"Ammonia for Power" is an open-access literature review that includes over 300 citations for recent and ongoing research in the use of ammonia in engines, fuel cells, and turbines, as well as providing references to decades of historical case studies and publications. The review, written by a consortium of ammonia energy experts from the University of Cardiff, University of Oxford, the UK's Science and Technology Facilities Council, and Tsinghua University in China, can be found in the November 2018 edition of Progress in Energy and Combustion Science.
This week, DNV GL published its annual Energy Transition Outlook, providing a long-term forecast for global energy production and consumption, and including a dedicated report describing its Maritime Forecast to 2050. This is the first forecast from a major classification society explicitly to evaluate ammonia as a maritime fuel.
By 2050, DNV GL predicts that 39% of the global shipping energy mix will consist of "carbon-neutral fuels," a category that include ammonia, hydrogen, biofuels, and other fuels produced from electricity. By 2050, these fuels will therefore have gained greater market share than oil, LNG, and battery-electric. If ammonia succeeds as the carbon-neutral fuel of choice in the shipping sector, this new demand will be roughly equivalent to 200 million tons of ammonia per year, more than today's total global production.
Last month, an important new consortium in the Netherlands announced its intention to research and demonstrate "the technical feasibility and cost effectiveness of an ammonia tanker fuelled by its own cargo." This two-year project will begin with theoretical and laboratory studies, and it will conclude with a pilot-scale demonstration of zero-emission marine propulsion using ammonia fuel in either an internal combustion engine or a fuel cell.
Of all the devices that can convert the chemical energy in ammonia to electricity, gas turbines and fuel cells appear to be receiving the lion’s share of development effort, outstripping that devoted to ammonia-fueled internal combustion engines (A-ICEs). An Ammonia Energy review last year found a number of organizations with histories of work on A-ICE technology, but reports of progress have not been forthcoming.
It was good news, therefore, when a representative of a newly engaged group appeared at the NH3 Energy+ Topical Conference earlier this month and delivered a talk on an innovative A-ICE “combustion strategy.” Donggeun Lee from the Department of Mechanical Engineering at Seoul National University (SNU) delivered the paper, entitled “Development of new combustion strategy for internal combustion engine fueled by pure ammonia,” on behalf of his co-authors, Hyungeun Min, Hyunho Park, and Han Ho Song.
In the race to place the automotive sector on a sustainable footing, the field is dominated by just two horses: battery-electricity and hydrogen fuel cells. The economic implementation of BEVs is already well underway, with motor companies on track in 2017 to sell more than a million vehicles globally for the first time. The economic implementation of FCVs is also in progress, albeit at a much earlier stage, and has the backing of major motor companies and public-sector agencies. Given the huge leads enjoyed by electricity and hydrogen, ammonia is scarcely seen as a contending fuel. Earlier this month, though, the U.S. Department of Energy’s ARPA-E unit published an interview with two of its program managers that has an intriguing implication: the race is far from over and ammonia may yet break to the front of the pack.
The University of Western Australia has entered the increasingly competitive field of ammonia energy research in Australia, announcing a collaborative agreement to develop "the world's first practical ammonia-powered vehicle" as well as an "ammonia-based hydrogen production plant."
These goals are supported by funding from the R&D arm of Shenhua Group, formerly a coal company but now "China's largest hydrogen producer with a production capacity to power 40 million fuel cell passenger cars."
In the last 12 months ...
The maritime industry has begun assessing ammonia as a carbon-free fuel, for internal combustion engines and fuel cells. This marks the first time since the 1960s, when NASA used ammonia to fuel the X-15 rocket plane, that industry players have seriously considered ammonia for transport applications.
A paper has just been published by researchers in The Philippines who set out to determine the most environmentally benign way to produce, transport, and use ammonia as a fuel for vehicles.
This new work provides a detailed life cycle analysis of a broad range of ammonia technologies, evaluating both carbon and nitrogen footprints of each, and identifying the optimal "well-to-wheel" pathway. Their results support the idea that using ammonia for energy presents a safe and sustainable way to bring about the hydrogen economy.
On April 27 the on-line journal Science Advances published “Carbon-free H2 production from ammonia triggered at room temperature with an acidic RuO2/γ-Al2O3 catalyst.” The lead author, Katsutoshi Nagaoka, and his six co-authors are associated with the Department of Applied Chemistry at Oita University in Japan. The innovation featured in the paper could prove to be an important enabler of ammonia fuel in automotive applications.
Next month the print edition of Fuel Processing Technology will feature a paper entitled “Auto-ignition of a carbon-free aqueous ammonia/ammonium nitrate monofuel: a thermal and barometric analysis.” This title is provocative. First, what is this idea of a fuel composed of a mixture of ammonia and ammonium nitrate (AN)? If ammonia is a good fuel, is it made better with the addition of ammonium nitrate? Second, why is it aqueous? Is the presence of water a feature or a bug? Third, what is a monofuel and why is this term used when the fuel is a mixture of two molecular species? And finally, why is the paper ultimately about auto-ignition?