Did you know that crystals form the basis for the penetrating icy blue glare of car headlights and could be fundamental to the future in solar energy technology?
The atomic arrangement at a relaxed InGaN/GaN interface. Research at ASU and Georgia Tech show layer-by-layer crystal growth may lead to record-breaking efficiencies in photovoltaic solar cell technology. Photo by: Arizona State University
Crystals are at the heart of diodes. Not the kind you might find in quartz, formed naturally, but manufactured to form alloys, such as indium gallium nitride or InGaN. This alloy forms the light emitting region of LEDs, for illumination in the visible range, and of laser diodes (LDs), in the blue-UV range.
Research into making better crystals with high crystalline quality, light emission efficiency and luminosity is also at the heart of studies being done at Arizona State University by research scientist Alec Fischer and doctoral candidate Yong Wei in professor Fernando Ponce’s group in the Department of Physics.
In an article recently published in the journal Applied Physics Letters, the ASU group, in collaboration with a scientific team led by professor Alan Doolittle at the Georgia Institute of Technology, has just revealed the fundamental aspect of a new approach to growing InGaN crystals for diodes, which promises to move photovoltaic solar cell technology toward record-breaking efficiencies.
Solar energy crystallizes
The InGaN crystals are grown as layers in a sandwich-like arrangement on sapphire substrates. Typically, researchers have found that the atomic separation of the layers varies; a condition that can lead to high levels of strain, breakdowns in growth and fluctuations in the alloy’s chemical composition.
“Being able to ease the strain and increase the uniformity in the composition of InGaN is very desirable,” says Ponce, “but difficult to achieve. Growth of these layers is similar to trying to smoothly fit together two honeycombs with different cell sizes, where size difference disrupts a periodic arrangement of the cells.”
As outlined in their publication, the authors developed an approach where pulses of molecules were introduced to achieve the desired alloy composition. The method, developed by Doolittle, is called metal-modulated epitaxy. “This technique allows an atomic, layer-by-layer growth of the material,” says Ponce.
Analysis of the atomic arrangement and the luminosity at the nanoscale level was performed by Fischer, the lead author of the study, and Wei. Their results showed that the films grown with the epitaxy technique had almost ideal characteristics and revealed that the unexpected results came from the strain relaxation at the first atomic layer of crystal growth.
“Doolittle’s group was able to assemble a final crystal that is more uniform and whose lattice structures match up … resulting in a film that resembles a perfect crystal,” says Ponce. “The luminosity was also like that of a perfect crystal. Something that no one in our field thought was possible.”
The perfect solar cell?
The ASU and Georgia Tech team’s elimination of these two seemingly insurmountable defects (non-uniform composition and mismatched lattice alignment) ultimately means that LEDs and solar photovoltaic products can now be developed that have much higher, efficient performance.
“While we are still a ways off from record-setting solar cells, this breakthrough could have immediate and lasting impact on light emitting devices and could potentially make the second most abundant semiconductor family, III-Nitrides, a real player in the solar cell field,” says Doolittle. Doolittle’s team at Georgia Tech's School of Electrical and Computer Engineering also included Michael Moseley and Brendan Gunning. A patent is pending for the new technology.