**Apache Airflow version**: 2.0.0rc3

**Kubernetes version (if you are using kubernetes)** (use `kubectl version`):

**Environment**:

- **Cloud provider or hardware configuration**: Linux
- **OS** (e.g. from /etc/os-release): Ubuntu
- **Kernel** (e.g. `uname -a`): 
- **Install tools**:
- **Others**:

**What happened**:

After shutting down the scheduler, while tasks were in running state, trying to restart the scheduler results in pk violations..

```[2020-12-15 22:43:29,673] {scheduler_job.py:1293} ERROR - Exception when executing SchedulerJob._run_scheduler_loop
Traceback (most recent call last):
  File "/home/jcoder/git/airflow_2.0/pyenv/lib/python3.7/site-packages/sqlalchemy/engine/base.py", line 1277, in _execute_context
    cursor, statement, parameters, context
  File "/home/jcoder/git/airflow_2.0/pyenv/lib/python3.7/site-packages/sqlalchemy/engine/default.py", line 593, in do_execute
    cursor.execute(statement, parameters)
psycopg2.errors.UniqueViolation: duplicate key value violates unique constraint "dag_run_dag_id_run_id_key"
DETAIL:  Key (dag_id, run_id)=(example_task_group, scheduled__2020-12-14T04:31:00+00:00) already exists.
```


**What you expected to happen**:

Scheduler restarts and picks up where it left off.

**How to reproduce it**:

Set example dag ( I used task_group) to schedule_interval `* * * * *` and start the scheduler and let it run for a few minutes. 
Shut down the scheduler
Attempt to restart the scheduler

**Anything else we need to know**:
I came across this doing testing using the LocalExecutor in a virtual env. If no else is able to reproduce it, I'll try again in a clean virtual env.

airflow/serialization/serialized_objects.py
"""Helper function of depth first search for serialization.
        The serialization protocol is:
        (1) keeping JSON supported types: primitives, dict, list;
        (2) encoding other types as ``{TYPE: 'foo', VAR: 'bar'}``, the deserialization
            step decode VAR according to TYPE;
        (3) Operator has a special field CLASS to record the original class
            name for displaying in UI.
        """
        if cls._is_primitive(var):
            
            if isinstance(var, enum.Enum):
                return var.value
            return var
        elif isinstance(var, dict):
            return cls._encode({str(k): cls._serialize(v) for k, v in var.items()}, type_=DAT.DICT)
        elif isinstance(var, list):
            return [cls._serialize(v) for v in var]
        elif HAS_KUBERNETES and isinstance(var, k8s.V1Pod):
            json_pod = PodGenerator.serialize_pod(var)
            return cls._encode(json_pod, type_=DAT.POD)
        elif isinstance(var, DAG):
            return SerializedDAG.serialize_dag(var)
        elif isinstance(var, BaseOperator):
            return SerializedBaseOperator.serialize_operator(var)