**Apache Airflow version**: 2.0.0rc3

**Kubernetes version (if you are using kubernetes)** (use `kubectl version`):

**Environment**:

- **Cloud provider or hardware configuration**: Linux
- **OS** (e.g. from /etc/os-release): Ubuntu
- **Kernel** (e.g. `uname -a`): 
- **Install tools**:
- **Others**:

**What happened**:

After shutting down the scheduler, while tasks were in running state, trying to restart the scheduler results in pk violations..

```[2020-12-15 22:43:29,673] {scheduler_job.py:1293} ERROR - Exception when executing SchedulerJob._run_scheduler_loop
Traceback (most recent call last):
  File "/home/jcoder/git/airflow_2.0/pyenv/lib/python3.7/site-packages/sqlalchemy/engine/base.py", line 1277, in _execute_context
    cursor, statement, parameters, context
  File "/home/jcoder/git/airflow_2.0/pyenv/lib/python3.7/site-packages/sqlalchemy/engine/default.py", line 593, in do_execute
    cursor.execute(statement, parameters)
psycopg2.errors.UniqueViolation: duplicate key value violates unique constraint "dag_run_dag_id_run_id_key"
DETAIL:  Key (dag_id, run_id)=(example_task_group, scheduled__2020-12-14T04:31:00+00:00) already exists.
```


**What you expected to happen**:

Scheduler restarts and picks up where it left off.

**How to reproduce it**:

Set example dag ( I used task_group) to schedule_interval `* * * * *` and start the scheduler and let it run for a few minutes. 
Shut down the scheduler
Attempt to restart the scheduler

**Anything else we need to know**:
I came across this doing testing using the LocalExecutor in a virtual env. If no else is able to reproduce it, I'll try again in a clean virtual env.

airflow/jobs/scheduler_job.py
if not tis_with_right_state:
            return len(event_buffer)
        
        filter_for_tis = TI.filter_for_tis(tis_with_right_state)
        tis: List[TI] = session.query(TI).filter(filter_for_tis).options(selectinload('dag_model')).all()
        for ti in tis:
            try_number = ti_primary_key_to_try_number_map[ti.key.primary]
            buffer_key = ti.key.with_try_number(try_number)
            state, info = event_buffer.pop(buffer_key)
            
            if state == State.QUEUED:
                ti.external_executor_id = info
                self.log.info("Setting external_id for %s to %s", ti, info)
                continue
            if ti.try_number == buffer_key.try_number and ti.state == State.QUEUED:
                Stats.incr('scheduler.tasks.killed_externally')
                msg = (
                    "Executor reports task instance %s finished (%s) although the "
                    "task says its %s. (Info: %s) Was the task killed externally?"
                )
                self.log.error(msg, ti, state, ti.state, info)
                request = TaskCallbackRequest(
                    full_filepath=ti.dag_model.fileloc,
                    simple_task_instance=SimpleTaskInstance(ti),
                    msg=msg % (ti, state, ti.state, info),
                )
                self.processor_agent.send_callback_to_execute(request)
        return len(event_buffer)
    def _execute(self) -> None: