Phase transitions—transformations from one state of matter to another—are ubiquitous in food and cooking. Butter’s phase transition from a solid to a liquid results in flaky pie crusts, while water’s phase transition from a liquid to a gas can be used to steam vegetables. There are various ways to manipulate these phase transitions, such as by altering temperature, pressure, or salt content. In this classic home experiment, we will make ice cream by using salt to alter the phase behavior of water.
- Understand how solutes (salt) affect the phase behavior of a solvent (water).
- Use freezing point depression to make a batch of amazing ice cream.
- 1 cup cream
- 1/2 cup sugar
- 200 grams ice
- Kosher salt
- 1 quart Ziploc bag
- 1 gallon Ziploc bag
Part 1: Use salt to lower the melting point of ice
To successfully freeze ice cream without the help of a freezer, we need a way to efficiently transfer heat out of the ice cream. Liquid water is much better than solid ice at transferring heat, so an ice-water bath will absorb heat from our ice cream better than solid ice. To effectively freeze ice cream, however, we need stable temperatures well below 0˚C.
How is it possible to have a mixture of water and ice at a temperature below 0˚C, water’s freezing point?
When you take ice straight out of the freezer, the ice will be roughly the same temperature as the freezer itself. The temperature in a home freezer is typically between 0˚C and -20˚C. As the ice sits out, it will absorb heat from its surroundings and slowly get warmer until it reaches 0˚C and begins to melt. Adding impurities like salt to ice will lower its melting point. This means that salted ice will start melting at temperatures below 0˚C. As a result, a salty ice-water bath can stay liquid at temperatures well below 0˚C and efficiently freeze our ice cream. We refer to this phenomenon as “freezing point depression.”
We can use the freezing point depression equation to calculate how much a solvent’s freezing point will drop as a solute is added:
∆Tf = b · Kf · i
∆Tf Freezing point depression, defined as Tf of pure solvent – Tf of solution.
K f Cryoscopic constant of the solvent. This is an intrinsic property of the solvent.
b Molar concentration of the solute: the number of moles of solute per kilogram of solvent.
i Number of ion particles per molecule of solute, also known as the “Van’t Hoff factor”.
Salt is made up of one sodium ion and one chloride ion, so its Van’t Hoff factor is 2.
- Use the freezing point depression equation to calculate how much salt (our solute) is needed to decrease the freezing point of water (our solvent) from (a) 0˚C to -5˚C, (b) 0˚C to -10˚C, (c) 0˚C to -15˚C, and (d) 0˚C to -20˚C.
- Plot the magnitude of freezing point depression (ΔTf) versus salt concentration (Results from 1a, b, c, and d). Remember to use units!
- Based on your answer from 1d, calculate how many grams of salt are required to create a -20˚C freezing point depression for 200g of ice. This is the amount of salt you will use in Part 2.
Some useful values:
Freezing point (Tf) for pure water: 0˚C.
Cryoscopic constant (Kf) for water: 1.853 ˚C*kg/mol.
Molecular weight of salt (NaCl): 58.44 g/mol.
Part 2: Use freezing point depression to make ice cream
- Combine cream and sugar in the quart-size bag and mix well. Place this bag inside the gallon bag.
- Record the initial temperatures of the ice and the cream mixture.
- In the gallon bag, pack the ice around the quart-size bag, and then sprinkle the calculated amount of salt over the ice. Be careful that the salt does not fall into the cream mixture.
- Gently shake the bag until the cream mixture solidifies into ice cream.
- Record the final temperatures of the ice-salt-water mixture and the ice cream.
- Enjoy your homemade ice cream!
- What was the final temperature of the ice cream? Did it end up below 0˚C? How does its temperature compare to the temperature of the salt-ice-water mixture?
- What was the final temperature of the ice-salt-water mixture? Is warmer or colder than the ice you started with? How does the temperature compare to the freezing point depression you calculated in Part 1?
In this experiment, we used salt to lower the freezing point of water. By adding salt to ice, we were able to achieve a salt-ice-water mixture that was able to freeze our ice cream.
Why does ice cream need temperatures colder than the freezing point of water in order to freeze?
When water freezes, it forms a well-ordered crystalline structure (an ice cube). This unique crystalline structure is what gives solid water a slightly lighter density. Although ice cream is a combination of cream, sugar, and flavorings, it is still approximately 60% water. The remaining 40% is a mixture of sugar molecules, fat globules, and milk proteins . This liquid mixture is emulsified: the water molecules are dispersed among sugar molecules, milk protein complexes, and large clusters of fat globules.. When this mixture is brought to the freezing temperature of water, the fats, proteins, and sugars hamper the freezing process by interrupting the formation of ordered crystal water structures. The ice cream mixture thus remains a liquid, requiring even colder temperatures below 0˚C to successfully solidify .
|Structure of ice cream. (A) an electron micrograph of ice cream showing air bubbles, ice crystals, and the sugar solution . Fat globules and milk proteins are not visible at this resolution. (B) Diagram of ice cream structure adapted from University of Guelph.|
How did the salt in our experiment create a salt-ice-water mixture below 0˚C?
At 0˚C, ice and water are “at equilibrium” with each other. The total amount of water and ice remains relatively constant, but individual water molecules are constantly switching states: as some water molecules melt and become liquid, other water molecules freeze and become solid. Adding a solute like salt shifts this equilibrium. Solutes essentially “trap” water molecules in the liquid state, preventing them from readily switching back to the solid state. On a macroscopic scale, salt causes solid ice to melt faster and at temperatures below 0˚C, resulting in a salt-ice-water mixture below 0˚C. To get a better feel for how this process works at the molecular level, check out this interactive demonstration of how temperature and solutes affect the water-ice equilibrium.
Contrary to popular belief, the addition of salt to ice does not actually make the ice any colder!
The temperature that you recorded for the salt-ice-water mixture was probably colder than the temperature of the pure ice you started with. How is this possible? When you take the temperature of solid ice, you are not really measuring the temperature of the ice itself—you are measuring the average temperature of the ice, the air around the ice, and any water that has formed from the ice melting. The true temperature of the ice depends on the temperature freezer it came from (typically between 0˚C and -20˚C) and the length of time the ice has spent out of the freezer.
- Interactive explanation of how temperature and solutes affect water-ice equilibrium
- “Ice Cream Structure” from University of Guelph
More from On Food and Cooking
- McGee, Harold. On Food and Cooking. Scribner, 2004. (39–44).
- Goff HD (1997) Colloidal aspects of ice cream—A review. International Dairy Journal 7: 363–373. doi:10.1016/S0958-6946(97)00040-X.
- Hartel RW (1996) Ice crystallization during the manufacture of ice cream. Trends in Food Science & Technology 7: 315–321. doi:10.1016/0924-2244(96)10033-9.
- Clarke C (2003) The physics of ice cream. Physics Education 38: 248–253. doi:10.1088/0031-9120/38/3/308.