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Ozone (O) is a trace gas of the troposphere, with an average concentration of 20-30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. . Ozone is also an important constituent of the stratosphere, where the ozone layer exists. The troposphere is the lowest layer of the Earth's atmosphere. It extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. It's concentration increases as height above sea level increases, with a maximum concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming. 
20-30 parts per billion by volume