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104 - Connect with people to Collect an audience
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Hello and welcome to the The Spark & The Art creativity podcast. Thank you for subscribing to our weekly podcast, where we alternate between interviews with creative folks from all different career levels and insight and inspiration episodes. All with the intention you'll get what you need to get your creative projects started and, more importantly, finished.
I'm your host Tucker and this week we talk about connecting with an audience and collecting those interested folks.
In our last interview episode we talked with Cory Smith a software developer and musician. Cory has done a few songs based on the tech world and at the end of the episode you can hear his song Developers (here is an aside: in the episode I ask him about a song he wrote comparing writing code to writing songs and neither of us could remember which one it was. Turns out it was Developers oh well.). The songs we talked about last episode - Developers, One More Thing and Takin' VC Money have 61 thousand, 11 thousand and 28 thousand listens respectively on his SoundCloud at SoundCloud.com/Smixx. Cory says this is because the songs resonated with a specific audience. He says in the interview that he just wanted to write something that he wanted to hear and figured that other people like him, developers who are fans of rap, would like to hear it too. He was right and submitted it to places where he knew his audience was. TechCrunch.com for example and when it was posted the song connected with the audience he was aiming for. It also lead to him being invited to fly to a couple conferences and perform live in front of those audiences.
That's the Connecting part.
To get listens or views or downloads or comments or likes or money or whatever it is you are trying for with your project be sure to know the audience you are trying to connect too. And like Cory you can start with and audience of just you and grow from there.
Now the Collecting part.
This is where it starts to feel funny for people. I know I struggle with it constantly. Cory got over 100 thousand combined listens on the three songs we mentioned previously. 100 Thousand people were intrigued enough to listen to the song. Sites like TechCrunch posted the song. When Smixx releases a new song how many of those people will he be able to tell? How many people will he be able to contact so they know that he has a new song that may resonate with them? About none really. See, even though he did the Connecting he didn't do the Collecting. No emails were collected in exchange for this listens or downloads. No calls to action were created to push a potential fan to a Facebook page or Twitter account. There was no way to create a reconnection. No way to grow that collection.
When Cory puts out a new song he has to start again from scratch basically. He has made some connections with the blogs that shared the songs previously but he doesn't have that place where he can collect those he's connected with. No place where they can all get together and talk about music and technology and share new songs when they come out.
There is a listener to this podcast who has created a colouring book called Doodled Blooms you can find her on twitter @MJ_Flowergirl. In the back she wrote small blurbs about each of the pieces she drew for the book. For image 10 she wrote this … This is super fantastic and makes me happy like you wouldn't believe. It's a real connection. It's a great connection. I've made a connection. At the risk of sounding crass I've also collected her. We chat on twitter but as she's mentioned it's not her main social platform.
So now on to Michelle. She's collected me for sure. I follow her on Instagram at DoodledBlooms we talk via email and I bought her book before I even knew about the awesome blurb she wrote. But beyond that she is connecting with people in real life. She has set up a colouring club in her town and has had book signings where real live people share their colouring they have done with their own hands and talk to her face-to-face about what creativity is and how happy they are when they colour her drawings. She's connecting with people in a very personal way. I can only hope that if she hasn't already that she starts collecting these people as well. Getting an email list going or pointing them to a Facebook group.
Did you know I have an email list? Did you know that if you sign up for it you get a free ebook called The Three Most Difficult Simple Things: guaranteed to transform your creative work. Probably not because I'm a terrible collector. I'm half-decent connector. I have quite a few people I talk with because of the podcast. But I haven't significantly tried to push my email list or start a Facebook group or get all these people into one place to start a community to build a tribe to make a little family of people who love to talk about creativity and it's challenges and rewards. I will though. And when I do you'll be the first to know where to go to start our little family. You know why I haven't yet? It's like when you throw a party and you think. What if no one shows up? What if I make this place for people to come and no one comes. That will make me sad. But at the same time you know who'll care? No one 'cause no one came so no one knows it was a flop and I can just try something else. Okay that settles it. Before July hits I'll have a place for us to hangout. Probably Facebook to start. What do you think? Let me know where you think we should collect ourselves? You can get me on twitter @sparkartpodcast and by email at Tucker@TheSparkAndTheArt.com
Do you know someone who has trouble connecting or collecting? Please share this episode with them and let's hope something sparks in them and they get their stuff going. The easiest way to share is to use the short link TheSparkAndTheArt.com/104 the hardest way is transcribe the entire thing onto lite-brites and string them up around your friends deck like patio lanterns.
Thanks for listening and remember: you won't get the art without the work and you won't do the work without the spark.
Creativity, Collecting Email Addresses, Connecting with fans, Building and audience


A method for producing an isocyanuric acid derivative having two hydrocarbon groups including: a first step of obtaining a compound of Formula (1); a second step of obtaining a compound of Formula (2) from the compound of Formula (1); a third step of obtaining a compound of Formula (3) from the compound of Formula (2); and a fourth step of obtaining a compound of Formula (4) from the compound of Formula (3), wherein Bn is a benzyl group, and two Rs are each a C1-10 hydrocarbon group, wherein all the steps are carried out at a temperature not exceeding 100° C.
The present invention relates to a novel method for producing an isocyanuric acid derivative having two hydrocarbon groups as a substituent to be bonded to a nitrogen atom.
An isocyanuric acid derivative and a method for synthesizing the same have been conventionally known. For example, Patent Document 1 describes a method for synthesizing 1,3-dimethyl-5-(2-hydroxyethyl) isocyanurate that is a specific example of an isocyanurate compound of the following Formula (I). A method for synthesizing 1,3-dimethyl isocyanurate used as a starting material for 1,3-dimethyl-5-(2-hydroxyethyl) isocyanurate is disclosed in pp. 397 to 398 of Non-Patent Document 1. Non-Patent Document 2 introduces a research result in which among 2,4,6-tris(benzyloxy)-1,3,5-triazine, 4,6-bis(benzyloxy)-1,3,5-triazine-2,4(1H,3H)-dione, and 6-(benzyloxy)-1,3,5-triazine-2,4(1H,3H)-dione, 6-(benzyloxy)-1,3,5-triazine-2,4(1H,3H)-dione is a benzylating reagent exhibiting the most excellent reactivity. Non-Patent Document 3 describes N-methylation using tetrabutylammonium isocyanurate. In the N-methylation, all mono-, di-, and tri-methyl isocyanurates are produced. Therefore, in a method described in Non-Patent Document 3, a mixture of the three types of N-methylated isocyanurates is always produced nonselectively.
An isocyanuric acid derivative is used in various applications. For example, the isocyanurate compound described in Patent Document 1 is expected to be used as a raw material for a photocurable resin. Patent Document 2 describes a composition for forming an anti-reflective coating for use in a lithographic process containing an isocyanuric acid derivative. Patent Document 3 describes an adhesive composition containing a polymer obtained by polymerizing an isocyanuric acid derivative and a monomer other than the derivative.
In a conventionally known method for producing a dialkylisocyanuric acid having two alkyl groups of isocyanuric acid derivatives, heating at a high temperature of 150° C. or higher for an extended period of time is required, and the selectivity of a reaction product is low. Therefore, this method is not industrially useful. Further, the method has a step in which safety is concerned as a problem.
(wherein Bn is a benzyl group, and two Rs are each a C1-10 hydrocarbon group), wherein all the steps are carried out at a temperature not exceeding 100° C.
For example, the C1-10 hydrocarbon group is an alkyl group.
The first step is a process in which cyanuric chloride is reacted with benzyl alcohol in the presence of a base selected from the group consisting of a tertiary amine, an alkali metal carbonate, and an alkali metal hydrogen carbonate to obtain a reaction product, and the reaction product is washed with a solvent containing at least one selected from the group consisting of an aliphatic hydrocarbon solvent and an alcohol as a main component to obtain the compound of Formula (1) without purification through column chromatography. The benzyl alcohol and the base can be each used in an amount of 1.0 molar equivalent to 1.9 molar equivalents relative to 1.0 molar equivalent of the cyanuric chloride.
The base used in the first step may be a tertiary amine. Examples of the tertiary amine include diisopropylethylamine. As the base, an alkali metal carbonate or an alkali metal hydrogen carbonate may be used instead of the tertiary amine. Examples of the alkali metal carbonate include sodium carbonate. Examples of the alkali metal hydrogen carbonate include sodium hydrogen carbonate.
The main component of the solvent used for washing the reaction product in the first step may be an aliphatic hydrocarbon solvent. Examples of the aliphatic hydrocarbon solvent include heptane. The main component of the solvent may be an alcohol. Examples of the alcohol include ethanol. Only one type of the solvents may be selected for use, or two or more types of the solvents may be mixed at any ratio for use. Herein, the main component of the solvent is a component that is contained in the solvent in an amount of more than 50% by mass and 100% by mass or less, and preferably 80% by mass or more. The solvent may further contain a subcomponent. The subcomponent may be an ester. Examples of the ester include ethyl acetate.
The second step is a process in which a reaction product obtained by reacting the compound of Formula (1) in a solution containing N-methylmorpholine and an acetic acid salt is washed with water to obtain the compound of Formula (2).
Examples of the acetic acid salt used in the second step include sodium acetate.
Examples of water used for washing the reaction product in the second step include ultrapure water.
The third step is a process in which the compound of Formula (2) is reacted with any one of compounds of the following Formulae (5) to (8) having a C1-10 hydrocarbon group in the presence of an alkali metal carbonate to obtain a reaction product, and to the reaction product, an aromatic hydrocarbon solvent and water are added, resulting in separation, to obtain the compound of Formula (3).
The one of the compounds of Formulae (5) to (8) used in the third step is, for example, an alkylating agent selected from the group consisting of halogenated alkyl, alkyl tosylate, alkyl mesylate, and dialkyl sulfate.
The alkylating agent may be halogenated alkyl or dialkyl sulfate. Examples of the halogenated alkyl include methyl iodide, ethyl bromide, and propyl bromide. Examples of the dialkyl sulfate include dimethyl sulfate. As the alkylating agent, alkyl tosylate or alkyl mesylate may be used instead of halogenated alkyl and dialkyl sulfate. Examples of the alkyl tosylate include methyl p-toluenesulfonate and ethyl p-toluenesulfonate. Examples of the alkyl mesylate include ethyl methanesulfonate.
Examples of the alkali metal carbonate used in the third step include potassium carbonate and cesium carbonate.
Examples of the aromatic hydrocarbon solvent used for separation of the reaction product in the third step include toluene. As water used with the aromatic hydrocarbon solvent, water used in the second step may be used.
The fourth step is a process in which the compound of Formula (3) is reacted with an alcohol compound in the presence of trifluoromethanesulfonic acid to obtain a reaction product, and the reaction product is washed with at least one solvent selected from the group consisting of an ester, a halogen-based solvent, and an alcohol to obtain the compound of Formula (4).
Examples of the alcohol compound used in the fourth step include methanol.
The at least one solvent used for washing the reaction product in the fourth step may be an ester. Examples of the ester include ethyl acetate. The at least one solvent may also be a halogen-based solvent or an alcohol. Examples of the halogen-based solvent include chloroform. Examples of the alcohol include ethanol.
The first to fourth steps are carried out at a temperature not exceeding 100° C. The temperature not exceeding 100° C. is 0° C. to 100° C., for example, 0° C. to 50° C.
A method for producing an isocyanuric acid derivative having two hydrocarbon groups according to the present invention does not include a step carried out at a temperature higher than 100° C. among all the steps, and does not require purification through column chromatography during purification of a reaction product. Therefore, this method is industrially useful. According to the present invention, the isocyanuric acid derivative having two hydrocarbon groups that is a target can be obtained at a high purity as compared with a conventional method.
FIG. 1 is a chromatogram illustrating a result of measurement of a compound of Example 1 obtained in a first step by high performance liquid chromatography.
FIG. 2 is a chromatogram illustrating a result of measurement of a compound of Example 4 obtained in a second step by high performance liquid chromatography.
FIG. 3 is a chromatogram illustrating a result of measurement of a compound of Example 5 obtained in a third step by high performance liquid chromatography.
FIG. 4 is a chromatogram illustrating a result of measurement of a compound of Example 6 obtained in a fourth step by high performance liquid chromatography.
The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to the present invention includes the first to fourth steps. Herewith, the compound of Formula (4) in which two hydrocarbon groups are introduced as a substituent bonded to a nitrogen atom of isocyanuric acid is obtained. In Formula (4), two Rs are each a C1-10 hydrocarbon group introduced. The hydrocarbon group may be a linear, branched, or cyclic hydrocarbon group, and have at least one double bond or triple bond. When the hydrocarbon group is an alkyl group, examples of the alkyl group include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group, n-pentyl group, n-nonyl group, n-decyl group, cyclohexylmethyl group, and cyclopentylmethyl group. Examples of the hydrocarbon group other than the alkyl group include benzyl group, allyl group, and propargyl group.
In the first step of the method of the present invention, cyanuric chloride is reacted with benzyl alcohol in the presence of a base such as a tertiary amine. In order to preferentially obtain the compound of Formula (1) in which only one chlorine atom of three chlorine atoms of cyanuric chloride is substituted with a benzyloxy group by this reaction, it is preferable that benzyl alcohol and the base such as a tertiary amine be each used in an amount of 1.0 molar equivalent to 1.9 molar equivalents relative to 1.0 molar equivalent of cyanuric chloride. When benzyl alcohol and the base such as a tertiary amine are each used in an amount of 2.0 molar equivalents relative to 1.0 molar equivalent of cyanuric chloride in the reaction, a compound in which two chlorine atoms of three chlorine atoms of cyanuric chloride are substituted with a benzyloxy group is produced as a by-product in substantially the same amount as that of the compound of Formula (1) that is a target, together with the compound of Formula (1). Therefore, the yield of the compound of Formula (1) is decreased.
Preferable examples of the tertiary amine used in the reaction include diisopropylethylamine, triethylamine, tributylamine, and 1,8-diazabicyclo[5.4.0]-7-undecene. When the reaction is carried out in a solution, it is preferable that a solvent be a halogen-based solvent. Examples of the halogen-based solvent include chloroform, dichloromethane, carbon tetrachloride, and dichloroethane.
Specifically, the reaction is started by adding a mixed solution of a benzyl alcohol, a base such as a tertiary amine and a halogen-based solvent dropwise to a mixed solution of cyanuric chloride and the halogen-based solvent. The temperature in the dropwise addition is preferably 0° C. to 5° C. When the addition dropwise is carried out at a temperature of higher than 5° C., a by-product is produced in addition to the compound of Formula (1) that is a target. Therefore, the purity and yield of the compound of Formula (1) are decreased. The reaction temperature after the dropwise addition is not particularly limited, and is usually 0° C. to 40° C., and preferably 20° C. to 30° C. The reaction time is usually 1 hour to 5 hours, and preferably 1 hour to 2 hours.
The reaction product obtained by the aforementioned reaction is separated, resulting in concentration. Subsequently, the reaction product is washed with a solvent containing at least one selected from the group consisting of an aliphatic hydrocarbon solvent and an alcohol as a main component, to obtain the compound of Formula (1). When the main component of the solvent used for the washing is the aliphatic hydrocarbon solvent, preferable examples thereof include heptane, hexane, octane, cyclopentane, cyclohexane, and cyclooctane. When the main component is the alcohol, preferable examples thereof include ethanol, methanol, isopropanol, n-propanol, sec-butyl alcohol, tert-butyl alcohol, n-butanol, and cyclohexanol. The amount of the solvent used in the washing is preferably 0.5 to 3.0 times the weight of the compound of Formula (1), and more preferably the same as the weight of the compound of Formula (1). The temperature in the washing is not particularly limited, and is usually 0° C. to 40° C., and preferably 20° C. to 30° C. The washing time is usually 10 minutes to 1 hour, and preferably 10 minutes to 30 minutes.
In the third step of the method of the present invention, the compound of Formula (2) is reacted with any one of compounds of Formulae (5) to (8) in the presence of an alkali metal carbonate. The amount of the one of the compounds of Formulae (5) to (8) to be used is preferably 2 molar equivalents to 3 molar equivalents, and more preferably 2.5 molar equivalents, relative to 1 molar equivalent of the compound of Formula (2). The amount of the alkali metal carbonate is preferably 2 molar equivalents to 3 molar equivalents, and more preferably 2.5 molar equivalents, relative to 1 molar equivalent of the compound of Formula (2). The temperature in the reaction is not particularly limited, and is usually 0° C. to 40° C., and preferably 20° C. to 30° C. The reaction time is usually 1 hour to 5 hours, and preferably 1 hour to 2 hours. When the reaction is carried out in a solution, it is preferable that a solvent be an aprotic polar solvent. Examples of the aprotic polar solvent include dimethyl sulfoxide, N-methylpyrrolidone, dimethylacetamide, and dimethylformamide.
When the one of the compounds of Formulae (5) to (8) used in the third step of the method of the present invention is selected, the type of hydrocarbon group to be introduced as a substituent bonded to a nitrogen atom of isocyanuric acid is determined. For example, as any one of the compounds of Formulae (5) to (8), a methyl group is introduced by using an alkylating agent having a methyl group, an ethyl group is introduced by using an alkylating agent having an ethyl group, a benzyl group is introduced by using a compound having a benzyl group (benzylating agent), an allyl group is introduced by using a compound having an allyl group (allylating agent), or a propargyl group is introduced by using a compound having a propargyl group. The one of the compounds of Formulae (5) to (8) is not limited to the aforementioned examples as long as it is a compound having a C1-10 hydrocarbon group.
To a reaction product obtained by the aforementioned reaction, an aromatic hydrocarbon solvent and water are added, resulting in separation. As a result, the compound of Formula (3) is obtained. In order to remove the aprotic polar solvent used in the reaction by this separation, it is preferable that the aromatic hydrocarbon solvent and water be each used in an amount of 10 times the weight of the compound of Formula (3). The washing is preferably performed two times. When the washing is performed one time, the aprotic polar solvent cannot be removed. When washing is performed three times, the yield of the compound of Formula (3) is decreased. Preferable examples of the aromatic hydrocarbon solvent include toluene, benzene, xylene, mesitylene, chlorobenzene, dichlorobenzene, nitrobenzene, and tetralin. The temperature in the separation is not particularly limited, and is usually 0° C. to 40° C., and preferably 20° C. to 30° C.
In the fourth step of the method of the present invention, the compound of Formula (3) is reacted with an alcohol compound in the presence of trifluoromethanesulfonic acid. Examples of the alcohol compound include methanol, ethanol, isopropanol, n-propanol, sec-butyl alcohol, tert-butyl alcohol, n-butanol, cyclohexanol, and phenol. The amount of the alcohol compound used is preferably 1 molar equivalent to 1.5 molar equivalents, and more preferably 1.2 molar equivalents, relative to 1 molar equivalent of the compound of Formula (3). The amount of the trifluoromethanesulfonic acid used is preferably 0.01 molar equivalents to 2 molar equivalents, and more preferably 0.1 molar equivalents, relative to 1 molar equivalent of the compound of Formula (3). The temperature in the reaction is not particularly limited, and is usually 0° C. to 40° C., and preferably 20° C. to 30° C. The reaction time is usually 1 hour to 5 hours, and preferably 1 hour to 2 hours. When the reaction is carried out in a solution, it is preferable that a solvent be an ether. Examples of the ether include diethyl ether, diisopropyl ether, methyl tert-butyl ether, cyclopentyl methyl ether, tetrahydrofuran, and dioxane.
To a reaction product obtained by the aforementioned reaction, an organic base is added. Concentration is carried out. The reaction product is washed with at least one solvent selected from the group consisting of an ester, a halogen-based solvent, and an alcohol. As a result, the compound of Formula (4) is obtained. Examples of the organic base include pyridine, 4-dimethylaminopyridine, triethylamine, tributylamine, N,N-dimethylaniline, and 1,8-diazabicyclo[5.4.0]-7-undecene. The amount of the organic base used is preferably 0.1 molar equivalents to 1.0 molar equivalent, and more preferably 0.5 molar equivalents, relative to 1 molar equivalent of the compound of Formula (3). When the solvent used in the washing is the ester, preferable examples thereof include ethyl acetate, methyl acetate, butyl acetate, and methyl propionate. When the solvent is the halogen-based solvent, preferable examples thereof include chloroform, dichloromethane, carbon tetrachloride, and dichloroethane. When the solvent is the alcohol, preferable examples thereof include ethanol, methanol, isopropanol, n-propanol, sec-butyl alcohol, tert-butyl alcohol, n-butanol, and cyclohexanol. The amount of the solvent used in the washing is preferably 2.0 to 5.0 times, and more preferably 3.0 times the weight of the compound of Formula (3). The temperature in the washing is not particularly limited, and is usually 0° C. to 40° C., and preferably 20° C. to 30° C. The washing time is usually 10 minutes to 1 hour, and preferably 10 minutes to 30 minutes.
Hereinafter, the method for producing an isocyanuric acid derivative having two hydrocarbon groups according to the present invention will be described with reference to specific examples. However, the present invention is not limited to the specific examples described below.
Purities shown in examples described below are results of measurement by high performance liquid chromatography (hereinafter abbreviated as HPLC). A measurement condition and the like are as follows. The purities are each obtained by dividing a peak of each component as shown in FIG. 1, and calculating the area of each peak of the respective components in percentage.
The purities shown in examples described below are results of measurement by HPLC. A measurement condition and the like are as follows. The purities are each obtained by dividing a peak of each component as shown in FIGS. 2, 3, and 4, and calculating the area of each peak in percentage.
15.00 g of cyanuric chloride (available from Tokyo Chemical Industry Co., Ltd.) and 150.00 g of dichloromethane were mixed, and the mixture was cooled to 0° C. with stirring. To the mixture, a mixed solution of 8.80 g of benzyl alcohol (available from Kanto Chemical Co., Inc.), 11.56 g of diisopropylethylamine, and 60.00 g of dichloromethane was added dropwise. After completion of dropwise addition, the temperature was increased to 25° C. and a reaction solution was stirred for 1.5 hours. To the reaction solution, 150.00 g of 1 M HCl was added, resulting in separation. To an organic phase, 150.00 g of saturated saline solution was added, resulting in separation. This separation operation was repeated twice. From the organic phase, a solvent was distilled off under reduced pressure, and a residue was then dried at 40° C. under reduced pressure. To the residue, 15.0 g of heptane was added, and the mixture was stirred at 25° C. for 10 minutes. After stirring, the mixture was filtered, and a cake was washed with 15.0 g of heptane twice. Herein, the cake is a solid material that remains after a liquid is separated by filtration of a solid-liquid mixture such as a slurry. The resulting crystal was dried at 40° C. under reduced pressure, to obtain 17.31 g of triazine compound of Formula (1) described above as a pale yellow solid (yield: 83.1%). The obtained compound was subjected to measurement under the HPLC analysis condition 1. The purity thereof was 97.8%. A chromatogram obtained by the measurement is shown in FIG. 1.
16.43 g of triazine compound of Formula (1) as a pale yellow solid (yield: 78.9%) was obtained in the same manner as in Example 1 except that a washing solvent was changed from heptane to ethyl acetate/heptane (1/9(w/w/)). The obtained compound was subjected to measurement under the HPLC analysis condition 1. The purity thereof was 98.1%.
16.58 g of triazine compound of Formula (1) as a pale yellow solid (yield: 79.6%) was obtained in the same manner as in Example 1 except that a washing solvent was changed from heptane to ethanol. The obtained compound was subjected to measurement under the HPLC analysis condition 1. The purity thereof was 98.3%.
A residue was obtained in the same manner as in Example 1 except that a washing solvent was changed from heptane to toluene. After stirring, the residue was completely dissolved. As a result, a crystal was not obtained.
3.06 g of triazine compound of Formula (1) as a pale yellow solid (yield: 14.7%) was obtained in the same manner as in Example 1 except that a washing solvent was changed from heptane to ethyl acetate. The obtained compound was subjected to measurement under the HPLC analysis condition 1. The purity thereof was 98.6%.
5.00 g of cyanuric chloride (available from Tokyo Chemical Industry Co., Ltd.) and 50.00 g of dichloromethane were mixed, and the mixture was cooled to 0° C. with stirring. To the mixture, a mixed solution of 2.93 g of benzyl alcohol (available from Kanto Chemical Co., Inc.), 3.86 g of diisopropylethylamine, and 20.00 g of dichloromethane was added dropwise. After completion of dropwise addition, the temperature was increased to 25° C. and a reaction solution was stirred for 1 hour. To the reaction solution, 50.00 g of 1 M HCl was added, resulting in separation. To an organic phase, 50.00 g of saturated saline solution was added, resulting in separation. This separation operation was repeated twice. From the organic phase, a solvent was distilled off under reduced pressure, and a residue was then dried at 40° C. under reduced pressure. The residue was subjected to silica gel chromatography using chloroform/hexane (1/1 (w/w)) as a developing solvent. The obtained solution was concentrated at 40° C. and dried under reduced pressure, to obtain 5.8 g of triazine compound of Formula (1) as a white solid (yield: 84.7%). The obtained compound was subjected to measurement under the HPLC analysis condition 1. The purity thereof was 77.9%.
To 5.8 g of the triazine compound of Formula (1) obtained in Comparative Example 3, 5.0 g of hexane was added, and the mixture was stirred at 25° C. for 10 minutes. After stirring, the mixture was filtered, and a cake was washed with 5.0 g of hexane twice. The resulting crystal was dried at 40° C. under reduced pressure, to obtain 5.50 g of triazine compound of Formula (1) as a white solid (yield: 79.1%). The obtained compound was subjected to measurement under the HPLC analysis condition 1. The purity thereof was 97.4%.
3.95 g of N-methyl morpholine (available from Tokyo Chemical Industry Co., Ltd.), 81.30 g of sodium acetate (available from Kanto Chemical Co., Inc.), and 450.00 g of water were mixed, and the mixture was cooled to 0° C. To the mixture, a mixed solution of 50.00 g of the triazine compound of Formula (1) obtained in Example 1 and 450.00 g of tetrahydrofuran was added dropwise with stirring at a temperature not exceeding 10° C. After completion of dropwise addition, the temperature was increased to 25° C. and a reaction solution was stirred for 46 hours. To the reaction solution, 50.00 g of 1 M HCl was added, and a solvent was then removed under reduced pressure until the weight was 675.00 g. The deposited crystal was filtered, and a cake was washed with 50.00 g of water twice. Subsequently, a residue was dried at 40° C. under reduced pressure, to obtain a crystal. To the crystal, 150.00 g of ethanol was added, and the mixture was stirred at 25° C. for 10 minutes. After stirring, the mixture was filtered, and a cake was washed with 25.00 g of ethanol twice. A residue was dried at 40° C. under reduced pressure, to obtain 29.49 g of triazinedione compound of Formula (2) (yield: 68.9%). The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 95.7%. A chromatogram obtained by the measurement is shown in FIG. 2.
A NMR device used in 1H NMR measurement was JNM-ECA500 manufactured by JEOL Ltd.
A reaction was carried out in the same manner as in Example 4 until a reaction solution was obtained. To the reaction solution, 100.00 g of diethyl ether was added, and the mixture was filtered. Subsequently, separation was carried out, and a dimethyl sulfoxide phase was removed. To a diethyl ether phase, 100.00 g of water was added, resulting in separation. This separation operation was repeated twice. From the organic phase, a solvent was distilled off under reduced pressure, and a residue was then dried at 40° C. under reduced pressure. As a result, 3.30 g of dimethyltriazinedione compound of Formula (3) was obtained (yield: 26.5%). The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 98.8%.
A reaction was carried out in the same manner as in Example 4 until a reaction solution was obtained. 2.00 g of dimethyltriazinedione compound of Formula (3) was obtained (yield: 18.0%) in the same manner as in Example 4 except that cyclopentyl methyl ether was added to the reaction solution. The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 94.0%.
A reaction was carried out in the same manner as in Example 4 until a reaction solution was obtained. 7.70 g of dimethyltriazinedione compound of Formula (3) was obtained (yield: 68.5%) in the same manner as in Example 4 except that ethyl acetate was added to the reaction solution. The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 96.2%.
0.48 g of dimethylisocyanuric acid of Formula (4) as a white solid (yield: 75.0%) was obtained in the same manner as in Example 5 except that a washing solvent was changed from ethyl acetate to chloroform. The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 98.9%.
0.43 g of dimethylisocyanuric acid of Formula (4) as a white solid (yield: 66.5%) was obtained in the same manner as in Example 5 except that a washing solvent was changed from ethyl acetate to ethanol. The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 99.1%.
0.58 g of dimethylisocyanuric acid of Formula (4) as a pale yellow solid (yield: 90.6%) was obtained in the same manner as in Example 5 except that a washing solvent was changed from ethyl acetate to toluene. The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 96.2%.
0.69 g of dimethylisocyanuric acid of Formula (4) as a pale yellow solid (yield: >99.9%) was obtained in the same manner as in Example 5 except that a washing solvent was changed from ethyl acetate to heptane. The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 89.1%.
0.64 g of dimethylisocyanuric acid of Formula described above as a pale yellow solid (yield: 99.4%) was obtained in the same manner as in Example 5 except that a washing solvent was changed from ethyl acetate to cyclopentyl methyl ether. The obtained compound was subjected to measurement under the HPLC analysis condition 2. The purity thereof was 92.0%.
For example, an isocyanuric acid derivative having two hydrocarbon groups produced by the present invention can be applied to an anti-reflective coating-forming composition for lithography, a resist underlayer film-forming composition, a resist upper layer film-forming composition, a photocurable resin composition, a thermosetting resin composition, a flattened film-forming composition, an adhesives composition, and other compositions.
the fourth step is a process in which the compound of Formula (3) is reacted with an alcohol compound in the presence of trifluoromethanesulfonic acid to obtain a reaction product, and the reaction product is washed with at least one solvent selected from the group consisting of an ester, a halogen-based solvent, and an alcohol to obtain the compound of Formula (4), and all the steps are carried out at a temperature not exceeding 100° C.
2. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the C1-10 hydrocarbon group is an alkyl group.
3. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein in the first step, the benzyl alcohol and the base are each used in an amount of 1.0 molar equivalent to 1.9 molar equivalents relative to 1.0 molar equivalent of the cyanuric chloride.
4. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the base is a tertiary amine.
5. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the at least one solvent used in the first step is selected from the group consisting of heptane and ethanol.
6. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein in the second step, a reaction product obtained by reacting the compound of Formula (1) in a solution containing N-methylmorpholine and an acetic acid salt is washed with water to obtain the compound of Formula (2).
7. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the one of compounds of Formulae (5) to (8) is an alkylating agent selected from the group consisting of halogenated alkyl, alkyl tosylate, alkyl mesylate, and dialkyl sulfate.
8. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 7, wherein the alkylating agent is methyl iodide, ethyl bromide, propyl bromide, dimethyl sulfate, methyl p-toluenesulfonate, ethyl p-toluenesulfonate, or ethyl methanesulfonate.
9. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the alkali metal carbonate used in the third step is potassium carbonate or cesium carbonate.
10. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the aromatic hydrocarbon solvent is toluene.
11. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the at least one solvent used in the fourth step is selected from the group consisting of ethyl acetate, chloroform, and ethanol.
12. The method for producing an isocyanuric acid derivative having two hydrocarbon groups according to claim 1, wherein the temperature not exceeding 100° C. is 0° C. to 50° C.


There are varying reasons Great Artists fail young talents when they sign them and I hope I am able to make sense with the points below. 1. Doing the same genre as your Boss is often a prob!
The other thing has to do with features and collaborations. Many Big guys often do not give artist they've signed enough features, some for good reasons some for reasons best known to these guys.
One of the reasons could be the fact that, these signees will always live in the shadows of their label Boss if they continue to spoon feed them through features/collaborations. This is why most musician/Label Bosses back off with features and collaborations. The public often turn to misconstrue this reason. It's not because they do not want to help, it's because they want their signees to create their own path.


Manslaughter is the legal term for when a person is killed in a way that is considered to be less culpable than murder by the laws of the country. In the hierarchy of Texas homicide, manslaughter falls below murder.
In general, the laws of the country differentiate between the levels of criminal culpability based on the state of mind, or mens rea, of the person who committed the crime. In homicide, this general rule applies. Murder requires malice while manslaughter does not. Like murder being broken down into two categories, manslaughter is as well.
Voluntary manslaughter occurs when the defendant might have had the intent to cause the death of another person, but the liability for this intent is reduced because of the circumstances surrounding the death or the person's state of mind. Basically, voluntary manslaughter comes down to crimes of passion or heat of the moment killings.
Involuntary manslaughter, which can also be called criminally negligent homicide, occurs where there is not the intent to kill or cause a serious injury. Here, the death is due to recklessness or criminal negligence on the part of the person who killed the deceased.
While it may seem like manslaughter, particularly voluntary, lets people get away with murder, it doesn't. The crimes are separate and require separate elements. In many manslaughter cases, the defendant is charged with murder but the jury is given the instructions that if they find intent or mental state lacking, they can find the defendant guilty of manslaughter.
If you have been charged with a crime and need experienced representation, contact Austin criminal defense lawyer Ian Inglis at (512) 472-1950.


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This volume assesses the European Union (EU) as a 'Diplomatic Actor' in key foreign policy fields in the post-Lisbon era. It brings together leading scholars and practitioners in order to examine the main players, processes and outcomes of the EU's collective diplomatic engagement in the fields of security, human rights, trade and finance and environmental politics. In addition, the collection also analyses institutional developments and the EU's responses to major internal and external challenges in the context of international politics and global diplomacy. It provides the first comprehensive overview of the scope, nature and impact of the EU's growing role as a diplomatic actor and offers a comparative analysis of EU diplomacy in bilateral, multilateral and international fora. By taking stock of the successes and failures of EU diplomacy, this volume identifies the main internal and external conditions that shape the EU's influence in global affairs.


text:
Q: How can I group multiple e-mail addresses and user names using a regular expression I have the following text that I am trying to parse:

"user1@emailaddy1.com" <user1@emailaddy1.com>, "Jane Doe" <jane.doe@ addyB.org>,
"joe@company.net" <joe@company.net>

I am using the following code to try and split up the string:
Dim groups As GroupCollection
Dim matches As MatchCollection
Dim regexp1 As New Regex("""(.*)"" <(.*)>")
matches = regexp1 .Matches(toNode.InnerText)
For Each match As Match In matches
    groups = match.Groups
    message.CompanyName = groups(1).Value
    message.CompanyEmail = groups(2).Value
Next

But this regular expression is greedy and is grabbing the entire string up to the last quote after "joe@company.net".  I'm having a hard time putting together an expression that will group this string into the two groups I'm looking for:  Name (in the quotes) and E-Mail (in the angle brackets).  Does anybody have any advice or suggestions for altering the regexp to get what I need?

A: Rather than rolling your own regular expression, I would do this:
string[] addresses = toNode.InnerText.Split(",");
foreach(string textAddress in addresses)
{
    textAddress = address.Trim();
    MailAddress address = new MailAddress(textAddress);
    message.CompanyName = address.DisplayName;
    message.CompanyEmail = address.Address;
}

While your regular expression may work for the few test cases that you have shown.  Using the MailAddress class will probably be much more reliable in the long run.

A: How about """([^""]*)"" <([^>]*)>" for the regex? I.e. make explicit that the matched part won't include a quote/closing paren. You may also want to use a more restrictive character-range instead.

A: You need to specify that you want the minimal matched expression.
You can also replace (.*) pattern by more precise ones:
For example you could exclude the comma and the space...
Usually it's better to avoid using .* in a regular expression, because it reduces performance !
For example for the email, you can use a pattern like [\w-]+@([\w-]+.)+[\w-]+ or a more complex one.
You can find some good patterns on : http://regexlib.com/

A: Not sure what regexp engine ASP.net is running but try the non-greedy variant by adding a ? in the regex.
Example regex
""(.*?)"" <(.*?)>

redpajama_set_name: RedPajamaStackExchange


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text:
Home ― About DSU ― Office of the President ― Academic Leadership
SDBOR
President's Cabinet
Dean, Beacom College of Computer and Cyber Sciences
Dr. Richard Hanson serves as Dean of the Beacom College of Computer and Cyber Sciences. The College, with about 40 fulltime equivalent faculty, serves more than 3300 students in more than 150 classes with academic programs in computer science, computer forensics, network security and cyber operations. Dr. Hanson is President Emeritus of Bemidji State University, President Emeritus of Northwest Technical College in Minnesota, former interim president of North Dakota State University, and former President of Waldorf College in Forest City, IA. He has served more than 12 years as a chief academic officer/provost and more than 20 years as a professor of child development and family science. Dr. Hanson served many years as a consultant evaluator for the Higher Learning Commission and has provided leadership around NCAA (Division I and Division II) and NAIA athletics including athletic conference leadership.
In addition to leading the effort to develop a Master Academic Plan at Dakota State, he has responsibility for DSU2025, the university strategic planning process. He has worked within the South Dakota Apprenticeship Network, the DSU Cyber Cync Incubator and Entrepreneurial Center (CCIEC), the South Dakota Partnership for Student Success (SDPaSS), and the Sioux Falls School District Computer Science Academy. He has also been involved with the DSU RISING! effort at Dakota State University. Dr. Hanson and his wife, Dianne, have three grown daughters and five grandchildren.
Office Location: Beacom Institute of Technology
Dorine Bennett
Dean, College of Business and Information Systems
College of Business and Information Systems
Ed.D., University of South Dakota
M.B.A., University of South Dakota
B.S., Dakota State University
Dr. Dorine Bennett is the Academic Dean of College of Business and Information Systems. She is an active member of national and regional health information management associations and has earned Fellowship status in the American Health Information Management Association. Prior to coming to DSU, she worked in the health information management field in long term care, community health, and acute care settings. Dr. Bennett has a Master's of Business Administration (MBA), with an emphasis in Management of Information Systems. She also holds a PhD in Educational Administration, Adult and Higher Education.
Office Location: East Hall
Judy Dittman
Interim Dean, College of Arts and Sciences / Title III Director
Ph.D., University of Iowa
M.S., South Dakota State University
B.S., Black Hills State University
Dr. Judy Dittman is the Interim Dean for the College of Arts and Sciences. She has served in a variety of positions including Provost, Associate Provost, Dean for the College of Education, Director of Athletics, originator and Director of the DSU Wellness Center, Assessment Committee Chair, Coordinator for the Secondary Education Coordinating Committee, and Faculty Senate Chair. Her teaching background is as diverse as her management positions having taught a number of introductory and methodology courses for physical education and exercise science and served as supervisor for physical education student teachers. In addition to the administrative and teaching responsibilities, Dr. Dittman also coached multiple sports including basketball, softball, and track and field.
Office Location: Beadle Hall
Mark Hawkes
Dean, Graduate Studies/ Professor / CTL Director
Graduate Office
Ph.D., Syracuse University
M.S., Brigham Young University
B.S., Brigham Young University
Dr. Mark Hawkes is Dean of Graduate Studies and the Director of the Center for Teaching and Learning at Dakota State University. He is also a Professor of Instructional Technology. Previous positions were held at the Evaluation and Policy Information Center of the North Central Regional Educational Laboratory in Chicago and the Center for Instructional Development at Syracuse University where he also received a Ph.D. Mark has led and participated in a number of district and statewide studies and evaluations of educational technology, fueling his research interests in the outcomes of educational technology application on student learning and teacher professional development. Additional research is also applied to understand optimal instructional design in distributed learning environments. Mark resides in Madison with his wife Joy and their five children.
Office Location: Kennedy Center
Crystal Pauli
Dean, College of Education / Associate Professor
Ph.D., Capella University
Ed.S., Minnesota State University-Moorhead
M.S., Northern State University
B.A., Dakota Wesleyan University
Dr. Crystal Pauli is the Dean of the College of Education and served as Director of Field Services for 13 years and special education faculty for two years prior to becoming the Dean in 2016. Before coming to DSU, Dr. Pauli was a Child Study Coordinator for the SW/WC Service Cooperative in Minnesota, a special education teacher in Minnesota, and an elementary teacher in South Dakota. Dr. Pauli is a member of the Board of Regents Education Discipline Council, South Dakota Association of Colleges of Teacher Education, Delta Kappa Gamma, Catholic Daughters of the Americas, VFW Auxiliary, DAV Auxiliary, and American Association of University Women. Dr. Pauli is involved in teacher education accreditation at the local, state, and national levels.

redpajama_set_name: RedPajamaCommonCrawl


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text:
Rugby Player Found Guilty of 'High Level' Breach of Contract for Posting Bible Verse on Instagram
Mikaela Mathews | ChristianHeadlines.com Contributor | Monday, May 13, 2019
#religious liberty
Australian rugby player Israel Folau has been found guilty of breach of contract by Rugby Australia for posting a Bible verse on homosexuality.
As Christian Headlines previously reported, Folau, who was contracted with Rugby Australia until 2022 and was paid over $1M a year, was fired for posting 1 Corinthians 6:9, warning that drunks, homosexuals, adulterers, liars, fornicators, thieves, atheists, and idolaters will go to hell.
Despite his termination, Folau requested a three-person independent hearing, according to the BBC. The hearing determined his breach of contract and will consider written statements from both parties before deciding Folau's punishment.
Folau had been warned about his posts previously. "At its core, this is an issue of the responsibilities an employee owes to their employer and the commitments they make to their employer to abide by their employer's policies and procedures and adhere to their employer's values," Raelene Castle, chief executive of Rugby Australia said.
The rugby player has since lost two of his major sponsors since the post. As reported by CBN News, both Land Rover and Asics have let go of his contracts. "We champion inclusivity and diversity," Asics wrote in a statement. "While Israel Folau is entitled to his personal views, some of those expressed in recent social media posts are not aligned with those of Asics. As such, our partnership with Israel has become untenable and he will no longer represent Asics as a brand ambassador."
Not everyone has rejected Folau, however. His former coach Alan Jones came to his defense. "The Australian people won't accept this," he said on his radio show 2GB, according to MSN. "Israel Folau, with my support and the support of millions of Australians, will take this fight every inch of the way. Rugby union preaches diversity — they really mean uniformity. They preach inclusion but they exclude Israel…I coached Australian rugby, I was proud of it, I was proud of the boys and I was proud of everything we stood for. Today, I'm ashamed of the people who've inherited our proud legacy. The battle has just begun, and it's a battle for all Australians."
He continued: "If we're not free to articulate our religious beliefs and quote from the Bible, and if we're not free to speak for fear that someone affects a hurt or is part of the offense industry, if that's where we've reached this country, we've reached a dark place and we are all at risk."
Despite the loss of his contract, Folau is in high spirits. When Jones comforted him, Folau responded: "Alan, I'm at peace, mate. My head is held high."
Rugby League to Fire $1M Star Player over Bible Verse Post on Homosexuality
Rugby Star Apologizes for 'I Love You Jesus' Easter Post after Backlash
Photo courtesy: Getty Images/Anthony Au Yeung/Stringer


PLANE food is often a disappointing and soggy mess - but it's rare to be served a dish that spans the decades.
So a passenger on an easyJet flight was stunned recently after he was served a sandwich labelled ten YEARS out of date.
Adrian Bell, 59, was returning to the UK from a holiday in Zante with his wife, Lindsey, 42, when he purchased the cheese toastie.
He looked at the snack and realised that the date read June 16, 2007 - nearly ten years out of date at that time.
But easyJet insists that the item was not out of date, but instead was labelled incorrectly.
When Adrian, a father of one from Wrexham, Wales, noticed the date on his toasted sandwich, he instantly complained to staff on the flight.
He claims one of the flight attendants then quipped: "We should charge you more, it's an antique".
Adrian said: "I was flying back to the UK after a family holiday on June 15 when I was served the sandwich.
"I told staff on the plane about it and they said it wasn't out of date - but they were just looking at the day and month, not the year."
He continued: "The date on the back read 16/06/2007, that's ten years out of date. The flight staff said that no one else had complained.
"I've been writing to customer service but they just don't answer. It was dangerous serving it, we don't know how long it's been frozen for.
''I told them and they carried on serving them, so I started telling the other passengers on the plane.
"It was still really tasty, to be honest, but it was over cooked."
But easyJet this morning insisted that the sandwich was still in date, and the confusion came from an incorrectly printed label.
A spokesperson said: "We have looked into this with our in-flight partner and they have confirmed that this sandwich was in date.
"This was obviously a manual printing error and we are surprised that anyone would think it was anything else."


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text:
Q: Does copy elision work with structured bindings Does mandatory copy elision apply to decomposition via structured bindings?  Which of the following cases does that apply to?
// one
auto [one, two] = std::array<SomeClass>{SomeClass{1}, SomeClass{2}};

// two
auto [one, two] = std::make_tuple(SomeClass{1}, SomeClass{2});

// three
struct Something { SomeClass one, two; };
auto [one, two] = Something{};

I suspect only the third case allows for copy elision, since the first two will be "decomposed" via std::get<> and std::tuple_size<> and std::get<> returns xvalues when the arguments are rvalues
A quote from the standard would be nice also!

A: Interesting question:
#include <iostream>
#include <array>
#include <tuple>
#include <typeinfo>
using std::cout;
using std::endl;

struct SomeClass
{
    int baz;

    SomeClass(int _b): baz(_b) {
        cout << __PRETTY_FUNCTION__ << " = " << baz << endl;
    }
    SomeClass(SomeClass&&) {
        cout << __PRETTY_FUNCTION__ << endl;
    }
    SomeClass(const SomeClass&) {
        cout << __PRETTY_FUNCTION__ << endl;
    }
};

template<typename T> void tell(T&& a)
{
    cout << "Tell: " << __PRETTY_FUNCTION__ << " = " << a.baz << endl;
}

int main()
{
     // one
     cout << "= 1 =" << endl;
     auto [one, two] = std::array<SomeClass,2>{SomeClass{1}, SomeClass{2}};
     cout << "===" << endl;
     tell(one); tell(two);
     // two
     cout << endl << "= 2 =" << endl;
     auto [one2, two2] = std::make_tuple(SomeClass{1}, SomeClass{2});
     cout << "===" << endl;
     tell(one2); tell(two2);
     // three
     cout << endl << "= 3 =" << endl;
     struct Something { SomeClass one{1}, two{2}; };
     auto [one3, two3] = Something{};
     cout << "===" << endl;
     tell(one3); tell(two3);

    return 0;
}

Produces output:
= 1 =
SomeClass::SomeClass(int) = 1
SomeClass::SomeClass(int) = 2
===
Tell: void tell(T&&) [with T = SomeClass&] = 1
Tell: void tell(T&&) [with T = SomeClass&] = 2

= 2 =
SomeClass::SomeClass(int) = 2
SomeClass::SomeClass(int) = 1
SomeClass::SomeClass(SomeClass&&)
SomeClass::SomeClass(SomeClass&&)
===
Tell: void tell(T&&) [with T = SomeClass&] = 0
Tell: void tell(T&&) [with T = SomeClass&] = 4199261

= 3 =
SomeClass::SomeClass(int) = 1
SomeClass::SomeClass(int) = 2
===
Tell: void tell(T&&) [with T = SomeClass&] = 1
Tell: void tell(T&&) [with T = SomeClass&] = 2

Second case uses either copy or move (if available)   constructor.  Values weren't  initialized, because  I intentionally didn't do that in constructors.
There are three protocols of binding

*

*binding to array

*binding to tuple-like type

*binding to public data members

In second case (sorry, I don't have access to C++17 pdf, so cppreference):

Each identifier becomes a variable whose type is "reference to
  std::tuple_element<i, E>::type": lvalue reference if its corresponding
  initializer is an lvalue, rvalue reference otherwise. The initializer
  for the i-th identifier is

*

*e.get<i>(), if lookup for the identifier get in the scope of E by class member access lookup finds at least one declaration (of whatever
  kind)

*Otherwise, get<i>(e), where get is looked up by argument-dependent lookup only, ignoring non-ADL lookup

First and second stage of example are actually  bindings to tuple-like type.
But... In second stage what we use to initialize? A template function that constructs tuple:
 std::make_tuple(SomeClass{1}, SomeClass{2});

which would actually either copy or move values. Further copy elision may occur, but
 auto t = std::make_tuple(SomeClass{1}, SomeClass{2});
 auto [one2, two2] = t;

would produce this output:
SomeClass::SomeClass(int) = 2
SomeClass::SomeClass(int) = 1
SomeClass::SomeClass(SomeClass&&)      //make_tuple
SomeClass::SomeClass(SomeClass&&)
SomeClass::SomeClass(const SomeClass&) //assignment
SomeClass::SomeClass(const SomeClass&)

Although properly de-sugaring structured binding looks like:
 auto t = std::make_tuple(SomeClass{1}, SomeClass{2});
 auto& one2 = std::get<0>(t);
 auto& two2 = std::get<1>(t);

and output  matches original:
SomeClass::SomeClass(int) = 2
SomeClass::SomeClass(int) = 1
SomeClass::SomeClass(SomeClass&&)
SomeClass::SomeClass(SomeClass&&)
===

So, the copy or move operation that happens, is  from constructing our tuple.
We would avoid that, if we construct tuple using universal references, then both desugared
 auto t = std::tuple<SomeClass&&, SomeClass&&>(SomeClass{1}, SomeClass{2});
 auto& one2 = std::get<0>(t);
 auto& two2 = std::get<1>(t);

and structured binding
 auto [one2, two2] = std::tuple<SomeClass&&, SomeClass&&>(SomeClass{1}, SomeClass{2});

would result in copy elision.

A:
Does mandatory copy elision apply to decomposition via structured bindings? Which of the following cases does that apply to?

Yes, all of them. The point of structured bindings is to give you named references to the destructured elements of the type you're binding to. This:
auto [one, two] = expr;

Is just syntax sugar for:
auto __tmp = expr;
some_type<0,E>& a = some_getter<0>(__tmp);
some_type<1,E>& b = some_getter<1>(__tmp);

Where some_type and some_getter depend on the kind of type we're destructuring (array, tuple-like, or type with all public non-static data members).
Mandatory copy elision applies in the auto __tmp = expr line, none of the other lines involve copies.

There's some confusion around an example in the comments, so let me elaborate on what happens in:
auto [one, two] = std::make_tuple(Something{}, Something{});

That expands into:
auto __tmp = std::make_tuple(Something{}, Something{}); // note that it is from
// std::make_tuple() itself that we get the two default constructor calls as well
// as the two copies.
using __E = std::remove_reference_t<decltype(__tmp)>; // std::tuple<Something, Something>

Then, since __E is not an array type but is tuple-like, we introduce variables via an unqualified call to get looked up in the associated namespace of __E. The initializer will be an xvalue and the types will be rvalue references:
std::tuple_element_t<0, __E>&& one = get<0>(std::move(__tmp));
std::tuple_element_t<1, __E>&& two = get<1>(std::move(__tmp));

Note that while one and two are both rvalue references into __tmp, decltype(one) and decltype(two) will both yield Something and not Something&&.


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Lizzie Borden lived with their father and stepmother into adulthood. Lizzie and her stepmother, Abby Borden, were not close. She worried that Abby Borden's family sought to gain access to her father's money.


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First Look image released from Save The Cinema, a Sky Original
Available on Sky Cinema and in cinemas from 14 January 2022
Sky today unveils a First Look image of Samantha Morton in the Sky Original film Save The Cinema. Inspired by the extraordinary real-life events sparked by tenacious hairdresser Liz Evans (Samantha Morton), Save The Cinema illustrates how the resolve of a small Welsh town, inspired by the magic of cinema, was able to bring Tinseltown to their doorstep.
The sleepy town of Carmarthen in Wales is not exactly the first place to spring to mind when thinking of Hollywood blockbusters. But this changed in 1993 when the town council made the unwelcome announcement that The Lyric Theatre – the town's much-loved but financially stricken cinema – would be demolished so a shopping centre could be built in its place.
It's down to Liz Evans, hairdresser and linchpin to the local community, to stand up for the ailing cinema and stop the bulldozers. As she and her friends barricade themselves in the theatre, she reaches out to postman turned town councillor Richard (Tom Felton) for help – and they come up with a grand plan.
To revitalise the cinema and stop the council taking the heart of the community away, a desperate Liz persuades Richard to write to Hollywood to ask for a helping hand. One late night phone call later and one of Hollywood's most legendary filmmakers throws The Lyric a monster-sized lifeline and a premiere Carmarthen will never forget. But will this be enough to save The Lyric?
Save The Cinema features an all-star cast including Samantha Morton (Fantastic Beasts and Where To Find Them), Tom Felton (Harry Potter), Jonathan Pryce (The Two Popes), Adeel Akhtar (Enola Holmes), Erin Richards (Gotham), Owain Yeoman (Emergence), Susan Wokoma (Enola Holmes), Colm Meaney (Gangs Of London), Rhod Gilbert (Have I Got News For You) and Keith Allen (Kingsman: The Golden Circle). The film is directed by Sara Sugarman (Confessions of a Teenage Drama Queen) and co-produced by Sky and Future Artists Entertainment Film & Television in association with Head Gear Films, LipSync and Ffilm Cymru.
Save The Cinema, a Sky Original will be released on Sky Cinema and in cinemas from 14 January 2022. The film will also be available on streaming service NOW via the Sky Cinema Membership.
Categories: Movies, News, SkyTags: Adeel Akhtar, Colm Meaney, Erin Richards, Jonathan Pryce, Keith Allen, liz Evans, Owain Yeoman, Rhod Gilbert, Samantha Morton, Sara Sugarman, Save The Cinema, Sky Cinema, Sky Original, Susan Wokoma, Tom Felton
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Professor's retirement highlights lifetime of work advancing health care research at ASU
Downtown Phoenix campus
Founder says goodbye on 20th anniversary of Center for Health Information and Research
Nowadays, you don't have to look very hard to see the power of big data. From targeted advertisements to specially curated Netflix queues to optimized navigation routes, algorithms, data capture and cloud computing do nothing less than make modern daily life possible.
In a research setting, big data has massive potential to inform and expand our understanding of a particular field, especially if that field produces incredible amounts of data every day.
Twenty years ago, ASU College of Health Solutions biomedical informatics Professor Bill Johnson saw that potential where others did not when he founded the Center for Health Information and Research (CHiR), Arizona's first and only health care data analytics repository — no small feat at a time when not many had attempted anything on that scale, let alone succeeded.
According to a number of Johnson's friends and colleagues, because CHiR works mostly behind the scenes, it hasn't always gotten the attention it deserves for the impact it has had on Arizonans' health. To date, CHiR has been responsible for approximately $7.6 million in sponsored research that has aided Arizona policymakers and health care professionals to better address such issues as Medicaid, opioid abuse and child drownings. His colleagues say it would be a misstep to overlook the value of such an entity, of which there are precious few in the country.
At a retirement ceremony for him Tuesday evening on the Downtown Phoenix campus, they praised Johnson for as much, and more.
"Bill really built a health care data infrastructure at a time when health care data infrastructures were not very prevalent," said Eugene Schneller, a professor of supply chain management at the W. P. Carey School of Business. "The other thing he did is he took a generation of students, many of whom are now CEOs in major systems around the country, and he really made them economics literate. And that's something that's really tough to do."
An economist by training, Johnson's first foray into health care was as a graduate student when he participated in research looking at the impact of health conditions on individuals' ability to work. Later, as a professor at Syracuse University, he was invited to participate in a Harvard medical malpractice study, the largest such study ever conducted, and then followed that up with a study on asbestos for the Mount Sinai Health System in New York.
After nearly two decades at Syracuse, Johnson joined ASU in 1991, assuming a joint appointment at what was then the School of Health Management and Policy and the W. P. Carey School of Business' Department of Economics. He soon found that his research reputation preceded him, and he was fielding numerous requests for contributions to studies assessing various aspects of the health care industry.
Johnson put together a small group of researchers to take on the work. One request came from the Flinn Foundation, which for many years had been concerned with quantifying the number of uninsured Arizonans — without much success. They asked if it was possible and Johnson told them it was, but that it would take time and patience due to the amount of data that needed to be collected, catalogued and analyzed.
The foundation was game and Johnson set about his task.
"The idea was that we'd go to health care providers and we would just ask them to share their data," he said.
Some researchers had tried before, but failed because they were only willing to accept data in certain formats.
"We just said, 'We'll take whatever you have,'" Johnson said. "Which in a few cases turned out to be pretty rough. Some of those systems were pretty old. I remember bringing back a tape from Yuma and my programmers, who were relatively young, had never seen one. They asked, 'What is that?' I told them, 'That's a DOS-based tape.'
"So we found that despite all that carrying on about different softwares making it impossible, that you could certainly translate the data from one software to another."
As the dataset grew, it eventually became the Center for Health Information and Research, officially founded in 1999. Today, it contains health care information on roughly 9 million individuals and roughly 300 million health care episodes. Crucially, it also contains the entire Medicaid database of Arizona.
Over the years, CHiR moved around the university with Johnson as new departments were created and old departments were restructured, finding a home for a time in the biomedical informatics department of the engineering school before it moved to the College of Health Solutions, where it exists now. At various points in time, its focus has shifted from health care delivery to the health workforce.
In one NIH study, researchers at CHiR were asked to look at the long-term outcome of Medicaid-required preventive procedures on infants. Because their database covers such a wide timespan, they were able to determine the effects on children into their early teens, whereas other organizations might only be able to look at the effects two or three years out. (CHiR found that the children who received preventive procedures were less likely to be injured but not necessarily less likely to become ill.)
"It's like a library," Johnson said. "So let's say you want to start a research project and you want to look at people with Alzheimer's. Well, what are your choices? You could go out and do a survey, which is time consuming and expensive and it's a one-time shot. Whereas every hospital, every health care provider, every insurance company, every day produces detailed data that now exists in this centralized database that is constantly updating from as many sources as possible. So you don't have to go through that whole long collection period and you actually have better data because you can follow people over time."
CHiR also has datasets on every pharmacist, nurse and physician in Arizona from as far back as 2007 for nurses and as far back as 1991 for physicians. That information is useful in instances where, for example, government and university officials are deciding whether to open a medical school or not.
"So there again we've got a longitudinal picture from, in some cases, the day a physician started to practice until they're middle-aged or older," Johnson said. "Because of CHiR and only because of CHiR, that data will be there the next time somebody wants to know about the distribution and age of primary care physicians in Arizona, for example. You're not going to have to wait two years to collect the data and then maybe find what you're looking for."
Johnson admits it's a hard sell to investors.
"It's very hard to get external funding to maintain the database during periods when nobody's interested in certain questions. But CHiR is pretty much operating at capacity all the time, which then very much limits its ability to take on new projects. And there's plenty of opportunities to explore new questions with the data we already have."
Community impact has always been at the core of CHiR's work. In 2005 and again in 2008, the center won the President's Medal for Social Embeddedness.
"I think it goes to Michael Crow's vision to impact the community in which we live," said George Runger, current director of CHiR and a professor of biomedical informatics at the College of Health Solutions. "I think that's really what our role is."
CHiR has no less than 28 projects currently underway, ranging from improved effectiveness of community health centers to tracking electronic health record adoption to the effects of extreme weather on asthma to child eye exam coverage.
Though Johnson relinquished his role as director of the center in 2012, he still plays a vital role in its research and day-to-day operations, something those who know him well expect will continue in spite of his retirement.
"I really don't believe him, that he's retiring," university provost and Executive Vice President Mark Searle said at Tuesday evening's ceremony. "So I said to him, 'That just means you're not on the payroll anymore, right?'
"Bill was doing this work long before this became a part of the national dialogue and the national rhetoric around public policy. He was truly a pioneer in this space. … And I'm so glad to see people here today to honor Bill for that work because it's truly a remarkable commitment. At ASU, we believe that we have to take responsibly for the health and the well-being of the communities that we serve, and that's exemplified by CHiR and all the work Bill has done over many, many years. He has really done the kinds of things that a university wants to be known for."
Top photo: ASU College of Health Solutions Professor of biomedical informatics and founder of the Center for Health Information and Research Bill Johnson and his wife, Saundra, listen to the accolades at his retirement celebration after a 28-year tenure at the university, on Tuesday, Sept. 10, 2019. About 50 former colleagues, staff, students and family came to honor the prolific researcher who combined his skills in economics with his passion for health solutions. Photo by Charlie Leight/ASU Now
Arizona Impact Downtown Phoenix campus Health Nursing and Health Care Research College of Health Solutions Faculty Staff
Emma Greguska
Reporter, ASU Now
(480) 965-9657 emma.greguska@asu.edu
Hispanic Heritage Month a time for pride, inclusion and learning
Hispanic Heritage Month is a time for pride and reflection, celebrating millions of Americans who have positively influenced and shaped our society.Beyond that, it should be a time of learning and inclusion for Hispanics and people who have an interest in delving deeper into other cultures, said Vanessa Fonseca-Chávez, an assistant professor of English in the College of Integrative Sciences and A...
Polytechnic campus
ASU professor offers insight on the monthlong celebration of Hispanic culture
Hispanic Heritage Month is a time for pride and reflection, celebrating millions of Americans who have positively influenced and shaped our society.
Beyond that, it should be a time of learning and inclusion for Hispanics and people who have an interest in delving deeper into other cultures, said Vanessa Fonseca-Chávez, an assistant professor of English in the College of Integrative Sciences and Arts at Arizona State University's Polytechnic campus.
"Hispanic culture and communities are more deeply embedded in the United States than what most people realize, and it's one of the fastest growing demographics," said Fonseca-Chávez, whose work focuses on layered colonial relationships in pre-Chicana/o and Chicana/o literature and cultural production in the Southwest United States.
ASU Now spoke to Fonseca-Chávez about the roots and intricacies of Hispanic Heritage Month, which runs from Sept. 15 to Oct. 15.
Question: Why do we have Hispanic Heritage Month?
Answer: Hispanic Heritage Month began in 1968, which is fitting because it coincides with the Chicana/o movement of the 1960s and 1970s and the struggle for educational, cultural and political recognition for Chicanx and Latinx communities. Hispanic Heritage Month allows us to take pause and reflect on the contributions of these communities, some of whom have been in the present-day U.S. since the late 1500s. The timeline for Hispanic Heritage Month is Sept. 15 through Oct. 15 to recognize the independence of many Latin American countries from Spain in the 19th century. I think Hispanic Heritage Month can be useful when conceptualized as both a learning and cultural process of inclusion. This means, whether inward or outward facing, we have to move beyond just painting a palatable image of Hispanics/Latinx and think critically about how Hispanics/Latinx have suffered from various forms of injustice and oppression over time.
Q: Where did the term Hispanic come from and is that preferable to or more accurate than Latino?
A: The word Hispanic came from the Nixon administration and later was used as a census term intended to embody a heterogenous group of individuals from Spanish-speaking countries. In 2000, the census began using the term Latino to refer to those who came from Latin America, recognizing that not all individuals who come from Latin America speak Spanish. Both are umbrella terms and fail to recognize region-specific and/or complex identities. Someone who identifies as Latinx might also identify as Puertoriqueña or Boriqua, and perhaps even Afro-Latinx. There has been a trend to use Latino over Hispanic, though I would not say that one is more accurate or preferable. In New Mexico, for example, people often refer to themselves as Hispano or Hispana. This may be viewed by those outside of New Mexico as assimilationist, but it is not up to us how one chooses to identify. When identities are imposed upon a population, it strips them of the agency to explore identity for themselves and come to terms with an identity that best frames their particular experiences.
Q: What do Hispanic Heritage Days across the United States look like and how do they vary?
A: Hispanic Heritage Month celebrations vary across the United States and, oftentimes, can be a reflection of the cultural/ethnic heritage of the region that has historically been shaped by migration patterns. This is not dissimilar to universities whose academic units represent regional identities and concerns. You see more Chicanx studies programs in the U.S. West and Southwest and more Latinx or Caribbean studies programs as we move toward the East Coast. However, we need to be cognizant of how we include other Latinx groups within Hispanic Heritage Month celebrations so that, regardless of where we are located geographically, we can learn more about all Latinx communities.
Q: When you have such a catch-all term as Hispanic Heritage Month for the 25-odd countries it represents, does that run the risk of a generic picture of one culture?
A: Absolutely; we are not one singular culture and should not be celebrated as such. This is a challenge that nearly all heritage month celebrations face. Those who are in charge of programming for Hispanic Heritage Month should be as inclusive as possible. This doesn't mean that we have to do something directed toward each country; that would be nearly impossible and potentially shallow. However, we can invite folks to the planning and presentation table who can expand our understanding of Latinx communities and be intentional in our efforts to bring in as many voices and perspectives as possible.
Q: What do you personally do to celebrate Hispanic Heritage Month?
A: Throughout the year, I consistently am looking for events in the community and at ASU that celebrate and highlight Hispanic communities. Every fall, I teach a transborder Chicana/o literature course and encourage my students to go to at least two events during the semester that can broaden their understanding of Chicanx/Latinx culture. I believe that representation matters and that learning about and appreciating other cultures can make us better human beings.
Top photo: Vanessa Fonseca-Chávez, in front of artwork by Calle 16 at the Barrio Cafe in Phoenix, is an assistant professor of English in the College of Integrative Sciences and Arts. Her teaching focuses on Chicana/o and indigenous literature and cultural production. Photo by Charlie Leight/ASU Now
Global Engagement Polytechnic campus College of Integrative Sciences and Arts Expert Q-and-A Diversity International Humanities Community Faculty Staff Campus student International student
Marshall Terrill
480-727-5176 marshall.terrill@asu.edu


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Kansas Supreme Court Schedules Oral Arguments for BTK Media Case
The Kansas Supreme Court has scheduled oral arguments for January 26, 2009, for the appeal that, among other issues, will raise the question of what are the limits to a news organization's rights to report the news. Melanie Valadez, Adm. of Estate of Roger G. Valadez, Appellee, v. Emmis Communications and Todd Spessard, Appellants.
The appeal was originally going to be heard by the state appellate court, but this fall the state's high court selected it on its own accord as a case that should instead be heard in that venue. Member Bernie Rhodes (Business Litigation - Kansas City) filed a brief with the Kansas Court of Appeals in May this year on behalf of KSN, a television station that in 2004 had identified a possible suspect in the BTK serial murders in its ongoing coverage of the matter. The station had been ordered in 2006 to pay $1.1 million in damages to Roger Valadez, whom Wichita police investigated as a BTK suspect.
In the brief, Mr. Rhodes argued that the Wichita news outlet performed journalism that complied with the ethics of the profession, in the station's efforts to report what eventually proved to be the truth, i.e., that Mr. Valadez was, in fact, being investigated in connection with the BTK case. Mr. Rhodes argued that other broadcast journalists also had identified the suspect, by showing footage of the outside of his house, as well as reporting on his age and address. (These stations had not included the suspect's name in their coverage).
A Kansas jury decided against the television station in the 2006 trial, holding that the television station acted outrageously and damaged Mr. Valadez' reputation by publicly airing his name after his arrest on Dec. 1, 2004 on unrelated charges. The defamation verdict was subsequently overturned by a judge, though $250,000 of the outrage verdict was left intact. Mr. Valadez was released the day after his arrest by Wichita police when a DNA test eliminated him as a BTK suspect. He died a month after the initial 2006 trial against KSN. Dennis Rader of Park City would later confess to committing the BTK murders.
About Lathrop Gage:
A full-service law firm, Lathrop Gage L.C. has 300 attorneys in 10 offices nationwide – from Denver, Colo. to New York, New York. In 2008, Chambers USA ranked Lathrop Gage's corporate, environmental, intellectual property, litigation, real estate and labor and employment teams among the best in the Midwest. For more information, visit www.lathropgage.com.
Bernard J. Rhodes


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Q: how to get data into an array after post using axios in reactjs I am creating album using reactjs. I'm using loopback-storage-connector for storing images.
this is my code for uploading image
fileUploadCarImg =()=>{
    for (let index = 0; index < this.state.file.length; index++) {
        const element = this.state.file[index];
        const fd = new FormData();
        fd.append('image2',element,element.name )
        axios.post('http://localhost:3000/api/attachmentBanks/Car_Image/upload',fd , {
            onUploadProgress : ProgressEvent => {
                console.log('Upload Progress: ' + Math.round(ProgressEvent.loaded / ProgressEvent.total *100) + '%')
            }
        })
        .then(res => {
            console.log(res.data.result.files.image2[0].name)
        });

    }

}

I want to store those image names into loopback-mysql-connector. so my idea is storing each and every image name (res.data.result.files.image2[0].name) into an array.
while uploading image console.log(this.state.file) print
Array(8) [ File, File, File, File, File, File, File, File ]

(8) […]

0: File { name: "IMG_20150905_072534.jpg", lastModified: 1442772056000, size: 241381, … }

1: File { name: "IMG_20151110_115108.jpg", lastModified: 1447206282000, size: 2749010, … }

2: File { name: "IMG_20151110_115124.jpg", lastModified: 1447206242000, size: 2797533, … }

3: File { name: "IMG_20151110_120625.jpg", lastModified: 1447205916000, size: 725661, … }

4: File { name: "IMG_20151110_120642.jpg", lastModified: 1447206122000, size: 687308, … }

5: File { name: "IMG_20151110_120704.jpg", lastModified: 1447205958000, size: 3364141, … }

6: File { name: "IMG_20151110_121043.jpg", lastModified: 1447205998000, size: 2921138, … }

7: File { name: "IMG_20151110_121050.jpg", lastModified: 1447206044000, size: 3867974, … }

length: 8

<prototype>: [

I just need to store name of the image.
Anyone please give any hint to solve my problem?

A: I suggest using the Array.prototype.map() function:
const names = res.data.result.files.map((file) => file.image2[0].name);

The array is quite hard to decipher, but with minor adjustments it should work.

A: Please, consider to use await
let data = [];
for (let index = 0; index < this.state.file.length; index++) {
    const element = this.state.file[index];
    const fd = new FormData();
    fd.append('image2',element,element.name )

    try {
        const res = await axios.post('http://localhost:3000/api/attachmentBanks/Car_Image/upload',fd , {
            onUploadProgress : ProgressEvent => {
                console.log('Upload Progress: ' + Math.round(ProgressEvent.loaded / ProgressEvent.total *100) + '%')
            }
        });

        data.push(res.data.result.files.image2[0].name);

    } catch(error) {
        //your handler
    }

}


Mention hashtags and most of us think of Instagram and Twitter. They are a growing area on Pinterest and on Facebook too. But what about LinkedIn? Do you use them and if so, what's the best approach?
The first time that hashtags on LinkedIn were a thing was back in 2016 but they only worked on the mobile app. You could tap them and see related content. The following year they showed up on desktop, but it was still unclear what the strategy behind them was. In 2018 there was talk of people being able to only post when they included a hashtag but that turned out to be just a short-term beta test.
At the moment, they are best approached in a similar way to Twitter, to help categorise content and connect it to other topics. Hashtags can be clicked and bring a dedicated feed of content featuring them and that means people can search for them as well.
Interestingly, hashtags work a little differently in profiles and company pages. You can add them, but they aren't clickable as they are when included in updates. However, if someone searches for a hashtag and you have either the word, with or without the # symbol, it should show up in the results.
There are two main things to do with hashtags on LinkedIn. First, you can find relevant hashtags and use them to interact with others. Second, you can add them to your content so people can search and find your stuff by its hashtag.
When you add a post straight to LinkedIn, you can either add the # to specific words in the update or add them at the end of the post. If you are writing an article on their Pulse platform, you can add hashtags to the end of the article and also use them when you tell your network (publish) the article.
You can also pop them in comments to help make a post more discoverable and associate your comment with a topic.
To find and follow a hashtag, simply search for it in the same way as any other term in the search bar. Select the hashtag you are looking for and then there will be a 'follow' button in the corner. Tap this and you will see the hashtag appear on the side of your main feed, under your communities and groups.
As with all platforms, there are a few best practice tips to help you use hashtags without overusing them.
Finding the best hashtag approach with LinkedIn is certainly simpler than on Instagram where you need a whole strategy just for them! Don't go over the top, use them smartly and ensure they are relevant and useful. Then you can enhance your LinkedIn profile and make more connections.