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The WF molecule is octahedral with the symmetry point group of O. The W–F bond distances are 183.2 pm. Between 2.3 and 17 °C, tungsten hexafluoride condenses into a pale yellow liquid having the density of 3.44 g/cm<sup>3</sup> at 15 °C. At 2.3 °C it freezes into a white solid having a cubic crystalline structure, the lattice constant of 628 pm and calculated density 3.99 g/cm<sup>3</sup>. At −9 °C this structure transforms into an orthorhombic solid with the lattice constants of "a" = 960.3 pm, "b" = 871.3 pm, and "c" = 504.4 pm, and the density of 4.56 g/cm<sup>3</sup>. In this phase, the W–F distance is 181 pm, and the mean closest intermolecular contacts are 312 pm. Whereas WF gas is one of the densest gases, with the density exceeding that of the heaviest elemental gas radon (9.73 g/L), the density of WF in the liquid and solid state is rather moderate.
The vapor pressure of WF between −70 °C and 17 °C can be described by the equation
where the "P" = vapor pressure (bar), "T" = temperature (°C).
WF