The main line of its research is the study of the atomic structure of solids. Several methods are used depending on the form of the samples and the parameters to be determined. The laboratory is equiped for the study of single crystals, powders and thin layers.
Single crystals (characteristic size ~0.1 mm) are measured by single crystal diffraction technique. This allows the determination of the atomic or molecular structure unknown subtances. There is a possibility to measure at non ambient conditions (25-300 K and max. 50 Kbar).
Powders (individual crystallites tipically have less than 1 mikron diameter) are measured by x-ray powder diffraction. More than 1 mg powder is necessary to take a good quality pattern. There is a possibility to measure as a function of temperature (100-1000 K ). The concentration of known phases can be determined from powder data.
Thin layer samples have large, smooth and flat surface. They can be composed of a single or a multilayer on a substrat. Layer thickness (in the range of 5-100 nm), periodicity (in the range of 5-50 nm) and surface/layer roughness can be determined.
X-ray holographic measurement on NiO. Left upper panel shows the measured Kossel line pattern, together with the hologram, which has a much smaller amplitude. The hologram of the atoms surrounding the Ni atom is depicted on the right upper panel. The 3D real space arrangement of atoms is shown on the lower panel, as reconstructed from the hologram. Click on the image to get a better view (290kB).
Beside these traditional methods the group is working on the development of new techniques for structure determination. In the last few years two methods, the nuclear resonant scattering of gamma rays from powders, and the atomic resolution x-ray holography were developed. The first one can be used to study the relation of hyperfine fields and crytal structures in powdered samples containing Mössbauer isotopes. The x-ray holography gives information on the local atomic environment of selected elements in three dimensions. The application of the above methods are not wide spread yet. Further theoretical and experimental work is necessary to implement them in commertial equipments.
Most important fields of research: Structural study of fullerenes, nuclear scattering, x-ray holography.
Gyula Faigel, E-mail:
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László Gránásy, E-mail:
Carbon nanostructures have been among the hottest topics in the study of novel materials in recent years. In our laboratory we investigate fullerenes, carbon nanotubes, graphene, and self-assembled nanostructures using various optical spectroscopy techniques ranging from the far-infrared to the UV region.
Fullerenes are highly symmetric structures and even small distortions can change their spectroscopic properties considerably. One special case of these distortions is caused by the molecular Jahn-Teller effect. In fullerene-based solids, the Jahn-Teller effect is coupled to strong electron correlation and this coupling results in unconventional phenomena, such as the Mott-Jahn-Teller insulating phase or correlated superconductivity. Vibrational spectroscopy is a very sensitive tool to detect the subtle details of these states and their transitions.
Carbon nanotubes are another exciting family of carbon materials both as model systems for unusual physical effects and as potential applications. We study fundamental properties of high purity single-walled carbon nanotube samples with different diameter distribution, the effect of doping and of covalent functionalization on the electronic properties, and ways to improve nanotube films to be used as transparent conductors, similar to the currently used ITO. Our methods are optical and fluorescence spectroscopy.
There is a wide variety of supramolecular structures that are investigated and, in some cases, prepared in our laboratory. Among these are fullerene-cubane rotor-stator systems, carbon nanotubes filled with various materials and hydrogen-bonded systems. We use vibrational spectroscopy to characterize the structure and dynamics of these systems.
For more information, please visit our website: http://www.nanonews.hu