Please solve the programming task below using a self-contained code snippet in a markdown code block.

In a linked list of size n, where n is even, the ith node (0-indexed) of the linked list is known as the twin of the (n-1-i)th node, if 0 <= i <= (n / 2) - 1.

For example, if n = 4, then node 0 is the twin of node 3, and node 1 is the twin of node 2. These are the only nodes with twins for n = 4.

The twin sum is defined as the sum of a node and its twin.
Given the head of a linked list with even length, return the maximum twin sum of the linked list.
 
Please complete the following python code precisely:
```python
# Definition for singly-linked list.
# class ListNode:
#     def __init__(self, val=0, next=None):
#         self.val = val
#         self.next = next
class Solution:
    def pairSum(self, head: Optional[ListNode]) -> int:
```