funding for the design of a new airfield electrical and lighting system at ACV Airport.
Humboldt County Department of Health and Human Services
$257,500: Funding for Mobile Intervention Services Team expansion: housing support ($250,000) including short term housing, immediate temporary housing, transitional housing for participants in aftercare and recovery, rental assistance for permanent housing including security deposits and application fees, and other similar costs that assist participants in achieving housing stability; project administration (accounting and reporting) 3 percent, $7,500.
$4,300: Funding for Foster Care clothing allowances.
Humboldt County District Attorney
$400,742: Funding for two full-time administrative analysts (each with a salary of $58,344 and $29,704 in benefits), one full-time legal secretary (with a salary of $40,144 and $23,478 in benefits), and one full-time deputy district attorney (with a salary of $112,694 and $48,330 in benefits).
Humboldt County District Attorney/Adult Protective Services
$38,308.50: Funding to continue the positions of: one full-time APS program coordinator (with a salary of $59,234.05 and $45,254.60 in benefits), responsible for collaborative program development, community and tribal engagement, best practice research and facilitation and organization of Multidisciplinary Teams with the Elder and Vulnerable Adult Services Team; one half-time district attorney investigator (with a salary of $43,474.21 and $25,395.90 in benefits) and one quarter-time deputy district attorney (with a salary of $19,771.83 and $8,759.48 in benefits), both to be assigned to elder and vulnerable adult abuse. Additional funds are requested for the continued funding of Structured Decision Making annual maintenance cost and fees ($25,788.50); a laptop computer and 12-month data plan for the APS program coordinator ($1,320); and funds for four staff and team partners to attend yearly professional development trainings in Sacramento ($11,200).
Humboldt County Fire Chiefs Association
$2,366,794: Funding for county planning contractual services ($91,000); county dispatch fees ($87,620); out of jurisdiction response, 299 corridor/Maple Creek ($252,855); 25 fire shelters for wildland personal protection equipment ($9,700); handheld and mobile radios ($575,619); 45 sets of personal protective equipment, structural ($107,500); 61 sets of personal protective equipment, wildland ($59,500); fire hose replacements, ($67,035); 97 Self-Contained Breathing Apparatus packs ($435,365); SCBA replacement bottles ($111,000); training facility upgrade, Eureka ($250,000); fixed training facility, Fortuna ($319,600).
Humboldt County Library
$66,358: Funding to maintain one security guard and add another (salary of $33,179 each).
Humboldt County Public Defender
$793,639: Funding for two additional full-time attorneys ($724,137), operational costs (insurance, $9,071; telephones, $1,500; utilities, $1,500), supplies and consumables (office supplies, $5,000; professional and special services, $1,000; staff development and training, $12,000; state bar dues, $850; books and periodicals, $2,000; office equipment, $12,000), out of county travel ($1,000), overhead costs (IT, ADA, communications, central service, $18,956), Sustain (Court) software licenses ($4,625).
Humboldt County Department of Public Works
$871,300: Funding to establish and expand the Public Works Road & Equipment Maintenance Division's ("County Roads") heavy brush/fuel break program through: one-time purchase of two equipment trailers ($84,000) to haul two brush cutters ($330,000); one porta-potty ($10,000); one brush chipper ($40,000); toilet paper, sanitizer and cleaning fees for the porta-potty ($2,000); motor pool usage of four vehicles ($27,800); equipment usage ($18,580); contracting Cal Fire inmate crews at $200 per day ($75,000); personal protective equipment, radios, small tools ($20,000); tracking costs, paying invoices, reporting ($35,000); ongoing funding for four new road maintenance workers ($57,000 salary and benefits each).
$50,000: Funding for illegal dump cleanup (garbage bin rental and disposal fees for illegally dumped garbage, cleanup encampments).
$3 million: Funding for one-time maintenance and capital improvement projects: personnel costs of "extra help RMW I" ($100,000); "maintenance north" ($1.45 million); "maintenance south" ($1.45 million).
Humboldt County Department of Public Works/Resort Improvement District No. 1
$181,500: Funding for roadway clearing on up to 16.5 miles of strategic (evacuation routes and potential fire breaks) roads within Shelter Cove subdivision.
K'ima:w Medical Center/Hoopa Valley Tribe
$370,011: Funding to maintain an ambulance base in Willow Creek.
KMUD/Redwood Community Radio, Inc. (nonprofit; Redway)
$44,344.17: Funding for an Emergency Broadcast upgrade ($15,300 personnel costs; $7,500 operating costs; propane for generators, $300; transportation costs to transmitter sites, $500; two generators, studio to transmitter link equipment, solar power system and a portable satellite phone, $36,544.17).
Mercy's Haven, Inc. (nonprofit; Blue Lake)
Funding for "faith-based next step (bridge) program, whose primary goal is the reunification of mothers with their children", namely, "needed paid staff including a case manager and two house managers."
McKinleyville Land Trust (nonprofit; McKinleyville)
$5,000: Funding for a community-based walkability and bikeability safety assessment to support Humboldt County's McKinleyville Town Center planning.
Miranda Community Services District
$72,000: Funding for one-time purchase of eight fire hydrants with associated valves and piping ($40,000); labor ($32,000).
North Coast Substance Abuse Council, Inc. (nonprofit; Eureka)
$77,500: Funding for 1,250 treatment bed-nights at a rate of $62 per bed-night; services provided to participants include 90 days of food, shelter, case management, group therapy, individualized counseling, drug testing and transportation.
Orleans Community Services District
$200,000: Funding toward a new fire station.
Palo Verde Volunteer Fire Department
$50,000: Funding toward the one-time estimated $60,000 purchase of a newer quick attack truck.
Redway Community Services District
$110,423.20: Funding to replace 40 obsolete fire hydrants ($67,419.20 in parts, $9,400 for labor equipment, $27,200 in labor, $1,404 for 52 newspaper ads and $5,000 for two signs along Redway Drive).
Redwoods Rural Health Center, Inc. (nonprofit; Redway)
$24,000: Funding to provide outpatient drug treatment counseling services for more than 50 patients at the RRHC.
Resort Improvement District No. 1
$51,761: Funding for three additional emergency sirens for the district's Shelter Cove community tsunami and emergency (wildfire) siren system.
Southern Humboldt Amateur Radio Club (SHARC)
$5,160.33: Funding for the upgrading of a Grasshopper (standalone) solar-powered repeater west of Weott, enabling coverage of the Humboldt County coast.
Southern Trinity Area Rescue (nonprofit; Mad River)
$82,528: Funding for two Emergency Medical Technicians at $31,200 salary and $6,864 benefits each, with projected Cost of Living Adjustments and overtime for both at $6,400.
Waterfront Recovery Services (Alcohol Drug Care Services, Inc.) (nonprofit; Eureka)
$638,750: Funding for a year of Medically Managed Detoxification services (five patients per day in five beds set aside) and Residential Treatment services (seven patients per day in seven beds set aside) for those who are suffering from substance use disorder and homelessness in Humboldt County.
The Times-Standard


text:
Choosing Xbox Games
Looking For Website
Can Somebody Write My Paper For Me Online? Sure, We Can!
Xbox games are very popular among game enthusiasts and you can locate them in many types of makes. Whether you intend to play a zombie game or a race https://virtualdatanow.com/how-to-become-a-cyber-security-engineer game, Xbox has it all. A lot of popular online games are Homeowner Evil 2 and Forza Horizon 4. If you like to play first-person shooters, also you can check out Food and The Prolonged Dark. Also you can choose to play games developed by businesses such as Assassin's Creed: Odyssey or A lot more Strange.
Xbox games can be purchased by a range of retailers and out of online retailers. Target has an amazing range of Video games. You can buy races games, action-adventure games, and more. You can also find a few classic titles like Satanás II, Círculo, and Círculo. If you want that can be played the latest video games, you can also obtain Xbox An individual games.
The Xbox was released in 2001 and was the 1st game gaming console created by Microsoft. It was primarily called DirectX-box and used DirectX online video application to create the games. It suffered from a number of delays and changes in pricing, but was finally a popular gaming console. Despite the relatively new status, the Xbox 360 system is still a superb investment and offers a great game playing experience.
The Xbox 360 and Xbox A single consoles all have a remodeled controller. The new controllers are bigger than the previous types and have extra ports that allow players with disabilities to connect to the system. The controllers also work along with the Kinect technology.
Best Sites To get Asian Dating
Protected Software Review
Top ten Free Management Software
Do you think that CBD pills are a good way to consume CBD?
There is no one definitive answer to this question. Some people believe that cbd tablets are a good way to consume CBD because they are easy to take and you know exactly how much CBD you are getting in each dose.
Have you ever tried CBD gummies?
Yep! I'm a big fan. I love that they're a great way to take cbd gummy and that they taste delicious. Plus, the gummies make it really easy to adjust your dosage.
How long has Tennessee had a medical marijuana program?
Tennessee has had a medical marijuana program ( https://wayofleaf.com/mmj-cards/state/medical-marijuana-card-in-tennessee ) for a little over two years now. In order to qualify for the program, patients must suffer from one of the following conditions: cancer, HIV/AIDS, Alzheimer's disease, muscular dystrophy, and post-traumatic stress disorder (PTSD).
© 2021 ServFusion . All Rights Reserved.


BAR HARBOR — The new building at the corner of Eden Street and Prospect Avenue looks like a large carriage house, but it houses a state-of-the-art electrical substation set to go live around the end of the year, officials said.
"Everything connecting immediately around the substation is underground," Steve Sloan of power company Emera Maine said, so no large power lines surround the facility.
A portion of Prospect Avenue has been closed during the construction for safety and should re-open around the first of the year, he said.
They then de-energized the facility to complete the commissioning work that is expected to take a few more weeks.
That will immediately improve reliability of the system here, he said, because the new substation is a stronger system than the separate padmount transformers connected to those circuits now.
The padmounts and the downtown substation on Edgewood Street will be phased out gradually. The total transition to a new system won't be complete until a new, second transmission line running along Route 3 is installed and connected to the new substation, and after transfer of the downtown circuits is completed.
The timeline for that work, Sloan said, depends on coordination with the Maine Department of Transportation's upcoming Route 3 rebuild project.
Emera purchased the property and began work last fall. The site was chosen and plans for the facility discussed with a citizens' advisory group for more than a year, following long debate about appropriate locations and community impact of the facility. The company plans to add landscaping to the site in the spring.
A 2015 citizens' petition amended the town's land use ordinance (LUO) to disallow "public utility installation" and "public utility facility" uses in certain residential districts in the town, including the one where the new substation is located, but Emera received its building permits for the project before the change took effect.


Before beginning something new, there is often doubt (can I really do this? Little old me?!), coupled with fear (I'm gonna end up hurt/homeless/a fool/dead), to contend with. Explorer and adventurer Ed Stafford was assailed by all of these emotions before embarking on his epic walk along the entire length of the Amazon river, from the source in Camana, Peru on the Pacific coast, to Maruda Beach in Brazil on the Atlantic coast. A journey which nobody was ever known to have accomplished before, he estimated it would take him one year to do – it took him two-and-a-half years. He was told by all that it was madness to attempt, and that he'd die trying. His family said they believed in him, but to quote his tongue-in-cheek words 'that didn't help cos they didn't have a f***ing clue!' All the experts told him it was suicide or impossible. But he began anyway. He followed his dreams. He chose to live life, rather than wonder 'what if'?
If you're choosing to do something hard, it might and probably will all feel like too much. You've taken on too big of a thing, you can't do this, not now at least. It's too soon. I'll wait. I'll do it after x, y or z, we tell ourselves. Well, it's not too soon. Now really is the time.
I'm a huge fan of the London Marathon. Despite applying through the ballots, I've never been lucky enough to get in and so have not run it yet. But I love to watch it on the TV, and remember as a kid, watching all of those people running, and feeling a huge bubble of emotion at what they were doing, without really understanding why. The music that the BBC use each year for the coverage sends a shiver up my spine and mists my eyes every time I hear it. There have been some incredible performances over the years, but for the purpose of this post, I wanted to mention a great story from the 2006 wheelchair marathon. David Weir is one of the most successful athletes Great Britain has ever had, winning a total of 6 Gold medals at the Paralympic Games and 6 London Marathons. And it is his second London victory I want to draw your attention to, as he nearly didn't start, nearly didn't begin. He won the race with a (then) new course record of 1:29:48, despite the wet conditions, and being ill on the build up both to, and during the race. He was interviewed at the finish and I was staggered when I heard him say "I wasn't even going to take part this morning. I've been suffering from a cold and it was 50/50 whether I would turn up or not." He had a cold and still won, and in the fastest time ever! I remember thinking at the time 'how would he be feeling now if he'd not raced? Wondering if he should have had a go? Should have gone to that start line anyway to see what he could do?' The same thought must surely have crossed his mind.
I thought about this a lot over the years, this fine line between starting and not starting, the tricks the brain plays on us to console us that it's ok to not try today, there will always be tomorrow. Well that might not be the case. Better to live today to the max, before tomorrow. When tomorrow comes it will be today, and we can live it to the max then, in its own turn. So it was that I found myself in a similar situation to David Weir, on the build up to the South Downs Way 100 2016, my second hundred miler. I'd been struggling with the same groin injury that had nearly scuppered my race the year before. It had gone away in the autumn of 2015, but flared up again the following Spring, and my training had suffered greatly as a result. I didn't dare run long on the injury for fear of making it really bad, so would split my long training runs up, covering perhaps 20-24 miles over two shorter runs, one at the start and one at the end of the day. As race day came closer, I really didn't think I'd be able to get round. I considered deferring my entry to the following year, but David Weir's story came back to me, and I thought about how I would feel on the morning of the race, as a spectator rather than a competitor. I decided to give it a go. I decided to begin.
Better to live today to the max, before tomorrow. When tomorrow comes it will be today, and we can live it to the max then, in its own turn.
It's better by far to begin and fail than to die without even trying. Whatever that thing is that you have always wanted to start – go, and start it. Today. Not a tomorrow that will never come. If you've started something and are doubting yourself, take a step back – the hardest step is often beginning the thing in the first place, so enjoy the journey you've set yourself upon, soak all of the feelings up, for they will provide moods of future joys. When you succeed, your life will forever by the richer for it. But only if you begin… There really is a boldness and a magic in it.


Run with style in the Karrimor X 2 in 1 Shorts. Designed with an elasticated waistband, the short-length shorts are a 2 in 1 design, with a tight, compression short and loose fitting overlays, designed with a dolphin hem. The shorts are crafted with DRX Technology, to make a breathable, ventilated design.


text:
2016 Civic Learning Award Winners Announced
SACRAMENTO—Chief Justice Tani G. Cantil-Sakauye and Superintendent of Public Instruction Tom Torlakson today announced nine winners of the Civic Learning Award for 2015–2016.
Council Facilitates Juvenile System Reforms
SAN FRANCISCO—At its public meeting on April 15, the Judicial Council changed court rules and forms to implement reforms targeting those coming to family and juvenile courts. One action dealt with the implementation of a new law that changes the...
Judicial Council Meeting Information
Chief Justice and Appellate Court Leaders Visit Award-Winning Schools
Chief Justice Tani G. Cantil-Sakauye and Court of Appeal presiding justices visited nine elementary, middle, and high schools this spring to present...
State Approves More Civic Learning
After more than a dozen years of striving for a more robust civics curriculum in California's public schools, advocates for civic learning are about to get their wish.
Power of Democracy Steering Committee
CA History Social Science Framework
CA English Language Arts Framework
Creating Access: The Judicial Council's 2016 Annual Review
In 2016, the Judicial Council continued focusing on efforts to better stabilize branch funding, improve branch governance, and to address concerns about fairness raised by the public, our sister branches of government, and stakeholders throughout the state.
2017 Civic Learning Award Winners
More than 50 California public elementary, middle, and high schools are being recognized with this year's Civic Learning Awards.
News Release - March 15, 2017
Court of Appeal Holds Education Program for High School Students
The Court of Appeal, Second Appellate District, Division Three, will host its "Appellate Court Experience" (ACE) educational outreach program.
Court of Appeal, Second Appellate District
Second Appellate District
Court of Appeal, Fourth Appellate District, Division Two, Conducts Innovative Program and Oral Arguments at Coachella Valley High School
RIVERSIDE—Presiding Justice Manuel A. Ramirez has announced that the Court of Appeal will conduct an innovative court-community program called "Outreach Plus" at Coachella Valley High School.
Court of Appeal, Fourth Appellate District
Date Sort descending
(-) News 41


text:
City Fines Couple for Hosting Bible Studies Without a Permit
Officials say the meetings violate residential use policies.
Morgan Feddes| September 23, 2011 04:23 PM
The city of San Juan Capistrano, California, has fined a family for holding regular Bible studies in their home.
Chuck and Stephanie Fromm, who have been hosting Bible studies and other gatherings in their home since 1994, were cited for violating a municipal code which requires a conditional use permit (CUP) for religious, fraternal, or nonprofit organizations that meet in residential areas. The Fromms were fined twice for a total of $300. When they appealed to the city, they were informed that the violations would be upheld and that any future meetings without a CUP would face a fine of $500 each.
The code in question prohibits such groups of three or more people meeting without a CUP, said Chuck Fromm, who is the former president of Maranatha! Music and co-founder and editor of Worship Leader magazine.
"The law says any nonprofit or fraternal organization," he said. "If I'm having five guys over to watch Sunday football every week, that's a regular meeting of three or more people that would require a [CUP]. Now, have they cited anybody for that? No, they're citing a religious meeting."
The Pacific Justice Institute (PJI), who is now representing the Fromms, plans to fight to have the city apologize to the Fromms and refund their money, PJI president Brad Dacus said. The organization also hopes to have the policy revised.
"No family in America should ever have to worry about a local government fining them simply for meeting with their friends and family in their own home to read the Bible or pray together," Dacus said. "The city is demanding that this family has to pay money to the city in order not even to have a Bible study, but in order just to seek permission from the city to be able to have a Bible study. That is totalitarian, it is a clear breach of fundamental civil liberties, and we at [PJI] intend to halt it in its tracks."
San Juan Capistrano issued a quote from city attorney Omar Sandoval stating that "the City of San Juan Capistrano does not prohibit home Bible studies. The issue with the Fromm case involves the question of when a property developed for residential use has been transformed into a place of public assembly. … The Fromm case further involves regular meetings on Sunday mornings and Thursday afternoons with up to 50 people, with impacts on the residential neighborhood on street access and parking."
However, Fromm said that the larger group meetings take place at the local clubhouse, a facility owned by all the residents in the area. The complex has seating for more than 100 people and has its own parking lot, Fromm said. According to a timeline of events he posted on his blog, the group did meet in the Fromm home for nearly a year while the clubhouse was being renovated, but it has moved back to meeting in the clubhouse in July. Currently, the Fromms plan to appeal the violation to the Orange County Superior Court in early October. There are also plans to file a case with the federal courts, Fromm said.
Since the law is meant for general applicability, the success of the case in court will depend whether or not it can be proven that the city was singling out religious groups, said Alan Brownstein, professor of law at the UC Davis School of Law. "Unless you can show that religion is being singled out for discriminatory or disfavored treatment, you don't have a free exercise claim anymore," he said.
In the meantime, Fromm and his wife are continuing to host Bible studies in their home. "They said they're going to cite us $500 for every meeting," he said. "We're [saying], 'Okay, cite us.'"
This is not the first time home Bible studies have been cited or barred in the recent past. In April 2009, San Diego county officials issued a warning to David and Mary Jones for hosting a weekly Bible study in their home without a permit for religious assembly; the county rescinded the warning in June of that year. In November of that year, Joe Sutherland of Gilbert, Arizona, was given a cease-and-desist order for church meetings in his home because it violated the city's zoning code. The city council revised the code the following March to allow the meetings.
Copyright © 2011 Christianity Today. Click for reprint information.
Related Elsewhere:
The Capistrano Dispatch, Los Angeles Times, and ABC News have also covered the dispute.
CaliforniaChurch and StateDiscriminationInternationalLaw and LegislationLaw EnforcementReligious FreedomUnited States
Morgan Feddes September 23, 2011
Christians fleeing Iraq; few entering U.S.
Soberly, a native son fights their cases in immigration court